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Preparation and characterization of spray deposited Cd1-xZnxS thin films on activated substrate

Published online by Cambridge University Press:  25 October 2013

Kaliappan Sankarasubramanian
Affiliation:
School of Physics, Madurai Kamaraj University, Madurai 625021, Tamil Nadu, India
Kunjithapatham Sethuraman*
Affiliation:
School of Physics, Madurai Kamaraj University, Madurai 625021, Tamil Nadu, India
Ramraj Ramesh Babu
Affiliation:
Crystal Growth and Thin Film Laboratory, Department of Physics, Bharathidasan University, Tiruchirappalli 620024, Tamil Nadu, India
Kandasamy Ramamurthi
Affiliation:
Department of Physics & Nanotechnology, SRM University, Chennai 603203, Tamil Nadu, India
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Abstract

Cd1−xZnxS thin films were deposited on the glass substrates (GS) and on the potassium permanganate activated substrates (KMAS) at 350 °C using spray pyrolysis technique. X-ray diffraction studies confirmed that the films are polycrystalline and belong to the hexagonal structure. Scanning electron microscopic studies revealed an effective change on the surface morphology of the film due to potassium permanganate activation (KMA). Transmittance spectra of Cd1−xZnxS thin films were recorded in the range of 320–700 nm and the transmittance was found to be high for the film coated on KMAS than GS. Photoluminescence spectra show a strong emission peak at 585 nm for the film coated on the GS and it is shifted to 592 nm for the film coated on KMAS. Thus the results authenticate that KMA influences the structural and optical properties of the deposited films.

Type
Research Article
Copyright
© EDP Sciences, 2013

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References

Akinci, O., Gurel, H.H., Unlu, H., Thin Solid Films 684, 511 (2006)
Zang, H., Ma, X., Yang, D., Mater. Lett. 58, 5 (2003)CrossRef
Yamaguchi, T., Yamamoto, Y., Tanaka, T., Demizu, Y., Yoshiba, A., Thin solid Films 281/282, 375 (1996)CrossRef
Lee, J.H., Song, W.C., Yi, J.S., Yang, K.J., Han, W.D., Hwang, J., Thin Solid Films 349, 431 (2003)
Abdinov, A.S., Mamedov, H.M., Hasanov, H.A., Amirova, S.I., Thin Solid Films 388, 480 (2005)
Oladeji, I.O., Chow, L., Ferekides, C.S., Viswanathan, V., Zhao, Z., Solar Energy Mater. Solar Cells 61, 203 (2000)CrossRef
Lui, T.Y., Zapien, J.A., Tang, H., Ma, D.D.D., Liu, Y.K., Lee, C.S., Lee, S.T., Shi, S.L., Xu, S.J., Nanotechnology 17, 5935 (2006)CrossRef
Bhattacharjee, B., Mandal, S.K., Chakrabarti, K., Ganguli, D., Chaudhuri, S., J. Phys. D: Appl. Phys. 35, 2636 (2002)CrossRef
Kumar, V., Juneja, S., Sharma, S.K., Singh, V., Sharma, T.P., JCT Res. 7, 399 (2010)
Prem Kumar, T., Rajasekar, S., Saravanakumar, S., Joseph, P.S., Sankaranarayanan, K., J. Adv. Microsc. Res. 5, 123 (2010)CrossRef
Sethi, R., Kumar, L., Sharma, P.K., Nano. Res. Lett. 5, 96 (2010)CrossRef
Celalettin Baykul, M., Orhan, N., Thin Solid Films 518, 1925 (2010)CrossRef
Raviprakash, Y., Bangera, K.V., Shivakumar, G.K., Sol. Energy 83, 1645 (2009)CrossRef
Patil, P.S., Mater. Chem. Phys. 59, 185 (1999)CrossRef
Burton, L.C., Hench, T.L., Appl. Phys. Lett. 29, 612 (1976)CrossRef
Feigeison, R.S., N’Diaye, A., Yin, S.Y., Bube, R.H., J. Appl. Phys. 48, 3162 (1977)CrossRef
Xia, D., Caijuan, T., Rongzhe, T., Wei, L., Lianghuan, F., Jingquan, Z., Lili, W., Zhi, L., J. Semicond. 32, 22003 (2011)
Kokotov, M., Hodes, G., J. Mater. Chem. 19, 3847 (2009)CrossRef
Gadde, R.R., Laitinen, H.A., Anal. Chem. 46, 2022 (1974)CrossRef
Raviprakash, Y., Bangera, K.V., Shivakumar, G.K., Curr. Appl. Phys. 10, 193 (2010)CrossRef
Cullity, B.D., Elements of X-Ray Diffraction (Addison-Wesley, MA, 1956)Google Scholar
Williamson, G.B., Smallman, R.C., Philosophical Magazine 1, 34 (1956)CrossRef
Zhao, Z., Zeng, J., Ding, Z., Wang, X., Hou, J., Zhang, Z., J. Appl. Phys. 102, 53509 (2007)CrossRef
Peng, X., Manna, L., Wickham, J., Scher, E., Kadavanich, A., Alivisatos, A.P., Nature 404, 59 (2000)