1. Introduction
Snow is a porous medium, and its internal microstructure (snow grain-size and shape, intergrain bond characteristics, pore structure) acts on its physical properties. This is typically the case for its mechanical properties (Reference Golubev and FrolovGolubev and Frolov, 1998). Most physical processes occurring inside snow are also strictly linked to its microstructure—dry- and wet-snow metamorphism (Reference ColbeckColbeck, 1983, Reference Colbeck1997)—and also its thermal properties (Reference Arons and ColbeckArons and Colbeck, 1995). The lack of snow microstructure observations restricts the investigation of snow properties. Therefore snow is considered in many studies as a simple medium like a packing of spherical ice particles. Classical observations such as sieving and photography of grains give quantitative data on grain-size and shape, but do not account for bond properties. Surface sections give more information on the two-dimensional (2-D) structure. The difficulty is then to derive three-dimensional (3-D) properties, especially for parameters which depend on connectivity. More recently, serial cuts have been performed on snow (Reference GoodGood, 1987; Reference Brzoska, Lesaffre, Coléou, Xu and PieritzBrzoska and others, 1999), but they are time-consuming and the ratio of the sample size to resolution is not really satisfactory (cube of 1283 voxels of 20 μm obtained from 64 section planes and the interpolation of one plane out of two in Reference Brzoska, Lesaffre, Coléou, Xu and PieritzBrzoska and others, 1999). An alternative way of obtaining information on snow texture is to infer it from other measurements. Information on the pore structure of snow can be deduced from air-permeability and capillary-rise measurements (Reference Jordan, Hardy, Perron and FiskJordan and others, 1999) or microstructural and micromechanical parameters using a penetrometer Reference Johnson and SchneebeliJohnson and Schneebeli, 1999). These methods provide bulk parameters linked to the microstructure but they do not describe the microstructure itself.
To visualize snow with high resolution, we used X-ray absorption tomography. The method developed to obtain the 3-D views of snow is described in section 2. In section 3, two important parameters for snow, porosity and local curvature, are calculated on four 3-D images from different snow samples. The results are then discussed in terms of sample size representativity
2. Methodology
2.1. X-ray tomography
The principle of X-ray absorption tomography is to reconstruct the spatial distribution of the linear attenuation coefficient within the object from X-ray projections recorded at different angular settings of the sample. Each element in the recorded projections corresponds to a line integral of the attenuation coefficient along the beam path. Via a standard reconstruction algorithm (filtered back-projection (Reference HermanHerman, 1980)) the 3-D distribution of the attenuation coefficient can be calculated by combining the information for the different angular positions. In our case, 900 projection images spanning 180° rotation around the vertical axis were recorded for each sample. The reconstructions were performed offline using a standard filtered back-projection software available at the European Synchrotron Radiation Facility (ESRF), Grenoble, France.
2.2. Experimental Set-Up
The experiments were carried out at the ID19 beamline of the ESRF. ID19 is devoted to high-resolution imaging, and features an energy-tunable, parallel X-ray beam of up to 14 mm × 40 mm cross-section (energy range 7–100 keV; divergence l μ rad). The cryostat was mounted on a precision-mechanics sample stage (rotation and translation; see Fig. 1), and the projections were recorded with a fast, high-resolution detector system. The latter consists of a powder phosphor screen which is coupled via light optics to a cooled 10242 charge coupled device (CCD) camera (Reference Labiche, Segura-Puchades, van Brussel and MoyLabiche, 1996). For this experiment an effective pixel size of 10 μm best met our needs to (a) resolve the shape of individual snow grains and (b) maintain a sufficiently large field of view to observe a statistically significant volume. Typical exposure times for a single radiograph in this configuration are in the order of Is, resulting in overall scan times of 15 min.
Fig. 1. Diagram of the microtomographic set-up used for snow.
2.3. Cryostat
X-ray microtomography is a well-established technique for visualizing completely diverse objects. The difficulty with our snow samples was to design a special cell able to prevent both melting and metamorphism of the snow sample during the experiment (i.e. for at least lh). Moreover, the device must not conceal the sample from the beam and must stand up to a 180° rotation. For this purpose, a refrigerated cell with cylindrical double walls was developed with the collaboration of the Laboratoire de Glaciologie et Geophysique de l’Environnement Grenoble, France (see Fig. 2). Liquid nitrogen was evaporated in the bottom of the sample holder, generating a cold and dry gas flow (T ∼ –100°C; dew-point temperature Td ≪–40°C), then brought around the Plexiglas sample holder, which ensures a sample temperature lower than –40°C Nitrogen gas was then passed inside the (gas-tight) bottom of the cell for gas warming up to (T∼+10°C; Td ≪ –40°C) and finally inside and outside the double shell; this prevented both dew outside, and rime inside. To ensure mechanical stability of the sample and to reduce thermal loss, the sample holder was laterally fastened to the cell using a 10 mm thick Bakelite plate.
