Hostname: page-component-77c89778f8-n9wrp Total loading time: 0 Render date: 2024-07-19T16:01:34.384Z Has data issue: false hasContentIssue false

Clay-organic studies

XI. Complexes of benzene, pyridine, and piperidine 1,3-substituted propanes with a synthetic Ca-fluorhectorite

Published online by Cambridge University Press:  09 July 2018

G. W. Brindley
Affiliation:
Materials Research Laboratory, and Department of Geochemistry and Mineralogy, Tile Pennsylvania State University, University Park, Pa., U.S.A.
T. D. Thompson
Affiliation:
Materials Research Laboratory, and Department of Geochemistry and Mineralogy, Tile Pennsylvania State University, University Park, Pa., U.S.A.

Abstract

Complexes are formed between a Ca-saturated fluorhectorite and organic molecules derived from propane by substituting benzene, pyridine, and piperidine rings in the 1,3 positions. The complexes are mainly of the A- and B-types described earlier by Greene-Kelly. Only one of the substances studied forms long-spacing complexes; in this case, the organic molecule is terminated at one end by a benzene ring and at the other by an active =NH group. Neutral forms of this molecule develop double-layer complexes, cationic forms develop single-layer complexes. The results are consistent with data for alcohols, alkyl chlorides and bromides, and alkyl amines.

Type
Research Article
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 1966

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

Aragón, F., Cano-Ruiz, J. & Macewan, D.M.C. (1959) Nature, Lond. 183. 740.Google Scholar
Brindley, G.W. (1965) Clay Miner. 6, 91.CrossRefGoogle Scholar
Brindley, G.W. & Moll, W.F. JR. (1965) Am. Miner. 50, 1355.Google Scholar
Brindley, G.W. & Ray, S. (1964) Am. Miner. 49, 106.Google Scholar
Greene-Kelly, R. (1955a) Trans. Faraday Soc. 51, 412.Google Scholar
Greene-Kelly, R. (1955b) Trans. Faraday Soc. 51, 425.CrossRefGoogle Scholar
Greene-Kelly, R. (1956a) Trans. Faraday Soc. 52, 1281 Google Scholar
Greene-Kelly, R. (1956b) J. phys. Chem., Ithaca. 60, 808.CrossRefGoogle Scholar
Johnson, R.C. & Shell, H.R. (1963) U.S. Bur. Mines Rep. Invest. 6235.Google Scholar
Sutherland, H.H. & Macewan, D.M.C. (1961) Clay Miner. Bull. 4, 229.CrossRefGoogle Scholar
Thompson, T.D. (1965) M.S. thesis, Pennsylvania State University.Google Scholar