Currently, there is significant ongoing research into the temporal and spatial variability of marine radiocarbon reservoir effects (MREs) through quantification of ΔR values. In turn, MRE studies often use large changes in ΔR values as proxies for changes in ocean circulation. ΔR values are published in a variety of formats with variations in how the errors on these values are calculated, making it difficult to identify trends or to compare values, unless the method of calculating the ΔR is explicitly described or all of the data are made available in the publication. This paper demonstrates the large range in ΔR values (+34 to −122) that can be obtained from a single, secure archaeological context when using the multiple paired sample approach, despite the fact that the terrestrial entities were of statistically indistinguishable 14C ages, as were the marine samples. This demonstrates the inherent variability in the ΔR calculations themselves and we propose that, together with calculation of mean ΔR, the distribution of ΔR values should be displayed, e.g. as histograms in order to illustrate the full data range. This spread is only apparent when employing a multiple paired sample approach as the uncertainty derived on a single pair of samples, taking account only of the errors on the individual 14C ages, will never truly represent the overall variability in ΔR that results from the intrinsic variability in the population of 14C ages in samples that might have been used. Consequently, ΔR values and the associated uncertainty calculated from single pairs should be treated with some caution. We propose that, where possible, when using paired archaeological samples, that a multiple paired approach should be employed as it will test the context security of the material used in the ΔR calculations. When summarizing the values by the weighted average, we also propose that the standard error for predicted values should be employed as this will fully encompass the uncertainty of a future ΔR calculation, using different samples for a similar time and location. Finally, we encourage future publishing of ΔR values using the histogram format, making all of the data available. This will help ensure that ΔR values are comparable across the literature and should provide a framework for standardization of publication methods.

Intensified archaeological research in the Caribbean over the past 2 decades has provided a wealth of new information on how and when these islands were settled prehistorically. However, there has been a paucity of research on islands in the southern Lesser Antilles, which would allow for more rigorous testing of migration models and various settlement pattern hypotheses. To address some of these chronological and geographical gaps, we present a corpus of 41 radiocarbon dates from several sites in the Grenadine Island chain. Results to date support a relatively late Ceramic Age settlement of these smaller islands (about AD 400) compared to other nearby, larger islands in the southern Lesser Antilles (about AD 200) as well as the Caribbean as a whole (about 400/500 BC). Intriguing questions also remain as to an apparent, but as yet inadequately tested, pattern where earlier colonization dates are correlated with larger island size.

Two Δ14C calibration curves have been produced that allow determination of the statistical average age of coca leaf and cocaine base specimens produced for the time period 1979–2009. These calibration curves are based on field collections of specimens in Bolivia, Colombia, Ecuador, and Peru. The coca leaf F14C and Δ14C calibration curves can be used to predict the ages of botanical tissues collected in tropical South America and possibly extended to other tropical locations. The cocaine F14C and Δ14C calibration curves can be used to predict the ages of seized cocaine specimens. Because the Δ14C of the atmosphere is diminishing, the precision of this approach for age determinations will continue to get less precise over time as atmospheric 14C content continues to decline.

The canopies of forests and cultivated fields can retard the ventilation of CO2 respired from the soil. The plants in dense canopies can then acquire a small fraction of their carbon by recycling some of the respired CO2. Furthermore, some plants can assimilate a small fraction of their carbon by uptake of CO2 in the soil via their roots. In tectonically active areas, the diffuse flux of CO2 from geological sources may be comparable to that from normal soil respiration. In such areas, both the canopy and root uptake effects may allow plants to acquire a measurable fraction of their carbon from geological sources. Because this “old” carbon lacks radiocarbon, its assimilation would increase the apparent 14C ages of the plants. These effects may account for some of the discrepancies between archaeological and 14C dates.

Systematic radiocarbon dating was performed on a unique EBA-MBA cemetery at Xeropigado Koiladas situated at the edge of the Kitrini Limni basin in the Kozani area, northwest Greece. It was found that this cemetery had a particularly long period of use of ~700 yr (between about 2420 and 1730 BC), which is especially pronounced if compared with the relatively small number of burials totaling 222. The dating revealed no spatial differentiation with time; the entire area of the cemetery was used throughout the time. There is a tendency of the dates to concentrate mostly in the time ranges 2200–2030 and 2000–1850 BC, which may tentatively suggest a more intense use of the cemetery during these periods. The results from multiple or consequent burials revealed that this cemetery was a landmark visible to the people of that time for at least 500 yr, if not for the entire period of its use. Some of the graves were built on top of, or adjacent to, older ones without disturbing the old burials. This implies that the Xeropigado cemetery was an important place of reference for at least 25 generations! No settlements have been found yet in the area that could be associated with the Xeropigado cemetery. Some synchronizations with various other sites in west Macedonia, for which 14C dates are available, are presented.

