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Layer Charge and Interlamellar Expansion in a Muscovite

Published online by Cambridge University Press:  01 January 2024

Joe L. White*
Affiliation:
Purdue University, Lafayette, Indiana, USA

Abstract

Treatment of a muscovite (Delamica) with molten lithium nitrate produced a lowering of the layer charge on the mica. By gradual reduction of the density of surface charge the dependence of interlamellar expansion on the attainment of a critical value of about 6.7 × 104 e.s.u./cm2 was demonstrated in a straightforward manner.

Type
Article
Copyright
Copyright © Clay Minerals Society 1956

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Footnotes

Journal Paper no. 994, Purdue University Agricultural Experiment Station, Lafayette, Indiana.

References

Barshad, Isaac, 1950, The effect of the interlayer cations on the expansion of the mica type of crystal lattice: Amer. Min. v. 35, p. 225238.Google Scholar
Barshad, Isaac, 1952, Factors affecting the interlayer expansion of vermiculite and montmorillonite with organic substances: Soil Sci. Soc. Amer. Proc., v. 16, p. 176182.CrossRefGoogle Scholar
Barshad, Isaac, 1954, Cation exchange in micaceous minerals. II. Replaceability of ammonium and potassium from vermiculite, biotite, and montmorillonite: Soil Sci. v. 78, p. 5776.CrossRefGoogle Scholar
Brindley, G. W., and MacEwan, D. M. C., 1953, Structural aspects of the mineralogy of clays and related silicates: Ceramics, A Symposium, British Ceramic Society, p. 1559.Google Scholar
Brown, George, 1953, A semi-micro method for the preparation of soil clays for x-ray diffraction studies: J. Soil Sci., v. 4, p. 229232.CrossRefGoogle Scholar
Norrish, K., 1954, The swelling of montmorillonite: Faraday Soc. Discussion 18, p. 120134.CrossRefGoogle Scholar
Walker, G. F., and Milne, A., 1950, Hydration of vermiculite saturated with various cations: Trans. 4th Intern. Congr. Soil Sci., v. 2, p. 6267.Google Scholar
White, Joe L., 1956, Reactions of molten salts with layer-lattice silicates: in Clays and Clay Minerals, Nat. Acad. Sci—Nat. Res. Council pub. 456, p. 133146.Google Scholar