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Structure and Properties of the Semiconductors Tl2SnAs2Q6 (Q = S, Se)

Published online by Cambridge University Press:  01 February 2011

Ratnasabapathy G. Iyer ,
Daniel Bilc ,
S. D. Mahanti  and
Mercouri G. Kanatzidis
Ratnasabapathy G. Iyer
Affiliation:
Department of Chemistry, Astronomy Michigan State University, East Lansing, MI 48824
Daniel Bilc
Affiliation:
Department of Physics andAstronomy Michigan State University, East Lansing, MI 48824
S. D. Mahanti
Affiliation:
Department of Physics andAstronomy Michigan State University, East Lansing, MI 48824
Mercouri G. Kanatzidis
Affiliation:
Department of Chemistry, Astronomy Michigan State University, East Lansing, MI 48824
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Abstract

We describe the Tl2SnAs2Q6, (Q= S, Se) compounds which consist of [SnAs2S6]2- layers with the Tl+ cations lying in between. Tl2SnAs2S6 and Tl2SnAs2Se6 crystallize in the space group P-3 with a = 6.706(4) Å, c = 7.187(6) Å and a = 6.996(3) Å, c = 7.232(4) Å respectively. These compounds are semiconductors with band gaps of 1.68 eV for the sulfide and 1.08 eV for selenide corresponding to their dark red and black colors respectively. Band structure calculations suggest indirect band gaps in these materials.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 848: Symposium FF – Solid-State Chemistry of Inorganic Materials V , 2004 , FF2.7
Copyright
Copyright © Materials Research Society 2005

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References

REFERENCES

1 (a) Sutorik, A. C., and Kanatzidis, M. G., Prog. Inorg. Chem, 43, 151, (1995).Google Scholar
b) Kanatzidis, M. G., Chem. Mater. 2, 353, (1990).Google Scholar
(b) Kanatzidis, M. G., Curr. Opin. Solid State Mater. Sci. 2, 139, (1997).Google Scholar
2 Iyer, R. G., and Kanatzidis, M. G., Inorg. Chem. 41, 3605 (2002).Google Scholar
3 Iyer, R. G., Do, J., and Kanatzidis, M. G., Inorg. Chem. 42, 1475 (2003).Google Scholar
4 (a) Petkov, K., Todorov, R., Kozhuharova, D., Tichy, L., Cernoskova, E., Ewen, P. J. S., J. Mater. Sci. 39, 961 (2004).Google Scholar
(b) Lippens, P. E., Idrissi, R. M. A., Olivier, F. J., Jumas, J. C., J. Alloys Compd. 298, 47 (2000).Google Scholar
5 (a) Takeuchi, Y., Ghose, S., Nowacki, W., Z. Kristallogr. 121, 321 (1965).Google Scholar
(b) Brown, K. L., Dickson, F. W., Z. Kristallogr. 144, 367 (1976).Google Scholar
(c) Engel, P., Gostojic, M., Nowacki, W., Z. Kristallogr. 165, 209 (1983).Google Scholar
(d) Graeser, S., Wulf, R., Edenharter, A., Schweizerische Mineralog Petrogr. Mitteil. 72, 293 (1992).Google Scholar
(e) Gostojic, M., Edenharter, A., Nowacki, W., Engel, P., Z. Kristallogr. 158, 43 (1982).Google Scholar
6 Blaha, P.; Schwartz, K.; Luitz, J. WIEN97, a full potential linearized augmented plane wave package for calculating crystal properties, Karlhienz Schwartz, Tech. Universitat Wien, Austria, 1999.Google Scholar
7 SMART 5.054, SAINT 6.36, SHELXTL 5.1: Bruker- Axs Inc., Madison, WI 1997.Google Scholar
8 Yamada, N., Ohno, E., Nishiuchi, K., Akahira, N., Takao, M. J. Appl. Phys. 69 (5), 2849 (1991).Google Scholar
9 (a) Idrissi, R. M. A., Durand, J. -M., Bonnet, B., Hafid, L., Olivier, F. J., Jumas, J. C., J. Alloys Compd. 239, 8 (1996).Google Scholar
(b) Koudelka, L., Pisarcik, M., Blinov, L. N., Gutenev, M. S., J. Non-Cryst. Solids 134, 86 (1991).Google Scholar
10 Drabold, D. A., Fedders, P. A., Klemm, S., Sankey, O. F., Phys. Rev. Lett. 67, 2179 (1991).Google Scholar
11 (a) Kolobov, A. V., Tominaga, J., J. Mater. Sci.-Mater. El. 14, 677 (2003).Google Scholar
(b) Lowrey, T. A., Hudgens, S. J., Czubatyj, W., Dennison, C. H., Kostyley, S. A., Wicker, G. C., Mater. Res. Soc. Symp. Proc. 101 (2004).Google Scholar