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Certification of Reference Materials by Energy-Dispersive X-ray Fluorescence Spectrometry?

Published online by Cambridge University Press:  06 March 2019

Leif Højslet Christensen
Affiliation:
Isotope Division Risø National Laboratory DK-4000 Roskilde, Denmark
Kaj Heydorn
Affiliation:
Isotope Division Risø National Laboratory DK-4000 Roskilde, Denmark
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Abstract

The present paper studies the precision and accuracy that can be achieved using energy-dispersive x-ray fluorescence spectrometry for the determination of total sulphur content in BCR 38 Fly Ash issued by the European Community Bureau of Reference.

Type
V. Applications of XRF and XRD to Life Sciences and the Environment
Copyright
Copyright © International Centre for Diffraction Data 1984

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References

1. Taylor, J.K., “Quality Assurance of Chemical Measurements”, Anal, Chem., 53: 1 588A (1981).Google Scholar
2. Heydorn, K., “Detection of Systematic Errors by the Analysis of Precision”, Accuracy of Trace Analysis, National Bureau of Standards Special Publication 422:127 (1976).Google Scholar
3. Griepink, B., Colinet, E., Guzzi, G., Haemers, L., and Muntau, H., “Certification of Trace Elements Content (As, Cd, Co, Cu, Fe, Mn, Hg, Na, pb, and Zn) in a Fly Ash Obtained from the Combustion of Pulverized Coal”, Fresenius Z. Anal, Chem. 315:20 (1982).Google Scholar
4. Nielson, K.K., “Matrix Corrections for Energy - Dispersive X-ray Fluorescence Analysis of Environmental Samples with Coherent/Incoherent Scattered X-rays”, Anal. Chem. 49:641 (1977).Google Scholar
5. Christensen, L.H. and Drabgfc, I., “A Generalized Matrix Correction Approach for Energy - Dispersive X-ray Fluorescence Analysis of Paint using Fundamental Parameters and Scattered Silver Ka Peaks”, Adv. X-Ray Anal., 26:377 (1983).Google Scholar
6. Christensen, L.H. and Rasmussen, L., “EDXRF Determination of Major and Minor Elements in Campound Fertilizers”, Adv. X-Ray Anal. 28:XX (1985).Google Scholar
7. Heydorn, K. and Nesrgaard, K., “Analysis of Precision of Activation Analysis Results”, Talanta, 20:835 (1973).Google Scholar
8. Heydorn, K. and Lada, W., “Peak Boundary Selection in Photopeak Integration by the Method of Covell”, Anal. Chem., 44:2313 (1972).Google Scholar
9. Heydorn, K., “Quality Assurance of Computer Programs for Photopeak Integration in Activation Analysis”, Proc. Conf. Computers Act. Anal. γ-Ray Spectroscopy, 85 (1979), Department of Energy, Washington.Google Scholar