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Synthesis and Characterization of New Electroactive Polymers

Published online by Cambridge University Press:  25 February 2011

L. R. Dalton
L. R. Dalton*
Affiliation:
Department of Chemistry, University of Southern California, Los Angeles, CA 90089-0482
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Abstract

A general scheme for the preparation of soluble electroactive polymers is reviewed with emphasis that polymers so prepared permit investigation of the effects of π-electron delocalization and lattice charge upon nonlinear optical activity. Particular attention is focused upon six membered ring polymer derivatized in 1,4 positions with vinylamine substituents. Such substituents influence rates of polymerization reactions and electronic properties as well as solubility. Preliminary measurement of χ(3) for as-synthesized polymers is effected by DFWM.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 109: Symposium K – Nonlinear Optical Properties of Polymers , 1987 , 301
Copyright
Copyright © Materials Research Society 1988

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References

REFERENCES

1. Wolff, P.A., Yuen, S.Y., Thomas, G.A., Solid State Comm. 60, 645 (1986).Google Scholar
2. Wynne, J.J., Phys. Rev. 178, 1295 (1969).CrossRefGoogle Scholar
3. Yuen, S.Y., Wolff, P.A., Ram-Mohan, L.R., Solid State Comm. 56, 485 (1985).Google Scholar
4. Miller, D.A.B., Chemla, D.S., Eilenberger, D.J., Smith, P.W., Gossard, A.G., Wiegmann, W., Appl. Phys. Letters 42, 925 (1983).Google Scholar
5. Miller, D.A.B., Seaton, C.T., Price, M.E., Smith, S.D., Phys. Rev. Letters 47, 197 (1981).CrossRefGoogle Scholar
6. Yuen, S.Y., Wolff, P.A., Appl. Phys. Letters 40, 457 (1982).Google Scholar
7. Wolff, P.A., Yuen, S.Y., Harris, K.A., Cook, J.W. Jr., Schetzina, J.F., private communication of work to be published.Google Scholar
8. Yuen, S.Y., Becla, P., Optics Letters 8, 356 (1983).Google Scholar
9. Yuen, S.Y., Appl. Phys. Letters, 43, 479 (1983).CrossRefGoogle Scholar
10. Carter, G.M., Chen, Y.J., Rubner, M.F., Sandman, D.J., Thakur, M.K., Tripathy, S.K., Nonlinear Optical Properties of Organic Molecules and Crystals, Vol.2, edited by Chemla, D.S. and Zyss, J. (Academic Press, New York, 1987), p. 85.CrossRefGoogle Scholar
11. Etemad, S., Baker, G.L., Jaye, D., Kayzar, F., Messier, J., Proc. SPIE, 682, 44 (1986).Google Scholar
12. Swiatkiewicz, J., Janiszewska, L., Prasad, P.M., private communication to be published.Google Scholar
13. Prasad, P.N., Proc. SPIE, 682, 120 (1986).Google Scholar
14. Flytzanis, C., in Nonlinear Optical Properties of Organic Molecules and Crystals, Vol.2, edited by Chemla, D.S. and Zyss, J.,(Academic Press, New York, 1987) p. 137.Google Scholar
15. Allen, S., Morley, J.O., Pugh, D., Docherty, V.J., Proc. SPIE, 682, 20 (1986).CrossRefGoogle Scholar
16. Andre, J.-M., Barbier, C., Bodart, V., Delhalle, J., in Nonlinear Optical Properties of Organic Molecules and Crystals, Vol.2, edited by Chemla, D.S. and Zyss, J. (Academic Press, New York, 1987) p. 137.CrossRefGoogle Scholar
17. Dalton, L.R., Proc. SPIE, 682, 77 (1986).CrossRefGoogle Scholar
18. Dalton, L.R., Thomson, J., Nalwa, H.S., Polymer, 28, 543 (1987).CrossRefGoogle Scholar
19. Prasad, P.M. and Ulrich, D.R., in Nonlinear Optical and Electroactive Polymers (Plenum Press, New York, 1987).Google Scholar
20. deMelo, C.P. and Silbey, R., private communication to be published.Google Scholar
21. Dalton, L.R., in Nonlinear Optical and Electroactive Polymers, edited by Prasad, P.N. and Ulrich, D.R. (Plenum Press, New York, 1987).Google Scholar
22. MacDiarmid, A.G., Chiang, J.C., Richter, A.F., Epstein, A.J., Synth. Met. 18, 285 (1987).Google Scholar
23. Patil, A.O., Shenoue, Y., Wudl, F., Heeger, A.J., J. Am. Chem. Soc. 109, 1858 (1987).CrossRefGoogle Scholar
24. Elsenbaumer, R.L., Jen, K.Y., Miller, G.G., Shacklette, L.W., Synth. Met. 18, 277 (1987).Google Scholar
25. Sato, M., Tanaka, S., Kaeriyama, K., Synth. Met. 18, 229 (1987).Google Scholar
26. Kaeriyama, K., Sato, M., Tanaka, S., Synth. Met. 18, 223 (1987).CrossRefGoogle Scholar
27. Epstein, A.J., Ginder, J.M., Roe, M.G., Wigen, P.E., these proceedings.Google Scholar
28. Arnold, F.E. and Van Deusen, R.L., J. Appl. Polym. Sci. 15, 2035 (1971).Google Scholar
29. Kim, O.-K., J. Polym. Sci.: Polym. Lett. Ed., 20, 663 (1982); Mol. Cryst. Liq. Cryst. 105, 161 (1984).Google Scholar
30. Jenekke, S.A. and Tibbetts, S.J., to be published.Google Scholar
31. Boudreaux, D.S., Chance, R.R., Wolf, J.F., Shacklette, L.W., Bredas, J.L., Themans, B., Andre, J.M., Silbey, R., J. Chem. Phys. 85, 4584 (1986).Google Scholar
32. Lehn, J.-M., in Nonlinear Optical Properties of Organic Molecules and Crystals, Vol.2, edited by Chemla, D.S. and Zyss, J. (Academic Press, New York, 1987) p. 215.Google Scholar
33. Fieser, L.F. and Chamberlain, E.M., J. Am. Chem. Soc. 17, 579 (1895).Google Scholar
34. Yu, Lu-Ping and Dalton, L.R., unpublished results.Google Scholar
35. MacDiarmid, A.G., Chiang, J.C., Richter, A.F., Somasiri, N.L.D., Epstein, A.J., in Conducting Polymers, edited by Alcacer, L. (Reidel Publications, Dordrecht, Holland, 1986).Google Scholar
36. As polaron concentrations increase, paramagnetic broadening likely becomes important for the ring and vinyl protons.Google Scholar