Hostname: page-component-84b7d79bbc-g5fl4 Total loading time: 0 Render date: 2024-07-25T21:00:40.110Z Has data issue: false hasContentIssue false
  • English
  • Français

Thermal Stability of Thin Films of Ion Beam Deposited CNx

Published online by Cambridge University Press:  01 February 2011

David C. Ingram ,
Asghar Kayani ,
William C. Lanter  and
Charles A. DeJoseph
David C. Ingram
Affiliation:
Condensed Matter and Surface Science Program, Department of Physics and Astronomy Edwards Accelerator Laboratory, Ohio University, Athens OH 45701
Asghar Kayani
Affiliation:
Condensed Matter and Surface Science Program, Department of Physics and Astronomy Edwards Accelerator Laboratory, Ohio University, Athens OH 45701
William C. Lanter
Affiliation:
Innovative Scientific Solutions, Corp., 2766 Indian Ripple Rd., Beavercreek, OH 45440
Charles A. DeJoseph
Affiliation:
Air Force Research Laboratory (AFRL/PRPE), Wright-Patterson AFB, OH 45433
Get access

Abstract

A dual ion beam deposition system was used to deposit thin films of CNx from a carbon target. A 1 keV nitrogen ion beam from a 3 cm Kaufman source was used to sputter carbon from a graphite target, and a second nitrogen ion beam of 50 eV, from an RF ion source, was used to bombard the growing film with nitrogen ions. Using this technique, rather than direct ion beam deposition from methane, it is possible to reduce the amount of hydrogen in these films to less than 5% (atomic), and to boost the nitrogen content to over 30%. These films were then subjected to isochronal heating up to 900°C to determine the stability of the films as compared to those with much higher concentrations of hydrogen.

CNx is a material that is difficult to fabricate without the inclusion of large amounts of hydrogen. A high hydrogen content has the tendency to make the material sensitive to property changes as it is heated over 200°C. Concomitant with a loss of hydrogen is the loss of nitrogen.

In the films that had lower amounts of hydrogen it was found that the loss of nitrogen during heating was delayed until higher temperatures were reached. However, instead of hydrogen being evolved during heating, the amount of hydrogen in the film increases, reaching a maximum concentration of ∼45% at 800°C.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 792: Symposium R – Radiation Effects and Ion Beam Processing of Materials , 2003 , R9.21
Copyright
Copyright © Materials Research Society 2004

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

[1] Liu, A.Y., Cohen, M.L., Physical Review B 32, (1985) 7988.Google Scholar
[2] Liu, A.Y., Cohen, M.L., Physical Review B 41 (1990) 10727.Google Scholar
[3] Ingram, D.C., Lanter, W.C., DeJoseph, C.A., and Kayani, A., Materials Research Society Symposium Proceedings 693 2001 55.Google Scholar
[4] Keay, J.C., and Ingram, D.C., Nuclear Instruments and Methods in Physics Research B 211 (2003) 305 Google Scholar
[5] Marton, D., Boyd, K.J., Al-Bayati, A.H., Todorov, S.S., and Rabalais, J.W., Physical Review Letters 73, (1994) 118.Google Scholar
[6] Ronning, C., Feldermann, H., Merk, R., Hofsass, H., Reinke, P., Thiele, J.-U., Physical Review B 58 (1998) 2207 Google Scholar