The Caribbean Archaic Age (about 3000–500 BC) is thought to represent the earliest migration of humans from South America into the Lesser Antilles. However, there is a conspicuous absence of these early sites on islands south of the Guadeloupe Passage. To date, only a single radiocarbon date derived from a Queen conch (Strombus [Eustrombus] gigas) shell at the Heywoods site on Barbados was indicative of an Archaic occupation in the southern Antilles apart from a scattering of poorly reported (and mostly undated) sites. Given a number of issues associated with reliance on a single date to establish a cultural horizon, along with other problems derived from possible carbonate cement contamination and dating marine shells of a longer-lived species such as Queen conch, 2 additional samples were taken from the same unit and context at Heywoods to confirm whether the site is truly representative of an occupation during the Archaic Age. Results from a Queen conch shell adze in Context 7 dated to 2530–2200 BC (2 σ) and overlaps with the only other Archaic date from the site dating to 2320–1750 cal BC, while a juvenile specimen of the same species from Context 8 at 3280–2940 BC (2 σ) indicates that Barbados may have been settled even earlier. This suggests that Heywoods may be the oldest site between Trinidad and Puerto Rico. While further confirmation is required, these new dates have implications for understanding the nature of migratory ventures in the Caribbean, such as whether the “Southward Route” hypothesis—which postulates that earlier migration events from South America during the Ceramic Age (beginning ∼500 BC) initially bypassed the southern Lesser Antilles—also applies to the Archaic, and if other phenomena such as active volcanism may have played a role in structuring settlement patterns. Questions also remain as to why Heywoods does not exhibit the typical lithic Archaic tool kit.

Quantification of the marine radiocarbon reservoir effect (ΔR) is essential in order to calibrate conventional 14C dates from marine shell samples with reliability. ΔR also provides information concerning the intensity of coastal upwelling in marine regions influenced by this phenomenon. 14C ages of closely associated marine samples (mollusk shells) and terrestrial samples (goat bones) from São Vicente Island, Cape Verde Archipelago, permitted the first calculation of the marine 14C reservoir effect in this region. A ΔR weighted mean value of 70 ± 70 14C yr was obtained. This value is in accordance with the previously published oceanographic conditions of the region indicating the existence of a seasonal active upwelling regime.

We developed and tested a new method to separate CO2 and CH4 from bulk gas samples for radiocarbon and stable-carbon analysis that utilizes a zeolite molecular sieve. To validate the technique, tests were performed using a suite of standard gases, composed of CO2 and CH4 of distinctly different isotopic composition. We employed the method to investigate the carbon isotopic composition of samples of dissolved CO2 and CH4 collected in situ from the near surface to deep layers of an ombrotrophic raised peat bog. Results showed that the age of both the CO2 and CH4 components of the dissolved gases increased with depth from ≃0–300 BP at 0.25 m to ≃4000 BP at 4 m. CH4 was mainly similar or slightly older in age compared to CO2, with the greatest difference in ages occurring at 1 m depth where CH4 was older by 430–615 yr. The δ13C values of CO2 increased with depth from −12.4‰ and −8.0‰ at 0.25 m to +6.9‰ and +8.3‰ at 4 m, whereas the δ13C of CH4 stayed in the range −58.4‰ to −70.6‰. The 14C results from the deepest layers are consistent with a similar source for both gases. 14C ages for the CO2 component were younger compared to CH4, within the shallower depths of the peat bog (≤1 m) and demonstrate the incorporation of acrotelm-derived respired CO2 into the catotelm.

