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Interactions of Clay Minerals with Organic Polymers. Some Practical Applications

Published online by Cambridge University Press:  01 July 2024

B. K. G. Theng
B. K. G. Theng*
Affiliation:
Division of Applied Mineralogy, C.S.I.R.O., Melbourne, Australia
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Abstract

An account is given of the interactions between clay minerals and organic polymers with particular reference to their applications in agriculture, foundation engineering and industry.

Résumé

Résumé

On donne un exposé des inter-réactions entre les minéraux argileux et les polymères organiques, en mentionnant en particulier leurs applications dans les domaines de l’agriculture, de la technique des fondations et de l’industrie.

Kurzreferat

Kurzreferat

Es wird über die Wechselwirkungen zwischen Tonmineralen und organischen Polymeren berichtet, und zwar unter besonderem Hinweis auf ihre Verwendungsbereiche in der Landwirtschaft, dem Ingenieurbau und der Industrie.

Резюме

Резюме

Подробно рассмотрено взаимодействие глинистых минералов с органическими полимерами; особое внимание уделено их применению в сельском хозяйстве, для улучшения свойств грунтов и в промышленности.

Type
Research Article
Information
Clays and Clay Minerals , Volume 18 , Issue 6 , December 1970 , pp. 357 - 362
Copyright
Copyright © 1970 The Clay Minerals Society

