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Third-Order Nonlinear Optical Effects in Organic Polymeric Films

Published online by Cambridge University Press:  25 February 2011

Paras N. Prasad
Paras N. Prasad*
Affiliation:
Department of Chemistry, State University of New York at Buffalo, Buffalo, New York 14214
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Abstract

This paper presents some recent theoretical and experimental work carried out in the author's laboratory on the nonlinear optical properties of organic polymers. The ab initio SCF theory has been used with the finite field method to calculate the third order nonlinearity of conjugated structures in order to understand the effect of conjugation and the role of substituents. Experimental studies of third order resonant nonlinearlty in polythiophenes and cumylphenoxy phthalocyanine, the latter in the form of Langmuir-Blodgett films, are presented using femtosecond degenerate four wave mixing.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 109: Symposium K – Nonlinear Optical Properties of Polymers , 1987 , 271
Copyright
Copyright © Materials Research Society 1988

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References

REFERENCES

[1] Prasad, P. N. and Ulrich, D. R., Eds., Nonlinear Optical and Electroactive Polymers (Plenum Press, New York, 1988).CrossRefGoogle Scholar
[2] Sauteret, C., Hermann, J. P., Frey, R., Pradese, P., Ducuing, J., Baughman, R. H. and Chance, R. R., Phys. Rev. Lett. 36, 956 (1976).CrossRefGoogle Scholar
[3] Rao, D. N., Chopra, P., Swiatkiewicz, J., Ghoshal, S. K. and Prasad, P. N., J. Chem. Phys. 84, 7049 (1986).CrossRefGoogle Scholar
[4] Rao, D. N., Swiatkiewicz, J., Chopra, P., Ghoshal, S. K. and Prasad, P. N., Appl. Phys. Lett. 48, 1187 (1986).CrossRefGoogle Scholar
[5] Prasad, P. N., Thin Solid Films 152, 275 (1987).CrossRefGoogle Scholar
[6] Berkovic, G., Shen, Y. R. and Prasad, P. N., J. Chem. Phys. 87, 1882 (1987).CrossRefGoogle Scholar
[7] Singh, B. P. and Prasad, P. N., J. Opt. Soc. Am. B (in press).Google Scholar
[8] Garito, A. F., Teng, C. C., Wong, K. Y., and Zamani-Khamiri, O., Mol. Cryst. Liq. Cryst. 106, 219 (1984).CrossRefGoogle Scholar
[9] Chopra, P., Carlacci, L., King, H. F. and Prasad, P. N., submitted to J. Chem. Phys.Google Scholar
[10] Boggaard, M. P. and Orr, B. J., Int. Rev. Sci. Phys. Chem.-Ser. two 2, 149 (1975).Google Scholar
[11] Zamani-Khamiri, O. and Hameka, H. F., J. Chem. Phys. 72, 5903 (1980); 73, 5693 (1980).Google Scholar
[12] Vardeny, Z., Ehrenfreund, E., Brafman, O., Nowak, M., Schaffer, H., Heeger, A. J. and Wudl, F., Phys. Rev. Lett. 56, 671 (1986).CrossRefGoogle Scholar
[13] Sate, M., Tanaka, S. and Kaeriyama, K., Makromol. Chem. 188, 1763 (1987).CrossRefGoogle Scholar
[14] Kobayashi, M., Chen, J., Mbraes, T. C., Heeger, A. J. and Wudl, F., Synth. Metal 9, 77 (1984).CrossRefGoogle Scholar
[15] 7. Ding, M. and Garmire, E., Appl. Opt. 22, 3177 (1983).CrossRefGoogle Scholar
[16] Druy, M. A. and Seymour, R. J., J. de Phys. Cell. 44, C3–595 (1983).Google Scholar
[17] Heeger, A. J., Moses, D. and Sinclair, M., Synthetic Metals 17, 343 (1987).CrossRefGoogle Scholar
[18] Abrams, R. L., Lam, J. F., Lind, R. C., Steel, D. G. and Liao, P. F., in Optical Phase Conjugation, edited by Fisher, R. A. (Academic Press, New York, 1983), p. 211.CrossRefGoogle Scholar
[19] Kanets, K., Kohno, Y. and Yoshino, K., Solid State Commun. 51, 267 (1984).CrossRefGoogle Scholar
[20] Kanets, K., Kohne, Y. and Yoshino, K., Mel. Cryst. Liq. Cryst. 118, 213 (1985).Google Scholar
[21] de Melo, C. P. and Silbey, R., Chem. Phys. Lett. 140, 537 (1987).CrossRefGoogle Scholar
[22] Barger, W. R., Snow, A. W., Wohltjen, H. and Jarvis, N. L., Thin Solid Films 133, 197 (1985).CrossRefGoogle Scholar
[23] Casstevens, M. and Prasad, P. N., to be published.Google Scholar