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The distribution of octahedral cations in the 2:1 layers of dioctahedral smectites studied by oblique-texture electron diffraction

  • S. I. Tsipursky (a1) and V. A. Drits (a1)

Abstract

Olique-texture electron diffraction examination of K-saturated dioctahedral smectites after 70–100 wetting-drying cycles allows the determination of cation distribution between trans and cis octahedra of the 2:1 layers. Studies of smectites with different compositions has revealed a wide variety of occupancies of the available octahedral sites.

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Bailey, S.W. (1966) The status of clay mineral structures. Clays Clay Miner. 14, 123.
Besson, G. (1980) Structure des smectites dioctahedrique, parametres conditionnant lesfautes d’ empilement desfeuillets. Thèse de Doctorat d'etat et Sciences Physiques, Orléans.
Besson, G. & Tchoubar, C. (1972) Détérmination du group de symmétrie du feuillet élémentaire de la beidellite. C.R. Acad. Sci. Paris 275, 633636.
Besson, G., de la Calle, C., Rautureau, M., Tchoubar, C, Tsipursky, S.I. & Drits, V.A. (1982) X-ray and electron diffraction study of the structure of the Garfield nontronite. Proc. Seventh Int. Clay Conf., Bologna and Pavia. 2940.
Bookin, A.S., Dainyak, L.G. & Drits, V.A. (1978) Interpretation of the Mössbauer spectra of layer silicates on the basis of the structural modelling. Phys. Chem. Miner. 3, 5859.
Bookin, A.S., Dainyak, L.G. & Drits, V.A. (1979) Interpretation of the Mössbauer spectra of Fe3+-containing layer silicates on the basis of the structural modelling. Pp. 2341 in: Cation Ordering in Structures of Minerals (L. I. Lapides, , editor). Nauka, Novosibirsk.
Boutouzova, G.Yu., Drits, V.A., Lisitsina, N.A. & Tsipursky, S.Y. (1979) The dynamics of the formation of clay minerals in ore-bearing sediments of the Atlantis II (Red Sea) (in Russian). Litologiya i poleznye iskopaemye 1,2042.
Dainyak, L.G. (1980) The interpretation of the Mössbauer spectra of some Fe3+ -containing silicates on the basis of structural modelling (in Russian). Thèsis, Geological Institute, Academy of Sciences, Moscow.
Donnay, G., Donnay, J.D.H. & Takeda, H. (1964) Trioctahedral one layer micas. II. Prediction of the structure from composition and cell dimension. Acta Cryst. 17, 13741377.
Drits, V.A. (1969) Some general remarks on the structure of trioctahedral micas. Proc. Int. Clay Conf, Tokyo, 5159.
Drits, V.A. (1975) Structural and crystal-chemical features of layer silicates. Pp. 3235 in: Crystal Chemistry of Minerals and Geological Problems (Kossovskaya, A. G., editor). Nauka, Moscow.
Drits, V.A. & Kossovskaya, A.G. (1980) Geological crystal chemistry of rock-forming dioctahedral smectites. Litologiya ipoleznye iskopayemye 1, 84112.
Glaeser, R. & Méring, J. (1954) Isothermes d'hydration des montmorillonites biioniques (Na,Ca). Clay Miner. Bull. 2, 188190.
Goodman, B.A., Russell, J.D. & Fraser, A.R. (1976) A Mössbauer and IR spectroscopic study of the structure of nontronite. Clays Clay Miner. 24, 5359.
Guggenheim, S. & Bailey, S.W. (1975) Refinement of the margarite structure in subgroup symmetry. Am. Miner. 60, 10231029.
Güven, N. (1971) The crystal structure of 2M phengite and 2M1-muskovite. Z. Krist. 134, 487490.
Güven, N., Pease, R.W. & Murr, L.E. (1977) Fine structure in the selected area electron diffraction patterns of beidellite. Clay Miner. 12, 6774.
Mamy, J. & Gaultier, J.P. (1976) Les phenomènes de diffraction de rayonnements X et électronique per les reseaux atomiques: application à l'étude de l'ordre cristalline dans les miréraux argileux. Ann. Agronomiques 27, 116.
Méring, J. & Glaeser, R. (1954) Sur le rôle de la valence de cations échangeables dans la montmorillonite. Bull. Soc. Fr. Miner. Crist. 77, 519522.
Méring, J. & Oberlin, A. (1971) Smectite. Pp. 193229 in: The Electron-Optical Investigation ofClays (Card, J. A., editor). Mineralogical Society, London.
Radoslovich, E.W. & Norrish, K. (1962) The cell dimensions and symmetry of layer-lattice silicates. I. Some structural considerations. Am. Miner. 47, 599616.
Radoslovich, E.W. & Burnham, C.W. (1964) Crystal structure of coexisting muscovite 2M1 and paragonite 2M1 . Carnegie Inst. Year Book 63, 232234.
Rozenson, I & Heller-Kallai, I. (1977) Mössbauer spectra of dioctahedral smectites. Clays Clay Miner. 25, 94101.
Tsipursky, S.I. & Drits, V.A. (1977) Effectiveness of the electronometric method of measuring the intensities at the electron diffraction structural studies. Izv. AN SSSR, Series Phys. 22632271.
Tsipursky, S.I., Drits, V.A. & Chekin, S.S. (1978) Revealing of the structural ordering of nontronites by oblique texture electron diffraction. Izv. AN SSSR, Ser. geol. 10, 105113.
Zvyagin, B.B. & Pinsker, Z.G. (1949) Electron diffraction study of the montmorillonite structure. Dokl. Acad. Nauk SSSR. 68, 3035.
Zvyagin, B.B. (1967) Electron Diffraction Analysis of Clay Mineral Structures. Plenum Press, New York.
Zvyagin, B.B., Vrublevskaya, Z.V., Zhoukhlistov, A.P., Sidorenko, O.V., Soboleva, S.V. & Fedotov, A.F. (1979) In: High Voltage Electron Diffraction Study of Layer Minerals (Drits, V. A., editor). Nauka, Moscow.

The distribution of octahedral cations in the 2:1 layers of dioctahedral smectites studied by oblique-texture electron diffraction

  • S. I. Tsipursky (a1) and V. A. Drits (a1)

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