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UO2 Corrosion Study in Mineral Water: A Surface Analysis Approach

Published online by Cambridge University Press:  26 February 2011

P. Franco
Affiliation:
IRDI/DCAEA/SEAIN-CEA/CEN SACLAY, 91191 Gif sur Yvette (France)
P. Trocellier
Affiliation:
IRDI/DCAEA/SEAIN-CEA/CEN SACLAY, 91191 Gif sur Yvette (France)
F. Menes
Affiliation:
IRDI/DCAEA/SEAIN-CEA/CEN SACLAY, 91191 Gif sur Yvette (France)
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Abstract

Surface examination of sintered UO2 pellets, leached in groundwater at 90°C, have been conducted and the main results are described. They show the presence of a hydrated layer in which the uranium content decreases with leaching time. The oxidation state of uranium seems to remain (IV). The major components of the layer are magnesium and silicon. The growth of the surface layer in mineral water involves a decrease of uranium release in opposition to its continuing increase i n deionized water.

Type
Research Article
Copyright
Copyright © Materials Research Society 1989

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References

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