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Molecular semiconductor-doped insulator (MSDI) heterojunctions as new transducers for chemical sensors

Published online by Cambridge University Press:  23 November 2011

M. Bouvet ,
V. Parra  and
J.-M. Suisse
M. Bouvet*
Affiliation:
ICMUB, Université de Bourgogne, CNRS UMR 5260, 9 Avenue Alain Savary, BP 47870, 21047 Dijon, France
V. Parra
Affiliation:
DC Wafers Investments, S.L. 24227 León, Spain
J.-M. Suisse
Affiliation:
ICMUB, Université de Bourgogne, CNRS UMR 5260, 9 Avenue Alain Savary, BP 47870, 21047 Dijon, France
*
ae-mail: marcel.bouvet@u-bourgogne.fr

Abstract

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This article describes a new principle of transduction involving an heterojunction between a Molecular Semiconductor and a Doped Insulator (MSDI). Herein, we report on an MSDI-based sensor featuring an heterojunction between a lutetium bisphthalocyanine (LuPc2), which acts as Molecular Semiconductor (MS) and a thin film of Doped Insulator (DI) made of substituted or fluorinated copper phthalocyanine (CuFnPc, where n = 0, 8, 16). Previously, we reported the peculiar effect of the heterojunction on the MSDI’s electronic behavior, suggesting this device as a new kind of transducer for gas chemosensing. Indeed, of particular significance was the key role of modulator played by the nature of the doped insulator sub-layer. While the MS thin film remains the only layer of the sensor exposed to gas atmosphere, the DI’s ability to tune the electronic characteristics of the organic heterojunction allows it to drastically affect the nature of the effective charge carriers. In particular, an increase in fluorination of the doped insulator can cause an inversion of the LuPc2 response toward electron accepting (ozone, ppb level) or donating (ammonia, ppm level) gases. The present work focuses on the structural, electronic and electrical properties of the MSDI heterojunction, which have been studied by UV-vis spectroscopy, atomic force microscopy, current-voltage measurements and chemical doping, in order to shed some light on this phenomenon. The unique ambipolar nature of LuPc2 is suggested to be the main property responsible for the MSDI’s unique behavior.

Type
Research Article
Information
The European Physical Journal - Applied Physics , Volume 56 , Issue 3: Focus on organic electronic devices , December 2011 , 34103
Copyright
© The Author(s), 2011

