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Amorphous Sulphur and its Relation to the Freezing Point of Liquid Sulphur

Published online by Cambridge University Press:  15 September 2014

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Extract

Rhombic and monoclinic sulphur are two physical states of the element with a transition point at 96°. The relation of amorphous sulphur to liquid sulphur is entirely different. The former is produced by heating liquid sulphur, and is found in increasing proportion as the temperature is raised. At 448° it reaches about forty per cent. As the temperature falls, the proportion of amorphous sulphur recedes, although sudden cooling arrests the regression, and furnishes solid specimens containing the larger proportions proper to higher temperatures. The case seems to be one of chemical equilibrium, S (liquid) ⇌ S (amorphous), in which the action, as written, is endothermal.

Type
Proceedings
Copyright
Copyright © Royal Society of Edinburgh 1904

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