Lascaux Cave is renowned for its outstanding prehistoric paintings, strikingly well-preserved over about 18,000 yr. While stalagmites and stalactites are almost absent in the cave, there is an extensive calcite flowstone that covered a large part of the cave until its opening for tourists during the 1950s. The deposit comprises a succession of calcite rims, or “gours,” which allowed seepage water to pond in large areas in the cave. Their possible role in preservation of the cave paintings has often been evoked, but until now this deposit has not been studied in detail. Here, we present 24 new radiocarbon accelerator mass spectrometry (AMS) and 6 uranium-thorium (U-Th) analyses from the calcite of the gours, 4 AMS 14C dates from charcoals trapped in the calcite, and 4 AMS 14C analyses on organic matter extracted from the calcite. Combining the calibrated 14C ages obtained on charcoals and organic matter and U-Th ages from 14C analyses made on the carbonate, has allowed the calculation of the dead carbon proportion (dcp) of the carbonate deposits. The latter, used with the initial atmospheric 14C activities reconstructed with the new IntCal09 calibration data, allows high-resolution age estimation of the gour calcite samples and their growth rates. The carbonate deposit grew between 9530 and 6635 yr cal BP (for dcp = 10.7 ± 1.8%; 2 σ) or between 8518 and 5489 yr cal BP (for dcp = 20.5 ± 1.9%; 2 σ). This coincides with humid periods that can be related to the Atlantic period in Europe and to Sapropel 1 in the eastern Mediterranean Sea. However, geomorphological changes at the cave entrance might also have played a role in the gour development. In the 1940s, when humans entered the cave for the first time since its prehistoric occupation, the calcite gours had already been inactive for several thousand years.

Previous research in leeward Kohala, Hawai'i Island, has determined that the Leeward Kohala Field System (LKFS), a vast agricultural zone covering ∼60 km2, developed between the 14th and 18th centuries AD. Additional analyses have documented the establishment of traditional socioeconomic territories, known as ahupua'a, in tandem with the expansion of the field system. This article further refines the chronology of human settlement and socioeconomic development in leeward Kohala through the analysis of deposits associated with prehistoric residences. Based upon survey and excavation, we present a chronology for Hawaiian household transition and economic development in 2 study areas of leeward Kohala, spanning the field system to the coast. Forty-nine radiocarbon dates from short-lived plant materials and 5 230Th dates on corals from residential and ritual features are synthesized into 3 temporal periods, which allow for comparison of residential size, distribution, number, and associated faunal materials from archaeological deposits. Changes in household composition and economy are suggested to have developed in tandem with the establishment of individual ahupua'a and land divisions within them, and the further development of agricultural production.

One of Hungary's geological and environmental treasures is nestled in the heart of the Great Hungarian Plain. The catchment basin of Lake Kolon was subjected to detailed environmental historical studies starting in 2005. Undisturbed cores taken along transects of the basin were subjected to detailed sedimentological, paleoecological, and geochemical studies. To establish a reliable timeframe of the lacustrine and marshland sedimentary sequence identified, 22 samples were analyzed by accelerator mass spectrometry (AMS) in the radiocarbon laboratories of Poznań and Tucson. With the new results in hand, we had the opportunity to elucidate the geological evolution of the area for the past 25,000 yr. This sequence is highly beneficial, as it is probably the most well-dated profile of the Quaternary from the area studied. The new absolute dates enabled the comparison of local geological evolution of the studied area with those of global climatic changes. As seen from our findings, the geological evolution of the catchment basin was congruent with major climatic events during the Pleistocene and the entire Holocene. However, a very peculiar trajectory was identified for the terminal part of the Pleistocene and the opening of the Holocene regarding the evolution of the landscape, the vegetation, and the fauna of this part of the Great Hungarian Plain.

This paper describes an optimal radiocarbon counting window for liquid scintillation (LS) 14C dating that secures for unquenched as well as for heavily quenched dating samples maximal stability of 14C counting efficiency and theoretically minimal quench correction. In high-precision dating, a balanced counting window with fixed channel limits is frequently used, where about 3% of the highest part of the 14C spectrum is sacrificed for high 14C counting stability. The stability is, however, diminished for quenched samples. Therefore, this window is here replaced by a balanced fixed-energy 14C counting window where the channel limits depend on the quench level. The LS system used must have a linear amplifier and a multichannel analyzer. All samples are measured at a fixed high voltage. For energy calibration and determination of the quench level, the channel number of the middle of the 59.5-keV peak from an external 241Am gamma source is determined before and after measuring each sample. This counting mode is valuable in high-precision dating. It could be widely applied if adapted to systems with a logarithmic amplifier, generally used in LS dating.