Fig 2 Details of the cryostat. LN2 indicates liquid nitrogen, and GN2 gaseous nitrogen.
2.4. Sample preparation
A cubic sample of about 200 cm3 was cut from a snow layer. To prevent sublimation and grain damage during sample machining and handling, the snow texture was strengthened. The technique used was similar to that for thin sectioning (Reference GoodGood, 1987). The sample was soaked by pouring diethyl-orthophthalate (phthalate for short; melting point –5°C) at –4°C. After it was entirely frozen (6h at –20°C), a lump of about 3 cm3 was extracted and machined, at –20°C, into a cylinder 9 mm in diameter and 9 mm high. When filled with phthalate, the reconstructed images lacked sufficient contrast to allow automatic processing. Therefore phthalate was removed by rinsing the sample in an isooctane bath at –2°C. Isooctane was then drained from the sample by putting the core on blotting paper for 10 s, and finally quickly evaporated under vacuum. To prevent sublimation until the start of the X-ray experiments, the sample was put in a gas-tight cylindrical sample holder and stored in a cool box with CO2 dry ice.
2.5. Snow characteristics
Four different snow samples (see Fig. 3) were prepared as described above:
The sample “wet grains” consisted of well-rounded grains, class 6a according to the International Classification for Snow (Reference ColbeckColbeck and others, 1990). They were obtained by soaking a sieved snow sample in water at 0°C and then draining it. Their mean convex radius, computed from 2-D images of grains (Reference Lesaffre, Pougatch and MartinLesaffre and others, 1998), equaled 0.26 mm.
The sample “crust” was collected in the field, at Col de Porte, Chartreuse mountain, France. It consisted of a melt-freeze crust, class 9e, partially faceted. This snow layer was wetted by rain, frozen and then faceted under a large natural temperature gradient. Its mean 2-D convex radius of curvature was 0.25 mm.
The sample “partially faceted particles”, class 4b, resulted from decomposing particles collected in the field and stored at 20°C for 1 month, probably under a slight temperature gradient due to storage conditions. It was then sieved and warmed up to –5°C in 2 days. The mean 2-D convex radius was 0.16 mm.
The last sample,”depth hoar”, class 5a, was prepared like the previous one, then put into a special device which maintained a large temperature gradient (∼100°C m−1) for 8 days. Due to experimental problems, this gradient was not applied for the following 3 days. The grains obtained were dense depth hoar; their mean 2-D convex radius was 0.17 mm.
Fig. 3. 2-D views of some grains taken from the four snow samples. For each one, the mean 2-D convex radius of curvature was computed on gram contours from 20 views of this kind.
2.6. Image processing
Image analysis was performed using classical algorithm on a commercial software (Visilog from NOESIS). Figure 4a presents a view (600 × 600 pixels, 256 grey levels) extracted from one of the 1024 reconstructed planes. Each plane is processed into a binary image where ice is distinguished from pore phase. Since the grey-level images showed sufficient contrast, an automatic threshold using the histogram of the grey-level image was applied (Fig 4b). Some remaining artifacts due to both ill-rinsed phthalate and reconstruction procedure were removed as follows. A first image (Fig. 4c) resulted from an opening procedure, then an erosion of depth 1–3 pixels, depending on sample, was applied (Fig. 4d); the opened image was restored (Fig. 4e) starting from the eroded one as a marker and retrieving only the objects containing a marker. This procedure does not modify the grain’s contours but may remove objects whose smallest size is less than 6, 4 or 2 pixels. Finally, small holes inside grains were removed with a closing procedure (Fig. 4f). This may also modify details (maximum size 2 pixels) of the grain’s contours. When this process had run on every plane, the binary 3-D data file could be generated. The account for continuity along the z axis was achieved by applying an averaging filter (kernel 33, value 1) to the data and thresholding the resulting image to 0.5. Too isolated voxels from grain or pore phase were removed by this procedure. The final result was a smoothed image. The similarity of the binary image overlaid with the grey-level one was visually checked for each plane. The image processes mainly affected small details of the grain’s contours. They seemed to be acceptable, although the size of the objects is large compared to the size of the pixels. In our case, “grain-size” was about 0.3–0.5 mm and pixel size 0.01 mm.
