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Solar Cells based on Cu2ZnSnS4 Thin Films Prepared from Metal Salts and Thioacetamide

Published online by Cambridge University Press:  17 April 2019

Achim Fischereder ,
Katharina Gruber ,
Wernfried Haas ,
Armin Zankel ,
Thomas Rath ,
Ferdinand Hofer  and
Gregor Trimmel
Achim Fischereder
Affiliation:
Institute for Chemistry and Technology of Materials, Graz University of Technology, Stremayrgasse 9, 8010 Graz, Austria Christian Doppler Laboratory for Nanocomposite Solar Cells, Graz University of Technology and NanoTecCenter Weiz Forschungsgesellschaft mbH, Austria
Katharina Gruber
Affiliation:
Institute for Chemistry and Technology of Materials, Graz University of Technology, Stremayrgasse 9, 8010 Graz, Austria
Wernfried Haas
Affiliation:
Christian Doppler Laboratory for Nanocomposite Solar Cells, Graz University of Technology and NanoTecCenter Weiz Forschungsgesellschaft mbH, Austria Institute for Electron Microscopy and Fine Structure Research, Graz University of Technology, Steyrergasse 17, 8010 Graz, Austria
Armin Zankel
Affiliation:
Institute for Electron Microscopy and Fine Structure Research, Graz University of Technology, Steyrergasse 17, 8010 Graz, Austria
Thomas Rath
Affiliation:
Institute for Chemistry and Technology of Materials, Graz University of Technology, Stremayrgasse 9, 8010 Graz, Austria Christian Doppler Laboratory for Nanocomposite Solar Cells, Graz University of Technology and NanoTecCenter Weiz Forschungsgesellschaft mbH, Austria
Ferdinand Hofer
Affiliation:
Institute for Electron Microscopy and Fine Structure Research, Graz University of Technology, Steyrergasse 17, 8010 Graz, Austria
Gregor Trimmel
Affiliation:
Institute for Chemistry and Technology of Materials, Graz University of Technology, Stremayrgasse 9, 8010 Graz, Austria Christian Doppler Laboratory for Nanocomposite Solar Cells, Graz University of Technology and NanoTecCenter Weiz Forschungsgesellschaft mbH, Austria
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Abstract

Copper zinc tin sulfide (Cu2ZnSnS4, CZTS) consists of abundant and cheap elements and is therefore a very promising alternative to semiconductors based on Ga or In as solar absorber material. In addition it displays very beneficial properties like a high optical absorption coefficient and an ideal band gap for photovoltaic applications. In this contribution we present the preparation of CZTS thin films from metal salts (copper(I) iodide, zinc(II) acetate and tin(II) chloride) and thioacetamide as sulfur source by a solution based precursor method. CZTS solar cells based on these films as absorber layer with a simple ITO/CZTS/CdS/Al assembly are fabricated and characterized. Efficiencies up to 0.5% were achieved demonstrating the potential of this precursor method for the preparation of CZTS thin films for photovoltaic applications.

Keywords

solution depositionphotovoltaicthin film
Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 1247: Symposium C – Solution Processing of Inorganic and Hybrid Materials for Electronics and Photonics , 2010 , 1247-C05-04
Copyright
Copyright © Materials Research Society 2010

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