Hostname: page-component-848d4c4894-tn8tq Total loading time: 0 Render date: 2024-06-21T14:02:43.523Z Has data issue: false hasContentIssue false
  • English
  • Français

Vanadium Oxide Nanotubes: New Synthesis Route and Mechanism of Formation.

Published online by Cambridge University Press:  01 February 2011

Maguy Jaber ,
Nathalie Steunou ,
Thierry Azaïs  and
Jacques Livage
Maguy Jaber
Affiliation:
Chimie de la Matière Condensée (UMR CNRS 7574), Université P. et M. Curie, T54-E5, 4 place jussieu, 75252 Paris cedex 05, France. steunou@ccr.jussieu.fr
Nathalie Steunou
Affiliation:
Chimie de la Matière Condensée (UMR CNRS 7574), Université P. et M. Curie, T54-E5, 4 place jussieu, 75252 Paris cedex 05, France. steunou@ccr.jussieu.fr
Thierry Azaïs
Affiliation:
Chimie de la Matière Condensée (UMR CNRS 7574), Université P. et M. Curie, T54-E5, 4 place jussieu, 75252 Paris cedex 05, France. steunou@ccr.jussieu.fr
Jacques Livage
Affiliation:
Chimie de la Matière Condensée (UMR CNRS 7574), Université P. et M. Curie, T54-E5, 4 place jussieu, 75252 Paris cedex 05, France. steunou@ccr.jussieu.fr
Get access

Abstract

The synthesis of vanadium oxide nanotubes containing phosphorus (VPOx-NT) is described. A mixture of V2O5.nH2O gels, phosphoric acid and hexadecylamine was heated under hydrothermal conditions at 180°C for 7 days. The VPOx nanotubes were characterized by X-ray diffraction, scanning and transmission electron microscopy, 51V and 31P solid state NMR. In-situ experiments were performed in order to get a better understanding of the mechanism of these nanotubes formation.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 847: Symposium EE – Organic/Inorganic Hybrid Materials , 2004 , EE9.24
Copyright
Copyright © Materials Research Society 2005

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1. (a) Krumeich, F., Muhr, H-J., Niederberger, M., Bieri, F., Schnyder, B., Nesper, R., J. Am. Chem. Soc. 121, 8324 (1999).Google Scholar
(b) Niederberger, M., Muhr, H-J., Krumeich, F., Bieri, F., Günther, D., Nesper, R., Chem. Mater. 12, 1995 (2000).Google Scholar
2. Guliants, V. V., Benziger, J. B., Sundaresan, S., Wachs, I. E., Jehng, J-M., Roberts, J. E., Catal. Today 28, 275 (1996).Google Scholar
3. Chandrappa, G. T., Steunou, N., Cassaignon, S., Bauvais, C., Livage, J., Catal. Today, 78(1–4), 85 (2003).Google Scholar
4. Lapina, O. B., Khabibulin, D. F., Shubin, A. A., Bondareva, V. M., J. Mol. Catal. 162, 381 (2000).Google Scholar
5. O'Mahony, L., Zemlyanov, D., Smith, M. E., Hodnett, B. K., Appl. Catal. 251, 327 (2003)Google Scholar
6. Sannes, M. T., Tuel, A., Solid State Nucl. Magn. Reson. 6, 157 (1996).Google Scholar
7. Durupthy, O., Coupé, A., Tache, L., Rager, M-N, Maquet, J., Coradin, T., Steunou, N., Livage, J., Inorg. Chem. 43, 2021 (2004).Google Scholar