Hostname: page-component-77c89778f8-gvh9x Total loading time: 0 Render date: 2024-07-18T20:21:57.204Z Has data issue: false hasContentIssue false

Clay Minerals Research at Ghent University

Published online by Cambridge University Press:  01 January 2024

W. Dekeyser*
Affiliation:
The University, Ghent, Belgium

Abstract

This contribution reviews the work done at Ghent University, together with some unpublished recent work. Next to the survey of clay minerals from soil samples for the soil mapping organization, the group has been concerned with the polytypism of micas, the alteration and transformation of clay minerals, and the role of migration of iron in mica-type structures under influence of temperature or chemical treatment. A study of growth spirals of biotite crystals threw some light on the origin and possibility of the existence of ordered sequences with great repeat distances, and also on the complexity of crystals of this type. The presence of dislocations in mica is also shown by examination of “bending figures” produced by indentation. A study of clay minerais in soil fractions from a limited area, reclaimed from the sea between the eleventh and nineteenth centuries, indicated great variation in mineral composition. If one accepts the logical working hypothesis that the mineral composition was homogeneously distributed at the start, one must accept a rapid transformation at particular spots. This evolution seems to proceed from muscovite (illite) toward montmorillo-nite. Neoformation of a small quantity of kaolinite accompanies the transformation to mont-morillonite.

Experiments carried out to achieve this process in the laboratory showed that micas submitted to a stream of CO2 dissolve rather rapidly in presence of water. All attempts to obtain clay minerals from the obtained solutions failed, except one, when small quantities of mont-morillonite and kaolinite were formed. The thermal evolution of glauconite and the location of iron ions were also studied. Some remarks on formulas of clay minerals are presented.

Type
Article
Copyright
Copyright © The Clay Minerals Society 1955

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

Amelinckx, S., and Dekeyser, W., 1952, Le polytypisine des minéraux micacés et argileux. I. Observations et leurs interprétations: Comm. Int. Congress Geology, C.I.P.E.A., v. 1.Google Scholar
Amelinckx, S., and Dekeyser, W., 1955, Le polytypisme des minéraux micacés et argileux: Compte Rendu de Recherches, no. 14 (C.R.R.), Chap. 2, p. 47; ed. by I.R.S.I.A., 53, rue de la Concorde, Brussels.Google Scholar
Baumhauer, H., 1915, Über die verschiedenen Modifikationen des Carborundums und die Erschienung der Polytypie: Z. Krist., v. 55, p. 249.Google Scholar
Dekeyser, W., and Amelinckx, S., 1955, Les dislocations et la croissance des cristaux: Masson, Paris, p. 168.Google Scholar
Dekeyser, W., Hoebeke, F., and Van Keymeulen, J., 1955, Les minéraux argileux des polders et de quelques autres régions naturelles: Compte Rendu de Recherches, no. 14 (C.R.R.), Chap. 6, p. 123.Google Scholar
Dekeyser, W., Van Keymeulen, J., Hoebeke, F., and Van Ryssen, A., 1955, L'altération et révolution des minéraux micacés et argileux: Compte Rendu de Recherches, no. 14 (C.R.R.), Chap. 4, p. 91.Google Scholar
Frank, F. C., 1949, The influence of dislocations on crystal growth: Faraday Soc. Trans., v. 5, p. 48.CrossRefGoogle Scholar
Hendricks, S. B., and Jefferson, M. E., 1939, Polymorphism of the micas with optical measurements: Amer. Min., v. 24, p. 729771.Google Scholar
Hoebeke, F., and Dekeyser, W., 1954, L'oxydation de la glauconite à basse temperature: C. R. (Paris), v. 238, p. 2171.Google Scholar
Hoebeke, F., and Dekeyser, W., 1955, La glauconite: Compte Rendu de Recherches, no. 14 (C.R.R.), Chap. 5.Google Scholar
Van Keymeulen, J., in press, L'altération des minéraux micacés par l'acide carbonique.Google Scholar
Van Keymeulen, J., and Dekeyser, W., 1952, L'altération des minéraux micacés par l'acide carbonique: C. R. (Paris), v. 236, p. 1367.Google Scholar
Votava, E., Amelinckx, S., and Dekeyser, W., 1955, Indentation figures on single crystals: Acta Metallurgica, v. 3, p. 8994.CrossRefGoogle Scholar