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Modelling, kinetics and equilibrium studies of crystal violet adsorption on modified montmorillonite by sodium dodecyl sulfate and hyamine surfactants

Published online by Cambridge University Press:  11 May 2021

Malihe Sarabadan ,
Hadis Bashiri Open the ORCID record for Hadis Bashiri [Opens in a new window]  and
Seyed Mahdi Mousavi
Malihe Sarabadan
Affiliation:
Department of Physical Chemistry, Faculty of Chemistry, University of Kashan, Kashan, Iran
Hadis Bashiri*
Affiliation:
Department of Physical Chemistry, Faculty of Chemistry, University of Kashan, Kashan, Iran
Seyed Mahdi Mousavi
Affiliation:
Department of Applied Chemistry, Faculty of Chemistry, University of Kashan, Kashan, Iran
*
*Email: hbashiri@kashanu.ac.ir
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Abstract

Two novel adsorbents – montmorillonite (Mnt)-hyamine and Mnt-hyamine-sodium dodecyl sulfate (SDS) – were synthesized using Mnt nanoparticles. The modified Mnt and Mnt nanoparticles were used for the removal of crystal violet from water, and they were characterized using various techniques. The effects of pH, time, temperature, adsorbent dosage and initial dye concentration on the dye-removal efficiency were investigated using response surface methodology. The optimum conditions for maximum dye removal were obtained. The optimum conditions for crystal violet adsorption on Mnt-hyamine, Mnt-hyamine-SDS and Mnt nanoparticles are temperatures 25.00°C, 29.97°C and 27.28°C; pH values 9.00, 10.41 and 9.40; adsorbent dosages 1.00, 1.15 and 1.06 g L–1; and initial dye concentrations 30.00, 98.74 and 99.44 mg L–1, respectively. The adsorbent dosage is the most critical variable for dye removal. Temkin and Langmuir are the best isotherms for studying adsorption equilibria. In the kinetic study, the fractal-like integrated kinetic Langmuir model was the most appropriate model, and the thermodynamic parameters were also determined. The synthesized adsorbents could be easily separated from solution. The Mnt-hyamine-SDS adsorbent has a high adsorption capacity (690.69 mg g–1) for the removal of crystal violet.

Keywords

adsorptioncrystal violethyaminemodified montmorillonitemontmorillonite nanoparticlesresponse surface methodology
Type
Article
Information
Clay Minerals , Volume 56 , Issue 1 , March 2021 , pp. 16 - 27
Copyright
Copyright © The Author(s), 2021. Published by Cambridge University Press on behalf of The Mineralogical Society of Great Britain and Ireland

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Footnotes

Associate Editor: Miroslav Pospišil

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