Fig. 4. Steps of the processing of the grey-level image of one plane into a binary image. The erosion depth varies between 3 pixels for “wetgrains”and 1 for “depth hoar”.
3. Results
For the first time, 3-D images of snow at high resolution (10 μm) were obtained by X-ray tomography. Image processing was performed on cubes with an edge size of 6 mm, extracted from the cylindrical sample. Figure 5 shows the images obtained from the different snow samples. Each view represents only one-eighth of the volume of the entire processed image.
Fig. 5. Subsamples (3003 voxels) of the four 3-D smoothed binary images. According to the computed values of curvature, the convex parts are colored blue, the concave one red; color saturation varies with the absolute value of curvature.
3.1. Porosity
Porosity is the simplest descriptive parameter for snow, but the most important for many physical snow properties. Porosity P was determined on the discrete image by counting the voxels in the pore phase.
, where I is the value of the voxel in the image (1 for ice, 0 for pore), S is a chosen set of voxels, and Nv
is the number of voxels in S. For each snow sample, porosity was computed on several cubes extracted from the image. In Figure 6, each curve represents the evolution of porosity for one set of embedded cubes where cube size grows from 203 to 2503. The different curves correspond to various separated sets of cubes. When cube size increases, porosity moves towards the mean porosity of the sample at a rate depending on grain type. Whereas the mean porosity of “crust” was achieved with a 10% precision when the cube’s edge is 250 voxels, the same precision was achieved for “partially faceted particles” for much smaller sampling cubes. Grain-size may explain the differences between the snow samples. It is obvious that small grains require a smaller volume than large grains to show significant porosity.
Fig. 6. Evolution of the porosity vs the volume size for each sample. Each curve represents a distinct set of embedded cubes.
For the studied samples, picked out from homogeneous snow, the observed volume of 9 mm high and 9 mm in diameter is sufficient to reach the porosity. However, this would not be the case in less homogeneous snow (e.g. melt-freeze polycrystals where clusters have a size close to the sample size). Unfortunately, bulk density was not measured, so comparison of the computed porosity with macroscopic density was not possible.
3.2. Curvature
Curvature is a central parameter in snow metamorphism. Dry-snow evolution under low temperature gradient and wet-snow evolution are governed by local curvature. In the following the numerical method used for modeling local curvature on discrete images is described. Then the results are presented on the four snow samples, and the determination of the representative elementary volume is discussed. Finally the 3-D convex curvatures are compared with the 2-D one from grain’s contours.
Model
The aim was to obtain the local curvature on each point of the surface of the grains. The initial image is the binary image where the values ”1” represent ice and ”0” the pores. First of all, it is necessary to define the grain’s discrete surface. For every voxel of the object, its background distance is defined as the distance between this point and the closer one belonging to the pore phase. This background distance is computed using the chamfer distance with a kernel (3, 4, 5), i.e. the distance between two voxels in contact with their side, edge and vertex are 3, 4 and 5, respectively (Reference Chassery and MontanvertChassery and Montanvert, 1991). The set of voxels whose chamfer distance is 3 defines the grain’s surface.
A model has been developed recently for computing curvatures on discrete 3-D images (Reference Brzoska, Lesaffre, Coléou, Xu and PieritzBrzoska and others, 1999). Local curvature on a point P is defined as C = 1/2[(1/R 1) + (l/R 2)], where R 1 and R 2 are the radii of curvature computed on two planes orthogonal to each other and containing the normal vector to the surface. The definition of the normal vector provided in Reference Brzoska, Lesaffre, Coléou, Xu and PieritzBrzoska and others (1999) was based on the association between the voxel from the surface computation and the voxel in the medial axis. It could not be used for 6003 size images due to processing time. The principle of the new method developed for locating the normal vector is as follows. The discrete chamfer distance map is used to find a voxel N where (NP) is a vector normal to the surface on P. Inside a spherical neighborhood of radius rn = 5 voxels (with respect to Euclidean distance), N is chosen as the voxel with the maximum background distance. An improvement in the determination of the normal vector would be the optimization of rn according to the shape of the surface (a larger neighborhood if the surface is smooth, a shorter one if it is rough; this procedure is in development). However, the use of a fixed value of rn gives a precise enough positioning of the normal vector for the computation of the curvature, and it is convenient. In order to compare the two methods, curvature was computed on a cube of 1253 voxels, extracted from the sample “partially faceted particles”. The mean values of curvature were 5.11mm-1 for the method using the medial axis and 4.95 mm-1 for the “new” method. The correlation between the two series (121549 values of curvature) was 0.87. The curvature was computed using a new frame, referenced with the two orthogonal planes. Then the radii of curvature were computed by means of parabolic interpolation of the discrete curves, intersection between grain’s contour and the planes of reference.
