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Novel nuclear magnetic resonance techniques for the study of quadrupolar nuclei in clays and other layered materials

Published online by Cambridge University Press:  09 July 2018

J . Rocha ,
C. M. Morais  and
C. Fernandez
J . Rocha*
Affiliation:
Department of Chemistry, CICECO, University of Aveiro, 3810-193 Aveiro, Portugal
C. M. Morais
Affiliation:
Department of Chemistry, CICECO, University of Aveiro, 3810-193 Aveiro, Portugal Laboratoire Catalyse et Spectrochimie (CNRS UMR 6506), ENSICAEN, 14050 Caen, France
C. Fernandez
Affiliation:
Laboratoire Catalyse et Spectrochimie (CNRS UMR 6506), ENSICAEN, 14050 Caen, France
*
*E-mail: rocha@dq.ua.pt
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Abstract

The main developments taking place in Nuclear Magnetic Resonance Spectroscopy (NMR) of quadrupolar (spin I > 1/2) nuclei with half integer spins in solids, particularly clays and other layered materials, have been reviewed. The advent of Multiple-Quantum (MQ) Magic-Angle Spinning (MAS) NMR spectroscopy has been a step-change development to the studies of quadrupolar nuclei in solids. It is now possible to record high-resolution spectra of important nuclei, such as 11B, 17O, 23Na, 27Al and 69,71Ga, in synthetic and natural clays. Since its introduction in 1995 MQMAS NMR has evolved considerably and, at present, a range of very useful related techniques are available and have been reviewed, as has the current situation with regard to applications to clays and other layered materials.

Keywords

nuclear magnetic resonance spectroscopyquadrupolar nucleiclayradio-frequency radiationSTMASMQMAS
Type
Research Article
Information
Clay Minerals , Volume 38 , Issue 3 , September 2003 , pp. 259 - 278
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 2003

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