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Dielectrophoretic Behavior of Clay Minerals I. Dielectrophoretic Separation of Clay Mixtures

Published online by Cambridge University Press:  01 January 2024

R. B. McEuen*
Affiliation:
Pure Oil Research Center, Crystal Lake, Illinois, USA

Abstract

This paper describes a method and apparatus for separating clay particles according to their ability to store electrical energy. Separation is accomplished by opposing an electrical dielectrophoretic force by a mechanical centrifugal force. The apparatus used to create these forces consists of an axially rotating, fluid-filled cylinder in which a non-uniform electric field is maintained by means of radially disposed electrode vanes.

The behavior in this separator of illite, prochlorite, montmorillonite, halloysite, and kaolinite is reported. Observed differences in the dielectrophoretic force acting on these clays indicate that they can be separated one from another by this method.

The basic equations which govern the motion of particles in this separator are discussed. From these equations and known electrical properties of clays it is concluded that the large dielectrophoretic force which acts on a clay particle must have its primary origin in an interaction between the non-uniform electric field and induced ionic space-charge which presumably is created in the particle’s interlayer regions and in the loosely associated external surface layer.

Type
General
Copyright
Copyright © The Clay Minerals Society 1963

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Footnotes

Published by permission of The Pure Oil Company.

References

Bairsto, G. E. (1920) On the variation with frequency of the conductivity and dielectric constant of dielectrics for high-frequency oscillations: Proc. Roy. Soc., v. 96, pp. 363382.Google Scholar
Kao, K. C. (1961) Some electromechanical effects on dielectrics: British Journal of Applied Physics, v. 12, pp. 629632.CrossRefGoogle Scholar
Macdonald, J. R. (1955) Note on theories of time-varying space-charge polarization: Journal of Chemical Physics, v. 23, pp. 23082309.CrossRefGoogle Scholar
Mueller, Hans (1941) Electro-optical field mapping: Journal of the Optical Society of America, v. 31, pp. 286291.CrossRefGoogle Scholar
O'Konski, C. T. (1960) Electric properties of macromolecules. V. Theory of ionic polarization in polyelectrolytes: Journal of Physical Chemistry, v. 64, pp. 605619.Google Scholar
Overbeck, J. Th. G. (1962) Electrokinetic phenomena: Chapter 5 “Colloid Science” Kruyt, H. R., editor, New York, Elsevier Publishing Company, 236 pp.Google Scholar
Pohl, E. A. (1958) Some effects of non-uniform fields on dielectrics: Journal of Applied Physics, v. 29, No. 8, pp. 11821188.CrossRefGoogle Scholar
Pohl, E. A., (1960) Non-uniform field effects in poorly conducting media: Journal of the Electrochemical Society, v. l07, pp. 386390.CrossRefGoogle Scholar
Pohl, E. A., and Schwar, J. P. (1960) Particle separations by non-uniform electric, fields in liquid dielectrics, batch methods: Journal of the Electrochemical Society, v. 107, pp. 383385.CrossRefGoogle Scholar
Pohl, E. A., and Plymale, C. E. (1960) Continuous separations of suspensions by nonuniform electric fields in liquid dielectrics: Journal of the Electrochemical Society, v. 107, pp. 390396.CrossRefGoogle Scholar
Sillars, V. A. (1937) The properties of a dielectric containing semi-conducting particles of various shapes: J. Inst. Elec. Engrs. (London), v. 80, pp. 378394.Google Scholar
Van Olphen, H., and Waxman, M. H. (1958) Surface conductance of sodium bentonite in water: Clays and Clay Minerals, Nat. Acad. of Sci.—Natl. Research Council, publ. 566, pp. 6180.Google Scholar
Von Hippie, A. R., editor (1954) Dielectric material and applications. New York, John Wiley, 313 pp.Google Scholar
Warshaw, C. M., and Roy, R. (1959) The classification and a scheme for identification of layer silicates: Contribution No. 59-40 (preliminary), College of Mineral Industries, The Penn. State Univ., Univ. Park, Pa., 72 pp.Google Scholar