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Solid-state intercalation of cationic surfactants into Tunisian smectites

Published online by Cambridge University Press:  09 July 2018

S. Gamoudi ,
N. Frini-Srasra  and
E. Srasra
S. Gamoudi*
Affiliation:
Laboratory of Physical Chemistry of Inorganic Materials and their Applications, National Center for Research in Materials Science, Tunisia
N. Frini-Srasra
Affiliation:
Department of Chemistry, Faculty of Sciences, University of El Manar, Tunisia
E. Srasra
Affiliation:
Laboratory of Physical Chemistry of Inorganic Materials and their Applications, National Center for Research in Materials Science, Tunisia
*
*E-mail: safagamoudi@gmail.com
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Abstract

Intercalation of cationic surfactants hexadecylpyridinium (HDPy+) and hexadecyltrimethylammonium (HDTMA+) into the interlayer space of homoionic (Na-, Ca- and Zn-) smectites by solid-solid reactions was investigated. These reactions were complete within 15 min. Changes in the surface and structure of the smectites modified with different surfactants were characterized using XRD, FTIR and DSC. The intercalation of surfactant is controlled by the exchangeable cation of smectite and monofunctional ammonium cation type. HDPy+ and HDTMA+ surfactants were retained by Zn-exchanged smectite, suggesting important surface properties (CEC = 80 meq/100 g clay, SBET = 116.5 m2/g) and acid-base properties (point of zero proton charge PZC, density charge σH). HDPy cation loading was effective, suggesting that the aromatic polar group is favoured for intercalation. Comparing with original clay, modification with surfactants increased the basal spacings d001. Based on the d001 spacing of modified smectites, different configurations of surfactants within smectite interlayer were proposed as a function of surfactant concentration, which were examined by FTIR and DSC.

Keywords

intercalationsmectitecationic surfactantsolid-state reaction
Type
Research Article
Information
Clay Minerals , Volume 48 , Issue 4 , September 2013 , pp. 583 - 593
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 2013

