Hostname: page-component-8448b6f56d-c47g7 Total loading time: 0 Render date: 2024-04-24T08:45:35.884Z Has data issue: false hasContentIssue false

High quality multicrystalline silicon grown by multi-stage solidification control method

Published online by Cambridge University Press:  15 July 2004

S. Nara
Affiliation:
Steel Research Laboratory, JFE Steel Corporation Mizushima, Kurashiki 712–8511, Japan
T. Sekiguchi*
Affiliation:
Nanomaterials Laboratory, National Institute for Materials Science 1-2-1, Tsukuba 305–0047, Japan
J. Chen
Affiliation:
Nanomaterials Laboratory, National Institute for Materials Science 1-2-1, Tsukuba 305–0047, Japan State Key Laboratory of Silicon Materials, Zhejiang University, Hangzhou 310027, P.R. China
Get access

Abstract

We have developed a method for growing high quality multicrystalline silicon (mc-Si) ingots for high efficiency solar cells. Grain size of the mc-Si wafers was controlled by the multi-stage solidification method. Impurity concentrations in the mc-Si ingots were also reduced by several ways. The efficiency of mc-Si solar cells produced from such mc-Si wafers has reached 18.3% with a cell area of 25 cm2. In this paper we have investigated this high quality mc-Si by means of electron-beam induced current (EBIC), transmission electron microscopy combined with energy-dispersive X-ray analysis (TEM-EDX), and secondary-ion mass-spectroscopy (SIMS). EBIC results revealed that grain boundaries in MUST mc-Si were electrically inactive at room temperature. No metal impurities were detected at these grain boundaries.

Keywords

Type
Research Article
Copyright
© EDP Sciences, 2004

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

M. Apel, I. Steinbach, Preprint 2nd World Conference and Exhibition on Photovoltaic Solar Energy Conversion, Vienna (1998), 1347
R. Corkish, A. B. Sproul, T. Puzzer, P. P. Altermatt, G. Heiser, Keung L. Luke, Proceeding of 2nd World Conference and Exhibition on Photovoltaic Solar Energy Conversion, Vienna (1998), 1298
C. P. Khattak, F. Schmid, Proceeding of 2nd World Conference and Exhibition on Photovoltaic Solar Energy Conversion, Vienna (1998), 1870 1cm
A. Lowerenz, M. Rinio, S. Riedel, M. Ghosh, M. Werner, H. J. Moller, Proceeding of 16th European Photovoltaic Solar Energy Conference and Exhibition (2000)
C. Hassler, W. Koch, W. Krumbe, A. Muller, A. Schertlich, Proceeding of 2nd World Conference and Exhibition on Photovoltaic Solar Energy Conversion, Vienna (1998), 1886
Yu, E. T., Barmak, K., Ronsheim, P., Johnson, M. B., MacFarland, P., Halbout, J. M., J. Appl. Phys. 79, 15 (1996)
K. Graff, The Electrochem. Soc. 121 (1982)
E. R. Weber, N. Wiehl, Defects in Semiconductors (North-Holland, 1983), p. 19
Read, W. T., Shockley, W., Phys. Rev. 78, 275 (1950) CrossRef
Hasson, G., Boos, J. Y., Herbeuval, I., Biscondi, M., Goux, C., Surf. Sci. 31, 115 (1972) CrossRef
J. W. Christian, The Theory of Transformations in Metals and Alloys (Pergamon, 1981), p. 353
Fisher, J. C., J. Appl. Phys. 22, 74 (1951) CrossRef
Le Claire, A. D., Philos. Mag. 42, 468 (1951) CrossRef
Fally, J., Fabre, F., Chabot, B., Rev. Phys. Appl. 22, 529 (1987) CrossRef
Hopkins, R. H., Seidensticker, R. G., Davis, J. R., Rai Choudhury, P., Blais, P. D., Mccormik, J. R, J. Cryst. Growth 42, 493 (1997) CrossRef
S. Nara, Y. Sakaguchi, in Proceeding of 12th Crystalline Silicon Solar Cell Materials and Processes (2002), 28
Sekiguchi, T., Sumino, K., Rev. Sci. Instrum. 66, 4277 (1995) CrossRef
Y. Komatsu et al., in Proceeding of 12th Crystalline Silicon Solar Cell Materials and Processes (2002), 87
Sekiguchi, T., Kusanagi, S., Miyamura, Y., Sumino, K., Acta Phys. Polon. A. 83, 71 (1993) CrossRef
Kusanagi, S., Sekiguchi, T., Shen, B., Sumino, K., Mat. Sci. Technol. 11, 685 (1995)