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References

Ahlrichs, J. L. (1962) Bonding of organic polyanions to clay minerals: Dissertation Abstr. 22, 2121.Google Scholar
Baum, V. O. (1969) Peroxide cured polyethylene compositions containing coated clays: U.S. Pat. 3, 425, 980.Google Scholar
Bergmann, W. and Fiedler, H. J. (1956) Der Einfluss synthetischer heteropolarer Linearkolloide unterschiedlicher Kettenlänge auf Kaolinund Bentonitauf- schlämmungen: Z. Pflanzenern. Düng. Bodenk. 72, 111–136.CrossRefGoogle Scholar
Beutelspracher, H. (1955) Wechselwirkung zwischen anorganischen und organischen Kolloiden des Bodens: Z. Pflanzenern. Düng. Bodenk. 69, 108–115.CrossRefGoogle Scholar
Bixler, H. J. and Fallick, G. (1969) Reinforcing filler for polymers: U.S. Pat. 3, 471, 439.Google Scholar
Blumstein, A. (1965) Polymerization of adsorbed monolayers. I. Preparation of the clay-polymer complex : J. Polymer Sci. A3, 2653–2664.Google Scholar
Carter, L. W., Hendricks, J. G. and Bolley, D. S. (1950) Elastomer reinforced with modified clay: U.S. Pat. 2, 531, 396.Google Scholar
Clapp, C. E. and Emerson, W. W. (1965) The effect of periodate oxidation on the strength of soil crumbs: Soil Sci. Soc. Am. Proc. 29, 127–134.CrossRefGoogle Scholar
Cook, L. E. (1966) China clays in the polymer industry: Rubber Plastics Age 47, 284–288.Google Scholar
Cook, L. E. and Pickering, F. G. (1968) Kaolinite fillers in rubber: Rubber Meeting of Swedish Inst. Rubber Technology, Falsterbo.Google Scholar
Emerson, W. W. (1955) Complex formation between montmorillonite and high polymers: Nature 176, 461.CrossRefGoogle Scholar
Emerson, W. W. (1956) Synthetic soil conditioners: J. Agr. Sci. 47, 117–121.CrossRefGoogle Scholar
Emerson, W. W. (1960) Complexes of calcium montmorillonite with polymers: Nature 186, 573–574.CrossRefGoogle Scholar
Emerson, W. W. (1963) The effect of polymers on the swelling of montmorillonite: J. Soil. Sci. 14, 52–63.CrossRefGoogle Scholar
Emerson, W. W. and Raupach, M. (1964) The reaction of polyvinyl alcohol with montmorillonite: Aust. J. Soil Res. 2, 46–55.CrossRefGoogle Scholar
Fallick, G. J., Bixler, H. J., Marsella, R. A., Garner, F. R. and Fettes, E. M. (1968). Mineral-reinforced thermoplastics: Modern Plastics 45, 143–149, 209, 214.Google Scholar
Ferrigno, T. H. (1962) Polyurethane foam containing inorganic pigment coated with polymeric material: U.S. Pat. 3, 024, 209.Google Scholar
Fischer, E. W. and Rentschier, W. (1957) Zur Verbesserung der Bodenstruktur durch synthetische Hochpolymere: Z. Pflanzenern. Düng. Bodenk. 76, 232–244.CrossRefGoogle Scholar
Furter, W. F. (1964) Filled linear polyethylene compositions: Can. J. Chem. Engng 77–81.CrossRefGoogle Scholar
Giles, C. H., MacEwan, T. H., Nakhwa, S. N. and Smith, D. (1960) Studies in adsorption. Part XI. A system of classification of solution adsorption isotherms, and its use in diagnosis of adsorption mechanisms and in measurement of specific surface areas of solids: J. Chem. Soc. 3973–3993.Google Scholar
Gluesenkamp, E. W. (1957) Organic materials: U.S. Pat. 2, 795, 545.Google Scholar
Greenland, D. J. (1963) Adsorption of polyvinyl alcohols by montmorillonite: J. Colloid Sci. 18, 647–664.CrossRefGoogle Scholar
Greenland, D. J. (1965) Interaction between clays and organic compounds in soils. II. Adsorption of soil organic compounds and its effect on soil properties: Soils and Fertilizers 28, 52 1–532.Google Scholar
Greenland, D. J., Lindstrom, G. R. and Quirk, J. P. (1962) Organic materials which stabilize natural soil aggregates: Soil Sci. S oc. Am. Proc. 26, 366–371.CrossRefGoogle Scholar
Hagin, J. and Bodman, G. V. (1954) Influence of the poly-electrolyte CRD-186 on aggregation and other physical properties of some California and Israeli soils and some clay minerals: Soil Sci. 78, 367–378.CrossRefGoogle Scholar
Harris, R. F., Allen, O. N., Chesters, G. and Attoe, O. J. (1963) Evaluation of microbial activity in soil aggregate stabilization and degradation by the use of artificial aggregates: Soil Sci. Soc. Am. Proc. 27, 542–546.CrossRefGoogle Scholar
Hedrick, R. M. and Mowry, D. T. (1952) Effect of synthetic polyelectrolytes on aggregation, aeration and water relations of soils: Soil Sci. 73, 427–441.CrossRefGoogle Scholar
Holmes, R. M. and Toth, S. J. (1957) Physico-chemical behavior of clay-conditioner complexes: Soil Sci. 84, 479–487.CrossRefGoogle Scholar
Ingles, O. G. (1968) Advances in soil stabilization (1961-67): Rev. Pure Appl. Chem. 18, 291–310.Google Scholar
Jordan, J. W. (1961) Organophilic clay-base thickeners: Clays and Clay Minerals 10, 299–308.Google Scholar
Kiselev, A. V., Lygin, V. I., Solomonova, I. N., Usmanova, D. O. and Eltekov, Y. A. (1968) Influence of the surface chemistry of adsorbents and fillers on adsorption of polymers: Kolloidn. Zh. 30. 386392.Google Scholar
Lamb, T. W. and Michaels, A. S. (1954) Altering soil properties with chemicals: Chem. Engng News 32, 488–492.CrossRefGoogle Scholar
LaMer, V. K. and Healy, T. W. (1963) Adsorption-flocculation reactions of macromolecules at the solidliquid interface : Rev. Pure Appi Chem. 13, 112–133.Google Scholar
LaMer, V. K. and Smellie, R. H. (1960) Theory of flocculation, subsidence and refiltration rates of colloidal dispersions flocculated by polyelectrolytes: Clays and Clay Minerals 9, 295–314.Google Scholar
Michaels, A. S. (1954) Aggregation of clay suspensions by polyelectrolytes: Ind. Eng. Chem. 46, 1485–1490.CrossRefGoogle Scholar