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References

Baldassari, S., Komarneni, S., Mariani, E. & Villa, C. (2006) Microwave versus conventional preparation of organoclays from natural and synthetic clays. Applied Clay Science, 31, 134–141.CrossRefGoogle Scholar
Bergaya, F. & Vaper, M. (1997) CEC of clays: Measurement by adsorption of a copper ethylenediamine complex. Applied Clay Science, 12, 275–280.Google Scholar
Bors, J., Dultz, St. & Riebe, B. (1999) Retention of radionuclides by organophilic bentonites. Engineering Geology, 54, 195–206.CrossRefGoogle Scholar
Bors, J., Patzko, A. & Dekany, I. (2001) Adsorption behavior of radioiodides in hexadecyl-pyridinium –humate complexes. Applied Clay Science, 19, 27–37.Google Scholar
Brigatti, M.F., Corradini, F., Franchini, G., Pacchioni, M. G. & Poppi, L. (1994) Interaction of exchanged Zn2+-montmorillonite with alkaline and earth alkaline cations. Applied Clay Science, 9, 121–128.Google Scholar
Bujdák, J. & Slosiariková, H. (1992) The reaction of montmorillonite with octadecylamine in solid and melted state. Applied Clay Science, 7, 263–269.Google Scholar
Caglar, B., Afsin, B., Tabak, A. & Eren, E. (2009) Characterization of the cation-exchanged bentonites by XRPD, ATR, DTA/TG analyses and BET measurement. Chemistry Engineering Journal, 149, 242–248.Google Scholar
Duc, M., Gaboriaud, F. & Thomas, F. J. (2005) Sensitivity of the acid–base properties of clays to the methods of preparation and measurement 2. Evidence from continuous potentiometric titrations. Colloid and Interface Science, 289, 148–156.Google Scholar
Dultz, S., Riebe, B. & Bunnenberg, C. (2005) Temperature effects on iodine adsorption on organo-clay minerals II. Structural effects. Applied Clay Science, 28, 17–30.Google Scholar
El-Nahhal, Z. & Safi, M. (2004) Adsorption of phenanthrene on organoclays from distilled and saline water. Journal of Colloid and Interface Science, 269, 265–273.Google Scholar
Han Ko, C., Fan, C., Chiang, P., Wang, M. & Lin, K. (2007) p-Nitrophenol, phenol and aniline sorption by organo-clays. Journal of Hazardous Materials, 149, 275–282.Google Scholar
He, H., Frost, R. L. & Zhu, J. (2004) Infrared study of HDTMA+ intercalated montmorillonite. Spectrochimica Acta Part A, 60, 2853–2859.Google Scholar
He, H., Yang, D., Yuan, P. & Frost, R. L. (2006a) A novel organoclay with antibacterial activity prepared from montmorillonite and Chlorhexidini Acetas. Journal of Colloid and Interface Science, 297, 235–243.CrossRefGoogle ScholarPubMed
He, H., Zhou, Q., Martens, W.N., Kloprogge, T.J., Yuan, P., Xi, Y.F., Zhu, J. X. & Frost, R. L. (2006b) Microstructure of HDTMA+-modified montmorillonite and its influence on sorption characteristics. Clays and Clay Minerals, 54, 689–696.Google Scholar
He, H.P., Frost, R.L., Bostrom, T., Yuan, P., Duong, L., Yang, D., Xi, Y. F. & Kloprogge, T. J. (2006c) Changes in the morphology with HDTMA+ surfactant loading. Applied Clay Science, 31, 262–271.Google Scholar
Heinz, H., Vaia, R.A., Krishnamoorti, R. & Farmer, B. L. (2007) Self-assembly of alkylammonium chains on montmorillonite: effect of chain length, head group structure, and cation exchange capacity. Chemistry of Materials, 19, 59–68.Google Scholar
Huertas, F., Chou, L. & Wollaster, R. (1998) Mechanism of kaolinite dissolution at room temperature and pressure: Part I. Surface speciation. Geochimica et Cosmochimica Acta, 62, 417–431.Google Scholar
Ijdo, W. L. & Pinnavaia, T. J. (1998) Staging of organic and inorganic gallery cations in layered silicate heterostructures. Journal of Solid-State Chemistry, 139, 281–289.Google Scholar
Ikhsan, J., Wells, J.D., Johnson, B. B. & Angove, M. J. (2005) Surface complexation modeling of the sorption of Zn(II) by montmorillonite. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 252, 33–41.Google Scholar
Khaorapapong, N. & Ogawa, M. (2007) Solid-state intercalation of 8-Hydroxyquinoline into Li(I)-, Zn(II)- and Mn(II)-montmorillonites. Applied Clay Science, 35, 31–38.Google Scholar
Khaorapapong, N. & Ogawa, M. (2008) In situ formation of bis(8-hydroxyquinoline) zinc(II) complex in the interlayer spaces of smectites by solid-solid reactions. Journal of Physics and Chemistry of Solids, 69, 941–948.Google Scholar
Kriaa, A., Hamdi, N. & Srasra, E. (2007) Acid-base chemistry of montmorillonitic and beidellitic-montmorillonitic smectite. Russian Journal of Electrochemistry. 43, 167–177.Google Scholar
Lazar, K., Pál-Borbély, G., Beyer, H. K. & Karge, H. G. (1994) Solid-state ion exchange in zeolites. Journal of the Chemical Society, Faraday Transactions, 90, 1329–1334.Google Scholar