References

Bouvet, M., in The Porphyrin Handbook, edited by Kadish, K.M., Guilard, R., Smith, K., vol. 19 (Academic Press, Boston, 2003), p. 37CrossRefGoogle Scholar
Bouvet, M., Pauly, A., in The Encyclopedia of Sensors, edited by Grimes, C.A., Dickey, E.C., Pishko, M.V., vol. 6 (American Scientific Publishers, Valencia, CA, 2006), p. 227Google Scholar
Rodriguez-Mendez, M.L., in The Encyclopedia of Sensors, edited by Grimes, C.A., Dickey, E.C., Pishko, M.V., vol. 9 (American Scientific Publishers, Stevenson Ranch, CA, 2006), p. 111Google Scholar
Mabeck, J.T., Malliaras, G.G., Anal. Bioanal. Chem. 384, 343 (2006)CrossRef
Simon, J., Bassoul, P., Design of Molecular Materials: Supramolecular Engineering (Wiley, Chichester, New York, 2000)Google Scholar
Snow, A.W., Barger, W.R., in Phthalocyanines: Properties and Applications, edited by Lever, A.B.P., vol. 1 (John Wiley and Sons, New York, 1989)Google Scholar
Valli, L., Adv. Colloid Interface Sci. 116, 13 (2005)CrossRef
Filippini, D., Alimelli, A., DiNatale, C., Paolesse, R., Lundstrom, I., D’amico, A., Angew. Chem. Int. Ed. 45, 3800 (2006)CrossRef
Simon, J., André, J.-J., Molecular Semiconductors (Springer Verlag, Berlin, 1985)CrossRefGoogle Scholar
André, J.-J., Holczer, K., Petit, P., Riou, M.-T., Clarisse, C., Even, R., Fourmigué, M., Simon, J., Chem. Phys. Lett. 115, 463 (1985)
Turek, P., Petit, P., André, J.-J., Simon, J., Even, R., Boudgema, B., Guillaud, G., Maitrot, M., J. Am. Chem. Soc. 109, 5119 (1987)CrossRef
L’Her, M., Cozien, Y., Courtot-Coupez, J., J. Electroanal. Chem. 157, 183 (1983)
Bouvet, M., Silinsh, E.A., Simon, J., Mol. Mater. 5, 255 (1995)
Bouvet, M., Simon, J., Chem. Phys. Lett. 172, 299 (1990)CrossRef
Parra, V., Rei Vilar, M., Botelho Rego, A.M., Ferraria, A.M., Boufi, S., Rodriguez-Mendez, M.L., Fonavs, E., Muzikante, I., Bouvet, M., Langmuir 23, 3712 (2007)CrossRef
Janata, J., Josowicz, M., J. Solid State Electrochem. 13, 41 (2009)CrossRef
Passard, M., Blanc, J.-P., Maleysson, C., Thin Solid Films 271, 8 (1995)CrossRef
de Haan, A., Debliquy, M., Decroly, A., Sens. Actuators B Chem. 57, 69 (1999)CrossRef
Santucci, S., Picozzi, S., Di Gregorio, F., Lozzi, L., Cantalini, C., Valentini, L., Kenny, J.M., Delley, B., J. Chem. Phys. 119, 10904 (2003)CrossRef
Boher, F.I., Sharoni, A., Colesniuc, C.N., Park, J., Schuller, I.K., Kummel, A.C., Trogler, W.C., J. Am. Chem. Soc. 129, 5640 (2007)
Yang, R.D., Gredig, T., Colesniuc, C.N., Park, J., Schuller, I.K., Trogler, W.C., Kummel, A.C., Appl. Phys. Lett. 90, 263506 (2007)CrossRef
De Saja, J.A., Rodriguez-Mendez, M.L., Adv. Colloid Interface Sci. 116, 1 (2005)CrossRef
Parra, V., Bouvet, M., Brunet, J., Rodriguez-Mendez, M.L., De Saja, J.A., Thin Solid Films 516, 9012 (2008)CrossRef
Guillaud, G., Simon, J., Germain, J.-P., Coord. Chem. Rev. 178, 1433 (1998)CrossRef
Bouvet, M., Leroy, A., Simon, J., Tournilhac, F., Guillaud, G., Lessnick, P., Maillard, A., Spirkovitch, S., Debliquy, M., de Haan, A., Decroly, A., Sens. Actuators B Chem. 72, 86 (2001)CrossRef
Bouvet, M., Guillaud, G., Leroy, A., Maillard, A., Spirkovitch, S., Tournilhac, F.-G., Sens. Actuators B Chem. 73, 63 (2001)CrossRef
Bouvet, M., Anal. Bioanal. Chem. 384, 366 (2006)CrossRef
Muzikante, I., Parra, V., Dobulans, R., Fonavs, E., Latvels, J., Bouvet, M., Sensors 7, 2984 (2007)CrossRef
Bouvet, M., Parra, V., Locatelli, C., Xiong, H., J. Porphyr. Phthalocyanines 13, 84 (2009)CrossRef
Parra, V., Arrieta, A.A., Fernandez-Escudero, J.A., Garcia, H., Apetrei, C., Rodriguez-Mendez, M.L., De Saja, J.A., Anal. Chim. Acta 563, 229 (2006)CrossRef
Apetrei, C., Apetrei, I.M., Nevares, I., Del Alamo, M., Parra, V., Rodriguez-Mendez, M.L., De Saja, J.A., Electrochim. Acta 52, 2588 (2007)CrossRef
Germain, J.-P., Schöllhorn, B., Pauly, A., Maleysson, C., Blanc, J.-P., Thin Solid Films 333, 235 (1998)CrossRef
Brunet, J., Pauly, A., Mazet, L., Germain, J.-P., Bouvet, M., Malézieux, B., Thin Solid Films 490, 28 (2005)CrossRef
Schöllhorn, B., Germain, J.-P., Pauly, A., Maleysson, C., Blanc, J.-P., Thin Solid Films 326, 245 (1998)CrossRef
Parra, V., Brunet, J., Pauly, A., Bouvet, M., Analyst 9, 1776 (2009)CrossRef
