Hostname: page-component-76fb5796d-x4r87 Total loading time: 0 Render date: 2024-04-26T08:43:03.294Z Has data issue: false hasContentIssue false

Nanometer scale mapping of cobalt in Al-doped ferromagnetic Zn0.7Co0.3O thin film

Published online by Cambridge University Press:  26 January 2006

J.-L. Maurice*
Affiliation:
Unité Mixte de Physique CNRS/Thales, associée à l'Université Paris-Sud, 91767 Palaiseau, France
K. Rode
Affiliation:
Unité Mixte de Physique CNRS/Thales, associée à l'Université Paris-Sud, 91767 Palaiseau, France
A. Anane
Affiliation:
Unité Mixte de Physique CNRS/Thales, associée à l'Université Paris-Sud, 91767 Palaiseau, France
D. Imhoff
Affiliation:
Laboratoire de Physique des Solides, Université Paris-Sud, 91405 Orsay, France
J.-P. Contour
Affiliation:
Unité Mixte de Physique CNRS/Thales, associée à l'Université Paris-Sud, 91767 Palaiseau, France
Get access

Abstract

There has been a renewed interest in zinc oxide in the materials science community after it was shown to be ferromagnetic when doped with cobalt. However, it has remained difficult to tell whether the origin of the phenomenon was intrinsic or due to secondary phases. Here, we examine with analytical transmission electron microscopy the distribution of cobalt in a thin film of ferromagnetic Al-doped Zn0.7Co0.3O that we have grown by pulsed laser deposition on alumina. We show that precipitation of a secondary phase does occur, but that it concerns less than 10% of the cobalt atoms. The precipitates appear to be made of hexagonal metallic Co, and their average diameter is 4 nm. Their magnetism could be the reason for the low measured Curie temperature of the sample (50 K). On the other hand, the overall measured magnetization of 0.7 $\mu_B$ per cobalt atom suggests that the Co atoms in solution are at the origin of most of the signal.

Keywords

Type
Research Article
Copyright
© EDP Sciences, 2006

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

Ueda, K., Tabata, H., Kawai, T., Appl. Phys. Lett. 82, 2302 (2001)
For a review, see Prellier, W., Fouchet, A., Mercey, B., J. Phys.: Cond. Matter 15, R1583 (2003)
Rode, K., Anane, A., Mattana, R., Contour, J.-P., Durand, O., Le Bourgeois, R., J. Appl. Phys. 93, 7676 (2003) CrossRef
K. Rode, A. Anane, J.-L. Maurice, F. Petroff, V. Cros, E. Fonda, J.-P. Contour, A. Fert, 49th Conf. on Magnetism and Magnetic Materials, Nov. 7–11, 2004, Jacksonville, FL, USA
H.-J. von Bardeleben (private communication)
Jeanguillaume, C., Colliex, C., Ultramicroscopy 28, 252 (1989) CrossRef
Maurice, J.-L., Briático, J., Carrey, J., Petroff, F., Schelp, L.F., Vaurès, A., Philos. Mag. 79, 2921 (1999) CrossRef
Yu-Zhang, K., Imhoff, D., Leprince-Wang, Y., Roy, E., Zhou, S.M., Chien, C.L., Acta Mater. 51, 1157 (2003) CrossRef