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Synthesis of New Multifunctional Polymers inCorporating BIS-(Diphenylamino)Diphenylpolyene Moieties

Published online by Cambridge University Press:  10 February 2011

C. W. Spangler ,
T. Faircloth ,
E. H. Elandaloussi  and
B. Reeves
C. W. Spangler
Affiliation:
Department of Chemistry and Biochemistry, Montana State University, Bozeman, MT 59717, uchcs@earth.oscs.montana.edu
T. Faircloth
Affiliation:
Department of Chemistry and Biochemistry, Montana State University, Bozeman, MT 59717, uchcs@earth.oscs.montana.edu
E. H. Elandaloussi
Affiliation:
Department of Chemistry and Biochemistry, Montana State University, Bozeman, MT 59717, uchcs@earth.oscs.montana.edu
B. Reeves
Affiliation:
Department of Chemistry and Biochemistry, Montana State University, Bozeman, MT 59717, uchcs@earth.oscs.montana.edu
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Abstract

A series of bis-(diphenylamino)diphenylpolyenes containing up to eight double bonds has been synthesized, both as parent model compounds, and functionalized for attachment as pendant chromophores. Oxidative doping of these new materials yields exceptionally stable bipolaronlike dications, even at the triene level. These new materials show promise as bimechanistic optical limiters by reverse saturable absorption and by 2-photon absorption.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 488: Symposium J – Electrical, Optical & Magnetic Properties of Organic IV , 1997 , 283
Copyright
Copyright © Materials Research Society 1998

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References

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