Bouvet, M., Parra, V., UPMC and CNRS, Patent FR2008/2922310 and PCT/FR2008/001325
Bao, Z., Lovinger, A.J., Dodabalapur, A., Appl. Phys. Lett. 69, 3066 (1996)CrossRef
Bao, Z., Lovinger, A.J., Brown, J., J. Am. Chem. Soc. 120, 207 (1998)CrossRef
De Oteyza, D.G., Barrena, E., Osso, J.O., Sellner, S., Dosch, H., J. Am. Chem. Soc. 128, 15052 (2006)CrossRef
De Oteyza, D.G., Barrena, E., Osso, J.O., Sellner, S., Dosch, H., J. Phys. Chem. B 110, 16618 (2006)CrossRef
Pietro, W.J., Adv. Mater. 6, 239 (1994)CrossRef
Murdey, R., Sato, N., Bouvet, M., Mol. Cryst. Liq. Cryst. 455, 211 (2006)CrossRef
Murdey, R., Bouvet, M., Sumimoto, M., Sakaki, S., Sato, N., Synt. Met. 159, 1677 (2009)CrossRef
Bouvet, M., Xiong, H., Parra, V., Sens. Actuators B Chem. 145, 501 (2010)CrossRef
Madru, R., Guillaud, G., Al Sadoun, M., Maitrot, M., Clarisse, C., Le Contellec, M., André, J.-J., Simon, J., Chem. Phys. Lett. 142, 103 (1987)CrossRef
Del Cano, T., Parra, V., Rodriguez-Mendez, M.L., Aroca, R.F., De Saja, J.A., Appl. Surf. Sci. 246, 327 (2005)Google Scholar
Roberts, M.E., Mannsfeld, S.C.B., Tang, M.L., Bao, Z., Chem. Mater. 20, 7332 (2008)CrossRef
Kondratyev, K.Y., Varotsos, C.A., Environ. Sci. Pollut. R 3, 205 (1996)CrossRef
Belghachi, A., Collins, R.A., J. Phys. D: Appl. Phys. 23, 223 (1990)CrossRef
Timmer, B., Olthuis, W., Van den Berg, A., Sens. Actuators B Chem. 107, 666 (2005)CrossRef
Birchall, J.M., Haszeldine, R.N., Morley, J.O., J. Chem. Soc. C 19, 2667 (1970)CrossRef
Eley, D.D., Hazeldine, D.J., Palmer, T.F., J. Chem. Soc., Faraday Trans. 2 69, 1808 (1973)CrossRef
Kirin, I.S., Moskalev, P.N., Makashev, Y.A., Russ. J. Inorg. Chem. 10, 1065 (1965)
Kirin, I.S., Moskalev, P.N., Makashev, Y.A., Russ. J. Inorg. Chem. 12, 369 (1967)
Clarisse, C., Riou, M.-T., Inorg. Chim. Acta 130, 139 (1987)CrossRef
Yim, S., Jones, T.S., Phys. Rev. B 73, 161305 (2006)CrossRef
De Oteyza, D.G., Krauss, T.N., Barrena, E., Sellner, S., Dosch, H., Appl. Phys. Lett. 90, 243104 (2007)CrossRef
Tadayyon, S.M., Grandin, H.M., Griffiths, K., Norton, P.R., Aziz, H., Popovic, Z.D., Org. Electron. 5, 157 (2004)CrossRef
Van Cott, T.C., Gasyna, Z., Shatz, P.N., Boyle, M.E., J. Phys. Chem. 99, 4820 (1995)
Orti, E., Brédas, J.-L., Clarisse, C., J. Chem. Phys. 92, 1228 (1990)
Orti, E., Piqueras, M.C., Crespo, R., Brédas, J.-L., Chem. Mater. 2, 110 (1990)CrossRef
Saito, T., Sisk, W., Kobayashi, T., Suzuki, S., Iwayanagi, T., J. Phys. Chem. 97, 8026 (1993)CrossRef
Basova, T., Kol’tsov, E., Hassan, A., Tsargorodoskaya, A., Ray, A., Igumenov, I., Phys. Stat. Sol. B 242, 822 (2005)CrossRef
Hiller, S., Schlettwein, D., Armstrong, N.R., Wohlre, D., J. Mater. Chem. 8, 945 (1998)CrossRef
Ho, Z.Z., Ju, C.Y., Hetherington, W.M. III, J. Appl. Phys. 62, 716 (1987)CrossRef
Ray, A.K., Exley, J., Ghassemlooy, Z., Crowther, D., Ahmet, M.T., Silver, J., Vacuum 61, 19 (2001)CrossRef
Yim, S., Heutz, S., Jones, T.S., Phys. Rev. B 67, 165308 (2003)CrossRef
Heutz, S., Jones, T.S., J. Appl. Phys. 92, 3039 (2002)CrossRef
Rodriguez-Mendez, M.L., Gorbunova, Y., De Saja, J.A., Langmuir 18, 9560 (2002)
Lau, K.M., Tang, J.X., Sun, H.Y., Lee, C.S., Lee, S.T., Yan, D., Appl. Phys. Lett. 88, 173513 (2006)CrossRef
Ye, R., Baba, M., Suzuki, K., Mori, K., Jpn. J. Appl. Phys. 46, 2878 (2007)CrossRef
Ishii, H., Sugiyama, K., Ito, E., Seki, K., Adv. Mater. 11, 605 (1999)3.0.CO;2-Q>CrossRef
Tanaka, Y., Kanai, K., Ouchi, Y., Seki, K., Org. Electr. 10, 990 (2009)CrossRef
Manaka, T., Iwamoto, M., Thin Solid Films 438–439, 157 (2003)CrossRef
Guillaud, G., Al Sadoun, M., Maitrot, M., Simon, J., Bouvet, M., Chem. Phys. Lett. 167, 503 (1990)CrossRef
Wang, J., Wang, H., Zhang, J., Jan, X., Yan, D., J. Appl. Phys. 97, 026106 (2005)CrossRef
Germain, J.-P., Pauly, A., Maleysson, C., Blanc, J.-P., Schollhörn, B., Thin Solid Films 333, 235 (1998)CrossRef
Jones, B.A., Facchetti, A., Wasielewski, M.R., Marks, T.J., J. Am. Chem. Soc. 129, 15259 (2007)CrossRef
Facchetti, A., Mater. Today 10, 28 (2007)CrossRef
Chen, Y., Bouvet, M., Sizun, T., Barochi, G., Rossignol, J., Lesniewska, E., Sens. Actuators B Chem. 155, 165 (2011)CrossRef