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Thiophene Oligomer and NTCDI Semiconductors with High Field-effect Transistor On/off Ratios

Published online by Cambridge University Press:  21 March 2011

Howard E. Katz ,
Andrew J. Lovinger ,
X. Michael Hong  and
Jerainne Johnson
Howard E. Katz
Affiliation:
Bo-Cheng Wang, and Krishnan Raghavachari
Andrew J. Lovinger
Affiliation:
Bo-Cheng Wang, and Krishnan Raghavachari
X. Michael Hong
Affiliation:
Bo-Cheng Wang, and Krishnan Raghavachari
Jerainne Johnson
Affiliation:
Bo-Cheng Wang, and Krishnan Raghavachari
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Extract

Organic semiconductors are of continued interest for low-cost display drivers and logic elements. Field-effect transistors (FETs) with organic semiconductor channels have been fabricated in arrays to drive electrophoretic display pixels[1] and polymer dispersed liquid crystals (http://www.research.philips.com/pressmedia/releases/000901a.html). Complementary logic elements and shift registers containing hundreds of organic-based FETs have been produced[2], and high-speed organic circuits have been fabricated on polyester substrates.[3] The source and drain electrodes of individual FETs have been patterned using microcontact printing and inkjet methods[4] to give extraordinary aspect ratios. Inorganic[5] and hybrid[6] materials have been deposited as FET semiconductors using the methods of “organic electronics”. Organic FET channels have been harnessed to demonstrate ambipolar transport[7], chemical sensitivity[8], superconductivity[9], and electrically pumped lasers[10].

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 665: Symposium C – Electronic, Optical and Optoelectronic Polymers and Oligomers , 2001 , C7.6
Copyright
Copyright © Materials Research Society 2001

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References

REFERENCES

1. Rogers, J. et al. , Toward Electronic Paper: Large Area, Rubber Stamped Plastic Sheets of Electronics and Microencapsulated Electrophoretic Inks. Proceedings of the National Academy of Sciences, 2001.Google Scholar
2. Crone, B. et al. , Large-scale complementary integrated circuits based on organic transistors. Nature, 2000. 403(6769): p. 521–523.Google Scholar
3. Kane, M.G. et al. , Analog and Digital Circuits Using Organic Thin Film Transistors on Polyester Substrates. Ieee Electron Device Letters, 2000. 21(11): p. 534–536.Google Scholar
4. Sirringhaus, H. et al. , High-resolution inkjet printing of all-polymer transistor circuits. Science, 2000. 290(5499): p. 2123–2126.Google Scholar
5. Ridley, B.A., Nivi, B., and Jacobson, J.M., All-Inorganic Field-Effect Transistors Fabricated by Printing. Science, 1999. 286: p. 746–749.Google Scholar
6. Kagan, C.R., Mitzi, D.B., and Dimitrakopoulos, C.D., Organic-inorganic hybrid materials as semiconducting channels in thin-film field-effect transistors. Science, 1999. 286(5441): p. 945–947.Google Scholar
7. Schon, J.H. et al. , Ambipolar pentacene field-effect transistors and inverters. Science, 2000. 287(5455): p. 1022–1023.Google Scholar
8. Torsi, L. et al. , Multi-parameter gas sensors based on organic thin-film-transistors. Sensors and Actuators B-Chemical, 2000. 67(3): p. 312–316.Google Scholar
9. Schon, J.H., Kloc, C., and Batlogg, B., Superconductivity in molecular crystals induced by charge injection. Nature, 2000. 406(6797): p. 702–704.Google Scholar
10. Schon, J.H. et al. , An organic solid state injection laser. Science, 2000. 289(5479): p. 599–601.Google Scholar
11. Laquindanum, J., Katz, H.E., and Lovinger, A.J., Synthesis, Morphology, and Field-Effect Mobility of Anthradithiophenes. Journal of the American Chemical Society, 1998. 120: p. 664–672.Google Scholar
12. Li, W. et al. , Field-Effect Transistors Based on Thiophene Hexamer Analogues with Diminished Electron Donor Strength. Chemistry of Materials, 1999. 11: p. 458–465.Google Scholar
13. Schon, J.H. et al. , High Mobilities in Organic Molecular Crystals. Materials Research Society Symposium Proceedings, 2000. 598: p. BB9.5.1–BB9.5.6.Google Scholar
14. Chwang, A.B. and Frisbie, C.D., Field Effect Transport Measurements on Single Grains of Sexithiophene: Role of the Contacts. Journal of Physical Chemistry B, 2000. 104: p. 12202–12209.Google Scholar
15. Katz, H.E., Torsi, L., and Dodabalapur, A., Synthesis, material properties, and transistor performance of highly pure thiophene oligomers. Chemistry of Materials, 1995. 7(12): p. 2235-&.Google Scholar
16. Horowitz, G. et al. , Thin-Film Transistors Based on Alpha-Conjugated Oligomers. Synthetic Metals, 1991. 41(3): p. 1127–1130.Google Scholar