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Understanding Aniline Surface Treatment of CdTe

Published online by Cambridge University Press:  01 February 2011

Kevin D. Dobson ,
Stephanie A. Einstein ,
Daniel D. Sadowsky ,
Brian E. McCandless  and
Robert W. Birkmire
Kevin D. Dobson
Affiliation:
Institute of Energy Conversion, University of Delaware, Newark, DE 19716, USA
Stephanie A. Einstein
Affiliation:
Institute of Energy Conversion, University of Delaware, Newark, DE 19716, USA
Daniel D. Sadowsky
Affiliation:
Institute of Energy Conversion, University of Delaware, Newark, DE 19716, USA
Brian E. McCandless
Affiliation:
Institute of Energy Conversion, University of Delaware, Newark, DE 19716, USA
Robert W. Birkmire
Affiliation:
Institute of Energy Conversion, University of Delaware, Newark, DE 19716, USA
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Abstract

Surface etching of CdTe under illumination in aqueous aniline-based solutions has been investigated. Analysis of treated samples shows the formation of crystalline Te on the CdTe surface. Analysis of bath and treatment conditions indicated the presence of aniline, Cl- ions, dissolved O2, consistent illumination and careful control of pH as critical for successful surface etching. A photocatalytic mechanism is proposed for the reaction, where CdTe is etched by H2O2 or similar, generated through reduction of dissolved O2 by conduction band electrons and complemented by oxidation of aniline. The generated Te is stable in the bath and the treatment provides reproducible surfaces. CdTe/CdS devices of 12% conversion efficiency were processed with 30 min aniline treatments. The toxicity of aniline is a concern and criteria for possible substitutes are discussed.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 865: Symposium F – Thin-Film Compound Semiconductor Photovoltaics , 2005 , F8.2
Copyright
Copyright © Materials Research Society 2005

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