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X-Ray Spectroscopic Studies of Bonding in Iron Germanides

Published online by Cambridge University Press:  06 March 2019

E. Adelson  and
A. E. Austin
E. Adelson
Affiliation:
Battelle Memorial Institute, Columbus Laboratories, Columbus, Ohio
A. E. Austin
Affiliation:
Battelle Memorial Institute, Columbus Laboratories, Columbus, Ohio
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Abstract

X-ray emission spectra have been obtained with a single crystal spectrometer having a resolution λ/dλ of 6,640 for iron Kβ5 spectra. The spectrometer consisted of a Jarrel-Ash Microfocus unit in conjunction with a Picker diffractometer which was operated as a rocking crystal spectrometer with a stepping angle of 1/400th of a degree. Kβ5 and Kβ1,3 spectra have been obtained from iron, Fe0.9Mn0.9Ge, Fe1.60Ge, FeGe, FeGe2 and germanium. Because the K05 spectra are due to 4p - Is transitions from the 3d bands, the Kβ5 intensities are a direct measure of the overlap or hybridization of the 3d - 4s - 4p bands. The experimental results can be correlated either with orbitals derived on the basis of coordination, or more roughly with possible band distributions.

Type
Research Article
Information
Advances in X-Ray Analysis , Volume 12: Seventeenth Annual Conference on Applications of X-ray Analysis, August 21-23, 1968 , 1968 , pp. 506 - 517
Copyright
Copyright © International Centre for Diffraction Data 1968

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