Lee, S. Y. & Kim, S. J. (2002) Expansion characteristics of organoclay as a precursor to nanocomposites. Colloids and Surfaces A, 211, 19–26.Google Scholar
Li, Z. & Gallus, L. (2005) Effect of surfactant agent upon the structure of montmorillonite : X-ray diffraction and thermal analysis. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 264, 61–67.Google Scholar
Liu, X. & Wu, Q. (2001) PP/clay nanocomposites prepared by grafting-melt intercalation, Polymer, 42, 10013–10019.Google Scholar
Noh, J. & Schwarz, J. A. (1989) Estimation of the point of zero charge of simple oxides by mass titration. Journal of Colloid and Interface Science, 130, 157–164.Google Scholar
Ogawa, M. & Kuroda, K. (1995) Photofunctions of intercalation compounds. Chemical Reviews, 95, 399–438.Google Scholar
Ogawa, M. & Kuroda, K. (1997) Preparation of inorganicorganic nanocomposites through intercalation of organoammonium ions into layered silicates. Bulletin of the Chemical Society of Japan, 70, 2593–2618.Google Scholar
Ogawa, M., Handa, T., Kuroda, K. & Kato, C. (1990a) Formation of organoammonium-montmorillonites by solid-solid reactions. Chemistry Letters, 19, 71–76.Google Scholar
Ogawa, M., Kato, K., Kuroda, K. & Kato, C. (1990b) Preparation of montmorillonite-alkylamine intercalation compounds by solid-solid reactions. Clay Science, 8, 31–36.Google Scholar
Patil, O., Curtin, D. Y. & Paul, I. C. (1984) Solid-state formation of quinhydrones from their components. Use of solid-solid reactions to prepare compounds not accessible from solution. Journal of American Chemical Society, 106, 348–353.Google Scholar
Rastogi, R.P., Singh, N. B. & Singh, R. P. (1977) Organic solid-state reactions. Journal of Solid-State Chemistry, 20, 191–200.Google Scholar
Reynolds, P. C. & Hower, J. (1970) The nature of interlayering in mixed-layer illite-montmorillonites. Clays and Clay Minerals, 18, 25–36.Google Scholar
Rutherford, D.W., Chiou, C. Y. & Eberl, D. D. (1997) Effects of exchanged cation on the mocroporosity of montmorillonite. Clays and Clay Minerals, 45, 534–543.Google Scholar
Schroth, B. K. & Sposito, G. (1997) Surface charge properties of kaolinite, Clays and Clay Minerals, 45, 85–91.CrossRefGoogle Scholar
Shen, Y. H. (2001) Preparations of organo-bentonite using nonionic surfactants. Chemosphere, 44, 989–995.Google Scholar
Shi, Q., Tan, S., Yang, Q., Jiao, Z., Ouyang, Y. & Chen, Y. (2010) Preparation and characterization of antibacterial Zn2-exchanged montmorillonites. Journal of Wuhan University of Technology – Mat. Sci. Ed., 25, 725–729.Google Scholar
Stein, A., Keller, S. W. & Mallouk, T. E. (1993) Turning down the heat: design and mechanism in solid-state synthesis. Science, 259, 1558.Google Scholar
Tang, Y., Hu, Y., Song, L., Gui, Z., Chen, Z. & Fan, W. (2003) Preparation and thermal stability of polypropylene/ montmorillonite nanocomposites. Polymer Degradation and Stability, 82, 127–131.Google Scholar
Toda, F., Tanaka, K. & Sekikawa, A. (1987) Host-guest complex formation by a solid-solid reaction. Journal of the Chemical Society, Chemical Communications, 4, 279–280.Google Scholar
Van Olphen, H. (1963) An Introduction to Clay Colloïd Chemistry. Interscience Publishers, New York, London.Google Scholar
Wang, C.C., Juang, L.C., Lee, C.K., Hsu, T.C., Lee, J. F. & Chao, H. P. (2004) Effects of exchanged surfactant cations on the pore structure and adsorption characteristics of montmorillonite. Journal of Colloid and Interface Science, 280, 27–35.Google Scholar
Xi, Y.F., Martens, W., He, H. P. & Frost, R. L. (2005) Thermogravimetric analysis of organoclays intercalated with the surfactant octadecyltrimethylammonium bromide. Journal of Thermal Analysis and Calorimetry, 81, 91–97.Google Scholar
Yilmaz, N. & Yapar, S. (2004) Adsorption properties of tetradecyl- and hexadecyltrimethylammonium bentonites. Applied Clay Science, 27, 223–228.Google Scholar
Yoshimoto, S., Ohashi, F. & Kameyama, T. (2005) X-ray diffraction studies of intercalation compounds prepared from aniline salts and montmorillonite by a mechanochemical processing. Solid State Communitions, 136, 251–256.Google Scholar
Zhou, Q., Frost, R.L., He, H. & Xi, Y. (2007) Changes in the surfaces of adsorbed para-nitrophenol on HDTMA organoclay – the XRD and TG study. Journal of Colloid and Interface Science, 307, 50–55.Google Scholar
Zhu, L. Z. & Chen, B. L. (2000) Sorption behavior of pnitrophenol on the interface between anion-cation organobentonite and water. Environmental Science and Technology, 34, 2997–3002.Google Scholar
Zidelkheir, B. & Abdelgoad, M. (2008) Effect of surfactant agent upon the structure of montmorillonite: X-ray diffraction and thermal analysis. Journal of Thermal Analysis and Calorimetry, 94, 181–187.CrossRefGoogle Scholar