The hypothesis is presented that an abrupt rise in atmospheric radiocarbon concentration evident in the Cariaco Basin varve record at 12,837 ± 10 cal yr BP, contemporaneous with the Rancholabrean termination, may have been produced by a super-sized solar proton event (SPE) having a fluence of ~1.3 × 1011 protons/cm2. A SPE of this magnitude would have been large enough to deliver a lethal radiation dose of at least 3–6 Sv to the Earth's surface, and hence could have been a principal cause of the final termination of the Pleistocene megafauna and several genera of smaller mammals and birds. The event time-correlates with a large-magnitude acidity spike found at 1708.65 m in the GISP2 Greenland ice record, which is associated with high NO-3 ion concentrations and a rapid rise in 10Be deposition rate, all of which are indicators of a sudden cosmicray influx. The depletion of nitrate ions within this acidic ice layer suggests that the snowpack surface at that time was exposed to intense UV for a prolonged period, which is consistent with a temporary destruction of the polar ozone layer by solar cosmic rays. The acidity event also coincides with a large-magnitude, abrupt climatic excursion and is associated with elevated ammonium ion concentrations, an indicator of global fires.

Accelerator mass spectrometry (AMS) radiocarbon dating a continuous core from Lake Gun Nur, northern Mongolia, shows a period between 10 and 8 ka BP that could not be dated accurately. Further dating on alkali-insoluble residue and humic acid from the same samples in the Gun Nur core suggest that this AMS 14C date anomaly is neither analytical nor material related. We hypothesize that the 14C anomaly may be derived from increasing production rates of 14C caused by diminished solar activity, a low 14CO2/14CO ratio in the atmosphere, or an unstable 14C flux in the lower atmosphere caused by changing geomagnetic field strength. Our results imply that the 14C data used for 14C age calibration cannot correct the age-depth regression between 8 and 10 ka BP to fit the age-depth model along with other time intervals.

Twenty-three samples of charred food remains, charcoal, burned animals, and human bones from 14 Lithuanian prehistoric sites were dated by radiocarbon as part of a dating project oriented towards renewing the prehistoric ceramics chronology. The new dates modified the dating of ceramic styles by hundreds to a thousand years. Three Textile Ware sherds were dated to 4230–2920 cal BC—the oldest known dates of Textile Ware pottery in the East Baltic. The organic-tempered pointed-bottomed Narva and Combed-like Wares were dated to 3970–3370 cal BC, while Bay Coast Ware (Haffküstenkultur, Rzucewo), including vessels decorated with cord impressions, were dated to 3940–3540 cal BC, i.e. to a period well preceding the Corded Ware/Battle Axe horizon in Europe. Three dates of Globular Amphorae Ware placed the phenomenon directly beyond the Bay Coast chronology, i.e. in 3450–2920 cal BC. Chamotte-tempered Corded Ware from SE Lithuania was dated to 2840–2570 cal BC. The first absolute dating of coarse ware of the Žalioji type pointed to a period of 760–515 cal BC instead of the previously assumed 2nd millennium cal BC. Cremated human bones from urns found at Paveisininkai, Kernavė, and Naudvaris cemeteries were dated to 790–380 cal BC. Accelerator mass spectrometry (AMS) dates obtained from charred food remains should be treated with a certain caution due to a possible freshwater reservoir effect that has not yet been examined in Lithuania.

The imprint of the radiocarbon bomb peak was detected in the top of stalagmite ER-77 from Grotta di Ernesto (NE Italy). This recently grown stalagmite reveals a reservoir age, also known as dead carbon fraction (dcf), of ≃1050 14C yr, or 12%. By applying a 14C soil-karst model, the age spectrum of soil organic matter (SOM) as well as the CO2 contribution of the single SOM reservoirs to the total soil CO2 can be derived. Under the assumption of constant vegetation, meaning both vegetation density and the age spectrum of SOM, it is possible to derive the soil-air 14C activity of the past using the 14C calibration curve (IntCal04). Hence, it is also possible to calculate an artificial stalagmite 14C data set covering the last 25,000 yr with parameters determined for stalagmite ER-77. With this artificially constructed data set, we derived the hypothetical atmospheric 14C activity by using the common method of applying a constant dcf on the modeled 14C data set of the stalagmite. This theoretical approach allows to analyze the impact of a constant and variable SOM age spectrum on atmospheric 14C reconstructions performed with real stalagmite 14C measurements. We observe deviations between IntCal04 and the atmospheric 14C activity as derived with our modeled 14C data set, which are larger for older SOM than for younger SOM and vary in time up to 2 pMC, depending on the strength of the variations in the atmospheric 14C level. This value is comparable with the 1-σ uncertainty given by IntCal04 for the last glacial. For a varying SOM age spectrum, the deviations between the calibration curve and 14C level of the atmosphere reconstructed with a stalagmite exceed 3 pMC, which is larger than the 1-σ uncertainty of IntCal04. In general, the SOM has smoothing, shifting, and 14C-depleting effects on the stalagmite 14C record and, therefore, on the stalagmite-derived atmospheric 14C activity. In this study, changes in soil-air pCO2 and carbonate dissolution conditions, which have also an important impact on the 14C record of a stalagmite, are not accounted for.

