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Time-Resolved X-Ray Absorption Spectroscopy: Strengths and Limitations

Published online by Cambridge University Press:  21 February 2011

A. Fontaine
Affiliation:
Lure (Lab. CNRS, CEA, MEN) Bât. 209D, 91405 ORSAY Cedex, FRANCE
E. Dartyge
Affiliation:
Lure (Lab. CNRS, CEA, MEN) Bât. 209D, 91405 ORSAY Cedex, FRANCE
J. P. Itie
Affiliation:
Physique des Milieux Condensés (C.N.R.S. - U.A. 782), Universit&M Curie, T13 E4, 4 place Jussieu, F-75252 Paris Cedex 05
A. Jucha
Affiliation:
Lure (Lab. CNRS, CEA, MEN) Bât. 209D, 91405 ORSAY Cedex, FRANCE
A. Polian
Affiliation:
Physique des Milieux Condensés (C.N.R.S. - U.A. 782), Universit&M Curie, T13 E4, 4 place Jussieu, F-75252 Paris Cedex 05
H. Tolentino
Affiliation:
Lure (Lab. CNRS, CEA, MEN) Bât. 209D, 91405 ORSAY Cedex, FRANCE
G. Tourillon
Affiliation:
Lure (Lab. CNRS, CEA, MEN) Bât. 209D, 91405 ORSAY Cedex, FRANCE
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Abstract

X-ray Absorption Spectroscopy has proved to be a powerful tool to elucidate a huge number of questions in materials science. Great interest exists in time-resolved experiments achieved with extreme energy resolution and energy scale stability to take a full benefit of the strong correlation between the stereochemical environment of the absorbing atom and the exact shape and position of the absorption edge.

Fast energy dispersive X-ray spectroscopy allows in-situ observations with data collected in a short time. Nowadays the main limitation concerns very low-concentration samples since It is no longer possible to use the dispersive geometry because detection of the signal via the decay channels is no more possible.

Type
Research Article
Copyright
Copyright © Materials Research Society 1989

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