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Sulfur Polymer Cement as a Low-Level Waste Glass Matrix Encapsulant, Part I: Thermal Processing

Published online by Cambridge University Press:  15 February 2011

Paul Sliva
Affiliation:
Pacific Northwest National Laboratory,(a) Richland, WA 99352, p-sliva@pnl.gov
Y. Benjamin Peng
Affiliation:
Pacific Northwest National Laboratory,(a) Richland, WA 99352, p-sliva@pnl.gov
L. Roy Bunnell
Affiliation:
Pacific Northwest National Laboratory,(a) Richland, WA 99352, p-sliva@pnl.gov
David K. Peeler
Affiliation:
Pacific Northwest National Laboratory,(a) Richland, WA 99352, p-sliva@pnl.gov
Xiangdong Feng
Affiliation:
Pacific Northwest National Laboratory,(a) Richland, WA 99352, p-sliva@pnl.gov
Paul Martin
Affiliation:
Pacific Northwest National Laboratory,(a) Richland, WA 99352, p-sliva@pnl.gov
Paul J. Turner
Affiliation:
Pacific Northwest National Laboratory,(a) Richland, WA 99352, p-sliva@pnl.gov
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Abstract

Sulfur polymer cement (SPC) is a candidate material to encapsulate low-level waste (LLW) glass. Molten SPC will be poured into a LLW glass cullet-filled canister, surrounding the glass to act as an additional barrier to groundwater intrusion. This paper covers the first part of a study performed at Pacific Northwest National Laboratory concerned with the fundamental aspects of embedding LLW glass in SPC. Part one is a study of the SPC itself. Variations in SPC properties are discussed, especially in relation to long-term stability and controlling crystallization in a cooling canister.

Type
Research Article
Copyright
Copyright © Materials Research Society 1996

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