Calibration is a fundamental stage of the radiocarbon (14C) dating process if one is to derive meaningful calendar ages from samples' 14C measurements. For the first time, the IntCal09 calibration curve (Reimer et al. 2009) provided an internationally ratified calibration data set across almost the complete range (0 to 50,000 cal BP) of the 14C timescale. However, only the last 12,550 cal yr of this record are composed of terrestrial data, leaving approximately three quarters of the 14C timescale necessarily calibrated via less secure, marine records (incorporating assumptions pertaining to the temporally variable “marine reservoir effect”). The predominantly annually laminated (varved) sediment profile of Lake Suigetsu, central Japan, offers an ideal opportunity to derive an extended terrestrial record of atmospheric 14C across the entire range of the method, through pairing of 14C measurements of terrestrial plant macrofossil samples (extracted from the sediment) with the independent chronology provided through counting of its annual laminations.

This paper presents new data (182 14C determinations) from the upper (largely non-varved) 15 m of the Lake Suigetsu (SG06) sediment strata. These measurements provide evidence of excellent coherence between the Suigetsu 14C data and the IntCal09 calibration curve across the last ~12,000 cal yr (i.e. the portion of IntCal based entirely on terrestrial data). Such agreement demonstrates that terrestrial plant material picked from the Lake Suigetsu sediment provides a reliable archive of atmospheric 14C, and therefore supports the site as being capable of providing a high-resolution extension to the “wholly terrestrial” (i.e. non-reservoir-corrected) calibration curve beyond its present 12,550 cal BP limit.

In order to assess open-system behavior of radiocarbon in fossil gastropod shells, we measured the 14C activity on 10 aliquots of shell material recovered from Illinoian (~190–130 ka) and pre-Illinoian (~800 ka) loess and lacustrine deposits in the Midwestern USA. Eight of the 10 aliquots yielded measurable 14C activities that ranged from 0.25 to 0.53 percent modern carbon (pMC), corresponding to apparent 14C ages between 48.2 and 42.1 ka. This small level of open-system behavior is common in many materials that are used for 14C dating (e.g. charcoal), and typically sets the upper practical limit of the technique. Two aliquots of gastropod shells from the Illinoian-aged Petersburg Silt (Petersburg Section) in central Illinois, USA, however, yielded elevated 14C activities of 1.26 and 1.71 pMC, which correspond to apparent 14C ages of 35.1 and 32.7 ka. Together, these results suggest that while many fossil gastropods shells may not suffer from major (>1%) open-system problems, this is not always the case. We then examined the mineralogy, trace element chemistry, and physical characteristics of a suite of fossil and modern gastropod shells to identify the source of contamination in the Petersburg shells and assess the effectiveness of these screening techniques at identifying samples suitable for 14C dating. Mineralogical (XRD) and trace element analyses were inconclusive, which suggests that these techniques are not suitable for assessing open-system behavior in terrestrial gastropod shells. Analysis with scanning electron microscopy (SEM), however, identified secondary mineralization (calcium carbonate) primarily within the inner whorls of the Petersburg shells. This indicates that SEM examination, or possibly standard microscope examination, of the interior of gastropod shells should be used when selecting fossil gastropod shells for 14C dating.

The long tradition of relative chronology based on pottery typology has often hindered the development of radiocarbon dating amongst the Tripolye giant-settlement in Ukraine. Although it is fairly reliable, relative chronology encounters insurmountable obstacles in identifying internal phases of development within a single settlement. This paper presents the first attempt to use 14C dates to monitor the chronological development of the Talianki giant-settlement, from its formation to the various phases of development and the final decline. It then goes one step further by proving genetic links between 2 “neighboring” settlements, confirming that one is the result of migration processes of the other. This study does not intend to prove that one of the dating techniques is better than the other, but to demonstrate that a synergetic combination of the 2 methods will certainly lead to more reliable results.

Ash is formed when plant calcium oxalate crystals (CaC2O4) decompose to form calcite (CaCO3). We found that ash does retain the original calcium oxalate radiocarbon concentration, but in addition, there is another minor 14C source. This is shown by the presence of a consistent small shift in the pMC and δ13C levels when comparing cellulose and ash from modern and archaeological woods. Possible mechanisms for 14C exchange during combustion or due to diagenesis are considered in order to define parameters for identifying better-preserved wood ash samples.