Michaels, A. S. and Morelos, O. (1955) Polyelectrolyte adsorption by kaolinite: Ind. Eng. Chem. 47, 18011809.CrossRefGoogle Scholar
Mortensen, J. L. (1960) Adsorption of hydrolyzed poly-acrylonitrile on kaolinite: Clays and Clay Minerals 9, 530–545.Google Scholar
Murray, H. H. (1961) Industrial applications of kaolin: Clays and Clay Minerals 10, 291–298.Google Scholar
Mussell, D. R. and Roth, H. H. (1957) Method and composition for the improvement of soil structure: U.S. Pat. 2, 778, 809.Google Scholar
Nahin, P. G. (1961) Perspectives in applied organo-clay chemistry: Clays and Clay Minerals 10, 257–271.Google Scholar
Nahin, P. G. (1964) Organo-clays bonded to polyethylene by ionizing radiation: Clays and Clay Minerals 13, 317–330.Google Scholar
Nahin, P. G. and Backlund, P. S. (1963) Organoclay-polyolefin compositions: U.S. Pat. 3, 084, 117.Google Scholar
Packter, A. (1957) Interaction of montmorillonite clays with polyelectrolyte: Soil Sci. 83, 335–342.CrossRefGoogle Scholar
Quirk, J. P. and Panabokke, C. R. (1962) Incipient failure of soil aggregates: J. Soil Sci. 13, 60–70.CrossRefGoogle Scholar
Ruehrwein, R. A. (1957) Chemical product: U.S. Pat. 2, 795, 567.Google Scholar
Ruehrwein, R. A. and Ward, D. W. (1952) Mechanism of clay aggregation by polyelectrolytes: Soil Sci. 73, 485–492.CrossRefGoogle Scholar
Schnitzer, M. and Kodarna, H. (1967) Reactions between a podzol fulvic acid and Na-montmorillonite: Soil Sci. Soc. Am. Proc. 31, 632–636.CrossRefGoogle Scholar
Showalter, W. E. (1966) Preparation of polyurethane foams containing an aluminum silicate filler: U.S. Put. 3, 227, 666.Google Scholar
Silberberg, A. (1962) The adsorption of flexible macro- molecules. Part I. The isolated macromolecule at a plane interface: J. Phys. Chem. 66, 1872–1883.CrossRefGoogle Scholar
Smith, D. A. (1968) Compounding elastomers with fillers. Part I: Rubber J. 38-40, 44.Google Scholar
Sołomko, V. P., Molokoyedova, T. A. and Uskov, I. A. (1966) Effect of fillers on the supramolecular structures and mechanical properties of crystalline polymers: Vysokomolekul. Soedin. 8, 104–108.Google Scholar
Solomon, D. H. (1968) Clay minerals as electron acceptors and/or electron donors in organic reactions: Clays and Clay Minerals 16, 31–39.CrossRefGoogle Scholar
Solomon, D. H. and Loft, B. C. (1968) Reactions catalyzed by minerals. III. The mechanism of spontaneous interlamellar polymerizations in aluminosilicates: J. Appl. Polymer Sci. 12, 1253–1262.CrossRefGoogle Scholar
Solomon, D. H. and Rosser, M. J. (1965) Reactions catalyzed by minerals. I. Polymerization of styrene: J. Appl. Polymer Sci. 9, 1261–1271.CrossRefGoogle Scholar
Suito, E. and Arakawa, M. (1964) Mechanism of reinforcement of rubber with hard clay. Infrared studies of rubber-filler systems: Bull. Inst. Chem. Res., Kyoto Univ. 42, 105–114.Google Scholar
Tarasenko, Yu. G., Uskov, I. A. and Sołomko, V. P. (1964) The effect of kaolin on the properties of polymethyl methacrylate and polystyrene: Ukr. Khim. Zh. 30, 86–90.Google Scholar
Theng, B. K. G., Greenland, D. J. and Quirk, J. P. (1967) The swelling in water of complexes of montmorillonite with polyvinyl alcohol: Aust. J. Soil Res. S, 69–75.CrossRefGoogle Scholar
Theng, B. K. G. and Walker, G. F. (1970) Interactions of clay minerals with organic monomers: Israel J. Chem. In press.CrossRefGoogle Scholar
Theng, B. K. G., Walker, G. F. and Ingles, O. G. (1969) Unpublished results.Google Scholar
Uskov, I. A. (1960a) Filled polymers. I. The filling of polymethyl methacrylate with aminated bentonite added directly to the monomer: Vysokomolekul. Soedin. 2, 200–204.Google Scholar
Uskov, I. A. (1960b) Filled polymers. III. Polymerization of polymethyl methacrylate during dispersion of sodium bentonite: Vysokomolekul. Soedin. 2. 926930.Google Scholar
Uskov, I. A., Galinskaya, V. I. and Artyukh, L. V. (1966) Calorimetric method of determining the interaction energy of polymers with fillers: Vysokomolekul. Soedin. 8, 1853.Google Scholar
Uskvo, I. A. and Kusnitsyna, T. A. (1960) Effect of dispersing aminated bentonite in monomer medium on reinforcement of polymethyl methacrylate: Vysokomol. Soedin. 2, 728–730.Google Scholar
Uskov, I. A., Tarasenko, Yu. G. and Sołomko, V. P. (1964) Effect of the degree of dispersion of clay fillers on the properties of amorphous polymers: Vysokomolekul. Soedin. 6, 1768–1772.Google Scholar
Uskov, I. A., Tarasenko, Yu. G., Surovtsev, V. I. and Solomko, V. P. (1963) Investigations of bentonite-filled polymethyl methacrylate and polystyrene: Vysokomolekul. Soedin. Adgeziya Polymerov Sb. Statei 31–34.Google Scholar
Van der Watt, H. V. H. and Bodman, G. B. (1960) Viscosimetric constants of suspensions of clay- polymer complexes: Clays and Clay Minerals, 9, 568–584.Google Scholar
Van Olphen, H. (1963) An Introduction to Clay Colloid Chemistry, Interscience, New York .Google Scholar
Walker, G. F. and Garrett, W. G. (1967) Silicate layer minerals and products made therefrom: U.S. Pat. 3, 356, 611.Google Scholar
Williams, B. G., Greenland, D. J. and Quirk, J. P. (1967) The tensile strength of soil cores containing polyvinyl alcohol: Aust. J. Soil Res. 5, 85–92.CrossRefGoogle Scholar
Williams, B. G., Greenland, D. J. and Quirk, J. P. (1968) The water-stability of natural clay aggregates containing polyvinyl alcohol: Aust. J. Soil Res. 6, 59–66.CrossRefGoogle Scholar