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XLII.—On the Precipitation of Soluble Chlorides by Hydrochloric Acid

Published online by Cambridge University Press:  15 September 2014

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Extract

In a communication made to this Society on December 6, 1897, a tendency towards maximum specific electrolytic conductivity was shown to be a characteristic of many chemical reactions. This tendency is very marked in reactions in which strong acids play a part. Thus, to take a well-known example, chlorine decomposes water under the influence of light with production of hydrogen chloride and oxygen, but as the hydrogen chloride accumulates in the solution, the decomposition of the water is more and more retarded. This photo-chemical reaction is a reversible one, for in the case of highly concentrated solutions the hydrogen chloride is oxidised to water and free chlorine.

Type
Proceedings
Copyright
Copyright © Royal Society of Edinburgh 1910

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References

page 562 note * Proc. Roy. Soc. Edin., vol. xxii. p. 33.

page 567 note * Z. für anorg. Ch., xxxix. 359, 1904.