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Sorption of Hydrogen and Deuterium in a Glassy Pd-Si Alloy by a Bendingcantilever Method

Published online by Cambridge University Press:  15 February 2011

B.S. Berry
Affiliation:
IBM T.J. Watson Research Center, Yorktown Heights, New York 10598, USA
W.C. Pritchet
Affiliation:
IBM T.J. Watson Research Center, Yorktown Heights, New York 10598, USA
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Abstract

The dilatation caused by the sorption of H and D in amorphous samples of melt-spun Pd82Si18 and sputter-deposited Pd81Si19 has been measured at room temperature for ambient charging pressures P up to 760 torr. By comparison with the strength of the Gorsky relaxation, it is concluded that (a) the dilatations per hydrogen and deuterium atom are identical and independent of concentration and (b) the non-linearity of the dilatation vs. p1/2 isotherms is due solely to a deviation from Sieverts' law. The isotherms exhibit a distinct isotope-dependence, of a similar nature to that for crystalline Pd. A sputterdeposited film is found to dissolve more H or D than a melt-spun ribbon, due possibly to a less structurally-relaxed configuration.

Type
Research Article
Copyright
Copyright © Materials Research Society 1982

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References

REFERENCES

1.Berry, B.S. and Pritchet, W.C., Scripta Met. 15, 637 (1981).Google Scholar
2.Berry, B.S. and Pritchet, W.C., Phys. Rev. B, 24, 2299 (1981).10.1103/PhysRevB.24.2299Google Scholar
3.Timoshenko, S., Collected Papers, McGraw Hill, New York, 1953, pp. 403–410.Google Scholar