Application for snow
Curvature was calculated from 3-D images of 6003 voxels, on each voxel of the grain’s surface, using the method described above. Figure 5 shows the result for the different snow types, the extracted image size being 3003 voxels. The convex parts are colored blue, the concave one red; color saturation varies with the absolute value of curvature. The plane zones of “crust” and “depth hoar” have pale colors. For “wet snow”, the red parts between the well-rounded grains indicate the place of the refrozen water menisci.
The results in Figure 7 show that the shape of the histogram of curvature is clearly different for each type of grain considered:
“crust” presents a peak in small values, due to the numerous flat zones on the grain’s surface;
“wet grains” presents a characteristic bulge in the negative value corresponding to the water menisci (capillary pressure), and a narrow maximum in the positive value;
“partially faceted particles” presents a rather symmetrical histogram centered on a positive value of curvature;
“depth hoar” was derived from the previous sample and then transformed under a large temperature gradient. The resulting histogram is distinctly shifted to the left, corresponding to the growth of the grains and the development of the facets. The numerous negative values are due to the complex shape of the depth-hoar crystals; they should indicate the presence of holes (see Fig. 5) which could appear in the part of the grains that sublimate.
Fig. 7. Histograms of the four curvature distributions on 56(f voxels cubes.
Representative elementary volume
Figure 8 shows several histograms of curvature on the sample “depth hoar”. Curvature has been computed on embedded cubes; the size of edge of the cubes varies from 80 to 560 voxels. As soon as the size reaches about 300 voxels, the obtained histograms are similar. This result was verified by computing curvature on separated cubes of size 3003 voxels. Similar results were obtained for each snow sample. This allows us to conclude that the size of the X-rayed samples is larger than the representative elementary volume for curvature.
Fig. 8. Variation of the curvature histogram according to the volume of computation. Results for “depth-hoar” sample.
Comparison with 2-D results
A relevant parameter for snow characterization is the histogram of curvature computed on the grain’s silhouettes. In Figure 9, the 2-D histograms of convex curvatures of about 50 grains have been superimposed on 3-D histograms. A comparison can be made only for positive curvatures because the bonds between grains, where most negative curvatures are situated, are mostly broken for a 2-D observation. For the samples “crust” and “wet grains”, the 3-D histogram is very close to the 2-D one. This is not the case for the other two samples. “Partially faceted particles” is made up of small decomposing particles that tend to lie flat on the observation plate. The edges of grains, the curvature of which is high, are therefore hidden. For “depth hoar” as well, 2-D observation shows only part of the grains. The ridges on the striated grains and the edges of the hollow grains are usually hidden, which decreases the percentage of pixels belonging to high-curvature classes.
Fig. 9. Comparison between the histogram of 3-D convex curvatures and the 2-D one, for each snow sample.
4. Discussion and Conclusion
The experimental technique described here has proved the feasibility of using X-ray microtomography to visualize snow samples of about 1 cm3 with a resolution of 10 μm. Presently it can be applied to every snow type cohesive enough to stand up to the rinse of the phthalate before X-ray exposure. Some improvements will soon be tested to visualize more brittle snow types. One way is to replace the filling medium (phthalate) by another chemical which offers a better contrast with ice for the purpose of X-rays. Another way is to replace the image-acquisition method, absorption for the moment, by multiple phase contrast imaging at different distances on snow impregnated with pure phthalate.
Spatial resolution of 10 μm is enough to visualize most snow-grain types. Tests on new snow have shown that this is not the case for precipitation particles such as stellars. Future upgrade of the CCD camera to 20482 will allow visualization of the same volume with a resolution of 5 /an.
However, the quality of the 3-D images is very good, and numerous studies can be envisaged that use direct observations of snow microstructure. The calculation of porosity and 3-D local curvature for four different snow samples has shown that the size of the studied sample is statistically representative for these parameters. High-resolution tomographic images will allow further investigation of other features of snow microstructure such as specific area or ice-bond geometry. Moreover, 3-D images could provide valuable data for numerical models in order to investigate complex snow properties like heat conductivity, or complex processes like metamorphism.
Acknowledgements
We thank J. Baruchel and O. Brissaud for fruitful discussions and their help for the experimental set-up, and P. Lamboley who wrote the program for visualizing 3-D data files.
