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25 - Batteries and electrochemistry

from Section VII - Energy sources

Published online by Cambridge University Press:  02 December 2010

Rahul Sarpeshkar
Affiliation:
Massachusetts Institute of Technology
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Summary

I have been so electrically occupied of late that I feel as if hungry for a little chemistry: but then the conviction crosses my mind that these things hang together under one law.

Michael Faraday

Ultra-low-power electronic systems often utilize batteries. The battery is frequently the heaviest and most critical portion of a portable system. The battery's size, weight, energy density, power density, form factor, cycling properties and lifetime can dictate constraints under which a portable electronic system must operate. Such constraints include the overall power dissipation of the system, the number of recharges that are possible in the system, the expected lifetime of the system, the overall size of the system, and the overall cost of the system. In this chapter, we shall provide a brief introduction to batteries with an emphasis on intuition and knowledge that is useful for providing insight into battery operation and ultra-low-power system design.

First, we shall begin with an exposition of the basic principles by which chemical energy is converted to electrical energy in a battery. Then, we shall discuss an equivalent circuit for a battery that intuitively describes several effects that are observed in practical batteries. We shall discuss the basics of lithium-ion and zinc-air batteries, two of the most common and most efficient batteries in existence in ultra-low-power electronic systems, particularly biomedical ones. We shall also briefly discuss the benefits of fuel cells and ultra capacitors, devices that are capable of being used in conjunction with or instead of batteries, and that are likely to be important in the future.

Type
Chapter
Information
Ultra Low Power Bioelectronics
Fundamentals, Biomedical Applications, and Bio-Inspired Systems
, pp. 789 - 821
Publisher: Cambridge University Press
Print publication year: 2010

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References

Linden, David and Reddy, Thomas B.. Handbook of Batteries, 3rd ed. (New York: McGraw-Hill, 2002).Google Scholar
Bard, Allen J. and Faulkner, Larry R.. Electrochemical Methods: Fundamentals and Applications, 2nd ed. (New York: Wiley, 2001).Google Scholar
Dearborn, S.. Charging Li-ion batteries for maximum run times. Power Electronics Technology Magazine, (2005), 40–49.Google Scholar
Chen, M. and Rincon-Mora, G. A.. Accurate, Compact, and Power-Efficient Li-Ion Battery Charger Circuit. IEEE Transactions on Circuits and Systems II: Express Briefs, 53 (2006), 1180–1184.CrossRefGoogle Scholar
Ragone, D. V.. Review of Battery Systems for Electrically Powered Vehicles. Mid-Year Meeting of the Society of Automotive Engineers, Detroit, Michigan, 1968.Google Scholar
,Lund Instrument Engineering Inc. Available from: www.powerstream.com.

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