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Effect of Wetting Agents on the Deformation Behavior of Kaolinite-Water Systems

Published online by Cambridge University Press:  01 January 2024

W. C. Ormsby*
Affiliation:
Department of Ceramic Technology, The Pennsylvania State University, University Park, Pennsylvania, USA
R. M. Witucki*
Affiliation:
Department of Ceramic Technology, The Pennsylvania State University, University Park, Pennsylvania, USA
*
2Present address: National Bureau of Standards, Washington 25, D. C.
3Present address: Research and Development Division, Corning Glass Works, Corning, New York

Abstract

An experimental technique was developed for studying the deformation properties of kaolinite-water mixtures, and a study was made of the effects of different wetting agents on the deformation behavior of these mixtures. Particular care was taken to minimize physical effects that could be attributed to preferred orientation of clay particles. Evaluation of different compositions was made in terms of stress-strain diagrams obtained by means of a simple compression plastometer test. Auxiliary studies included sedimentation and filtration experiments of kaolinite-water mixtures containing wetting agents.

The various classes of wetting agents investigated, viz., anionic, cationic and nonionic wetting agents, were found to affect the deformability of clay-liquid mixtures independently of the surface tension of the liquid phase. As compared with water alone, cationic and nonionic reagents decreased and anionic reagents increased the deformability of clay-liquid mixtures.

In general, the sedimentation and filtration properties of kaolinite-water mixtures containing various wetting agents were consistent with the results of the deformation experiments.

Type
Article
Copyright
Copyright © The Clay Minerals Society 1955

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Footnotes

Contribution no. 55–45, College of Mineral Industries.

This paper comprises part of a thesis submitted by the senior author in partial fulfillment of the requirements for the degree of Doctor of Philosophy, Department of Ceramic Technology, The Pennsylvania State University, University Park, Pennsylvania (June, 1955).

4

Division of Mineral Technology, The Pennsylvania State University, USA

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