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Recent developments on the use of the piezoelectric effect in ZnO nanorod-based p-n junctions for energy harvesting applications are presented. Two types of junctions are used. The first is a hybrid p-n device combining the semiconducting polymer poly(3,4-ethylene-dioxythiophene) poly(styrenesulfonate) (PEDOT:PSS) with ZnO nanorods. The second type of junction is an all-inorganic junction between n-type ZnO nanorods and p-type CuSCN. It is shown that both these diodes can be produced on flexible plastic substrates, which generate a voltage output when bent. The voltage output of the ZnO/PEDOT:PSS diodes are measured across a range of resistive loads while bending to find a maximum power point of 12 μWcm-2 at 4 kΩ. It is shown that a voltage output is also generated when this structure is vibrated acoustically. The ZnO/CuSCN diode is sensitized to sunlight with a Ru-based dye to form a photovoltaic device. It is shown that the device efficiency can be increased by application of acoustic vibrations. This is attributed to the electric field generated by the piezoelectric effect in ZnO affecting the charge-carrier recombination at the ZnO surface.
The basic story is well-known. Descartes goes looking for something absolutely certain, beyond even the slightest, most unreasonable doubt, to serve as the permanent foundation for his knowledge. He dismisses the propositions evidenced by his senses. The traditional skeptical worries about hallucinations, madness, dreams and deceiving gods convince him that there is no certainty there. He lands on a bedrock certainty capable of withstanding even his worries about a deceptive god: He exists.
But I have convinced myself that there is absolutely nothing in the world, no sky, no earth, no minds, no bodies. Does it now follow that I too do not exist? No: if I convinced myself of something then I certainly existed. But there is a deceiver of supreme power and cunning who is deliberately and constantly deceiving me; and let him deceive me as much as he can, he will never bring it about that I am nothing so long as I think that I am something. So after considering everything very thoroughly, I must finally conclude that this proposition, I am, I exist, is necessarily true whenever it is put forward by me or conceived in my mind.
(Second Meditation: AT VII 25: CSM II 16-17)
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