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Effect of particle size on the flocculation behaviour of ultra-fine clays in salt solutions

Published online by Cambridge University Press:  09 July 2018

L. S. Kotlyar
Affiliation:
National Research Council of Canada, Institute for Chemical Process and Environmental Technology, Montreal Road Campus, Ottawa, Ontario, Canada KlA OR6
B. D. Sparks
Affiliation:
National Research Council of Canada, Institute for Chemical Process and Environmental Technology, Montreal Road Campus, Ottawa, Ontario, Canada KlA OR6
Y. LePage
Affiliation:
National Research Council of Canada, Institute for Chemical Process and Environmental Technology, Montreal Road Campus, Ottawa, Ontario, Canada KlA OR6
J. R. Woods
Affiliation:
National Research Council of Canada, Institute for Chemical Process and Environmental Technology, Montreal Road Campus, Ottawa, Ontario, Canada KlA OR6

Abstract

The Athabasca oil sands deposit in Alberta contains ~5 x 109 m3 of bitumen accessible by surface mining. During bitumen separation from the mined ore, ultra-fine (<300 nm) aluminosilicate clays only a few layers thick (U/F) are mobilized and become dispersed in the process water. In this water containing dissolved salts from natural deposits, U/F are capable of forming thixotropic gels. The consequence of this is the production of large volumes of mature fine tailings (MFT) with a high water holding capacity. For mine planning purposes, the objective of predicting and possibly mitigating MFT formation requires an understanding of the colloidal behaviour of U/F particles in salt solutions. In this work, photon correlation spectroscopy and the deuterium NMR method are used to provide an insight into the U/F floc formation process. These results are correlated with conventional analysis of settling data.

Type
Research Article
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 1998

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References

Kotlyar, L.S., Sparks, B.D. & Schutte, R. (1995) Role of bicarbonate ions in the stability of ultra-fines suspensions. Environmental Sci. Health, A30, 12771288.Google Scholar
Kotlyar, L.S., Sparks, B.D. & Schutte, R. (1996) Effect of salt concentration on aggregation of colloidal clays. Clays Clay Miner. 44, 121131.Google Scholar
Kotlyar, L.S., Sparks, B.D., Deslandes, Y. & Schutte, R. (1994) The role of biwetted colloidal solids in structure formation in oil sands fine tailings. Fuel Sci. Technology, 12, 923935.Google Scholar
Kotlyar, L.S., Sparks, B.D., Schutte, R. & Capes, C.E. (1992a) Gel forming attributes of colloidal solids from fine tailings, formed during extraction of bitumen from Athabasca oil sands by the Hot Water process. AOSTRA J. Res. 8, 5560.Google Scholar
Kotlyar, L.S., Deslandes, Y., Sparks, B.D., Kodama, H. & Schutte, R. (1993) Characterization of colloidal solids from Athabasca sludge. Clays Clay Miner. 41, 341345.Google Scholar
Kotlyar, L.S., Lynds, M.M., Sparks, B.D., Schutte, R. & Woods, J.R. (1992b) Colloidal solids from sludge. To Sludge Fundamentals Consortium, NRC Internal Report No. EC-1243-92S, Ottawa, Ontario, Canada.Google Scholar
Mandelbrot, B.B. (1982) The Fractal Geometry of Nature. Freeman, W.H., San Francisco.Google Scholar
Michaels, A.S. & Bolger, J.C. (1962) Settling rates and sediment volumes of flocculated kaolin suspensions. I&EC Fundamentals, 1, 2433.CrossRefGoogle Scholar
Richardson, J.F. & Zaki, W.N. (1954) Sedimentation and fluidization: Part I. Trans. lnst. Chem. Eng. 32, 3552.Google Scholar
Ripmeester, J.A., Kotlyar, L.S. & Sparks, B.D. (1993) 2H NMR and the sol-gel transition in suspensions of colloidal clays. Colloids Surfaces, 78, 57–63.Google Scholar
Tambo, N. (1991) Basic concepts and innovative turn of coagulation/flocculation. Water Supply, 9, 1–10.Google Scholar
vanOlphen, H. (1991) An Introduction to Clay Colloid Chemistry. Crieger Publishing Company, USA.Google Scholar
Weitz, D.A., Lin, M.Y. & Lindsay, H.M. (1991) Universality laws in coagulation. Chemometrics and Intelligent Laboratory Systems, 10, 133–140.Google Scholar