The structure of positive boundary blow-up solutions to semilinear problems of the form −Δu = λf(u) in Ω, u = ∞ on ∂Ω, Ω ⊂ RN a bounded smooth domain, is studied for a class of nonlinearities f ∈ C1 ([0, ∞)\{z2}) satisfying f (0) = f(z1) = f (z2) = 0 with 0 < z1 < z2, f < 0 in (0, z1)∪(z2, ∞), f > 0 in (z1, z2). Two positive boundary-layer solutions and infinitely many positive spike-layer solutions are obtained for λ sufficiently large.