Hostname: page-component-848d4c4894-8bljj Total loading time: 0 Render date: 2024-07-03T09:13:04.008Z Has data issue: false hasContentIssue false

“Softlanding” of Monodispersed Small Metal Clusters in Rare Gas Matrices.

Published online by Cambridge University Press:  28 February 2011

W. Harbich
Affiliation:
IPE, EPF-Lausanne, Switzerland,
S. Fedrigo
Affiliation:
IPE, EPF-Lausanne, Switzerland,
J. Buttet
Affiliation:
IPE, EPF-Lausanne, Switzerland,
D.M. Lindsay
Affiliation:
Dept. of Chemistry, CCNY, New York, USA
Get access

Abstract

We report on the successful softlanding of size selected metal clusters in rare gas matrices. Cluster-ions are sputtered from a metal target, energy filtered and mass selected by a quadrupole mass filter. Deposited clusters are detected by optical spectroscopic methods ( absorption, excitation, fluorescence). Our results show that for dimers and trimers fragmentation decreases with decreasing landing energy. In the case of Ag2 for example fewer than 25% of the dimers fragment when they are deposited at 20 eV. Triatomic clusters appear to fragment less easily than the dimers. New spectroscopic transitions have been found for both diatomic and triatomic clusters. Our results, when compared with previous studies on conventionally prepared clusters, show that some dimer and trimer features are incorrectly assigned.

Type
Research Article
Copyright
Copyright © Materials Research Society 1991

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

[1] For a review see: Chapon, C., Gillet, M.F., Henry, C.R. eds.; Small particles and inorganic clusters; Proceedings of the fourth international meeting on small particles and inorganic clusters, Aix en Provence 1988, Springer Verlag 1989 CrossRefGoogle Scholar
[2] For example: Parks, E.K, Weiller, B.H., Bechthold, P.S., Hoffmann, W.F., Nieman, G.C., Pobo, L.G., Riley, S. J., J.Chem. Phys. 88, 1622, (1988)Google Scholar
[3] Lindsay, D.M., Meyer, F. and Harbich, W., Z. Phys. D12, 15 (1989)Google Scholar
[4] Harbich, W., Fedrigo, S., Meyer, F., Lindsay, D.M., Lignieres, J., Rivoal, J.C. and Kreisle, D., J.Chem. Phys. 93, (1990)CrossRefGoogle Scholar
[5] Klotzbücher, W. and Ozin, G.A., Inorg. Chem. 19, 3767 (1980)Google Scholar
[6] For a review see Ozin, G.A., Far. Symp. Chem. Soc. 14, 7, 1980 CrossRefGoogle Scholar
[7] Huber, K.P. and Herzberg, G., Constants of diatomic molecules (van Nostrand, New York, 1979)Google Scholar
[8] Kettler, U., Bechtold, P. S. and Krasser, W. in Physics and Chemistry of Small Clusters, edited by Jena, P., Rao, B. K. and Khanna, S. N. (Plenum, New York, 1987), pg. 589.Google Scholar
[9] Marcus, R. and Schwentner, N. in Physics and chemistry of Small Clusters, edited by Jena, P., Rao, B.K. and Khanna, S.N. (Plenum, New York, 1987),p 611 Google Scholar