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Powder diffraction investigations of naphthalenesulfonic acids and their complexes with DMAN

Published online by Cambridge University Press:  05 March 2012

A. Rafalska-Lasocha ,
M. Grzywa ,
B. Włodarczyk-Gajda  and
W. Lasocha
A. Rafalska-Lasocha
Affiliation:
Faculty of Chemistry Jagiellonian University, Ingardena 3. 30-060, Krako´w, Poland
M. Grzywa
Affiliation:
Faculty of Chemistry Jagiellonian University, Ingardena 3. 30-060, Krako´w, Poland
B. Włodarczyk-Gajda
Affiliation:
Faculty of Chemistry Jagiellonian University, Ingardena 3. 30-060, Krako´w, Poland
W. Lasocha*
Affiliation:
Faculty of Chemistry Jagiellonian University, Ingardena 3. 30-060, Krako´w, Poland
*
a)Author to whom correspondence should be addressed. Electronic mail: lasocha@chemia.uj.edu.pl
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Abstract

The X-ray diffraction patterns of two organic acids 1-naphthalenesulfonic acid dihydrate and 2-naphthalenesulfonic acid hydrate were measured at room temperature. Complexes of these acids with 1,8-bis(dimethylamino)naphthalene (DMAN) were synthesized, purified and investigated by means of X-ray powder diffraction. 1-Naphthalenesulfonic acid dihydrate as well as its complex with 1,8-bis(dimethylamino)naphthalene crystallize in the monoclinic system with unit cell parameters refined to a=0.91531(8) nm, b=0.7919(1) nm, c=0.8184(1) nm, β=101.618(9)° space group P21/m (11) and a=1.7781(4) nm, b=2.0122(4) nm, c=1.2337(2) nm, β=96.54(3)°, space group C2/m (12), respectively. 2-Naphthalenesulfonic acid hydrate crystallizes in the orthorhombic system with a=2.2749(3) nm, b=0.7745(1) nm, c=0.591 36(9) nm, space group Pnma, whereas its complex with 1,8-bis(dimethylamino)naphthalene crystallizes in the triclinic system a=1.3969(6) nm, b=1.4292(5) nm, c=1.1741(6) nm, α=90.93(3)°, β=98.14(3)°, γ=113.93(3)°, space group P-1 (2).

Keywords

X-ray powder diffractionnaphthalenesulfonic acidsDMAN
Type
New Diffraction Data
Information
Powder Diffraction , Volume 19 , Issue 4 , December 2004 , pp. 378 - 384
Copyright
Copyright © Cambridge University Press 2004

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References

Appelman, D. E., Evans, H. T., and Handwerker, D. S. (1966), “Program X-ray, Geological Survey.”Google Scholar
Brzezin´ski, B., Schroeder, G., Olejnik, J., Jarczewski, A., Grech, E., and Milart, P. (1997). “FTIR and 1H NMR studies of proton transfer reactions from ‘C-acids’ to N-bases in acetonitrile,” J. Mol. Struct. JMOSB4 406, 99. jmb JMOSB4 CrossRefGoogle Scholar
Głowiak, T., Grech, E., Lis, T., Nowicka-Scheibe, J., Malarski, Z., Sawka Dobrowolska, W., Stefaniak, L., and Sobczyk, L. (1998). “The [NHN]− homoconjugated anions: X-ray diffraction, IR and multinuclear MR studies,” J. Mol. Struct. JMOSB4 448, 121. jmb JMOSB4 CrossRefGoogle Scholar
Lasocha, W., and Lewinski, K. (1994). “PROSZKI—A system of programs for powder diffraction data analysis,” J. Appl. Crystallogr. JACGAR 27, 437. acr JACGAR CrossRefGoogle Scholar
Lasocha, W., Milart, P., Rafalska-Lasocha, A., and Schenk, H. (2001). “Crystal structure of the complex of 1,8-bis(dimethylamino)-naphthalene with p-nitrosophenol by powder diffraction methods,” Z. Kristallogr. ZEKRDZ 216, 117. zek ZEKRDZ CrossRefGoogle Scholar
Ozeryanskii, V. A., Pozharski, A. F., Głowiak, T., Majerz, I., Sobczyk, L., Grech, E., and Nowicka-Scheibe, J. (2002). “X-ray diffraction and IR-spectroscopic studies on protonated 4-amino-1,8-bis(dimethylamnino)naphthalene,” J. Mol. Struct. JMOSB4 607, 1. jmb JMOSB4 CrossRefGoogle Scholar
PDF-2—PCPDFWIN, version 1.20 September 1996, International Center for Diffraction Data, Newton Square, Pennsylvania.Google Scholar
Smith, G. S., and Snyder, R. L. (1979). “FN: A criterion for rating powder diffraction patterns and evaluating the reliability of powder-pattern indexing,” J. Appl. Crystallogr. JACGAR 12, 60. acr JACGAR CrossRefGoogle Scholar
Sonneveld, E., and Visser, J. W. (1975). “Automatic collection of powder data from photographs,” J. Appl. Crystallogr. JACGAR 8, 1. acr JACGAR CrossRefGoogle Scholar
Visser, J. W. (1969). “A fully automatic program for finding the unit cell from powder data,” J. Appl. Crystallogr. JACGAR 2, 89. acr JACGAR CrossRefGoogle Scholar
Werner, P. E., and Eriksson, L. (1985). TREOR, “A semi-exhaustive trial-and-error powder indexing program for all symmetries,” J. Appl. Crystallogr. JACGAR 18, 367. acr JACGAR CrossRefGoogle Scholar
deWolf, P. M. (1972). “A definition of the indexing figure of merit M20,” J. Appl. Crystallogr. JACGAR 5, 243. acr JACGAR CrossRefGoogle Scholar
Woz´niak, K., He, H., Klinowski, J., Barr, T. L., and Milart, P. (1996). “ESCA and solid-state NMR studies of ionic complexes of 1,8-Bis(dimethylamino)naphthalene,” J. Phys. Chem. JPCHAX 100, 11420. jch JPCHAX CrossRefGoogle Scholar