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Single-Ion Conducting Polymer Electrolytes: Synthesis and Characterization

Published online by Cambridge University Press:  21 February 2011

Kate E. Doan ,
S. Ganapathiappan ,
Kaimin Chen ,
M.A. Ratner  and
D.F. Shriver
Kate E. Doan
Affiliation:
Northwestern University, Department of Chemistry and Materials Research Center, Evanston, IL 60208
S. Ganapathiappan
Affiliation:
Northwestern University, Department of Chemistry and Materials Research Center, Evanston, IL 60208
Kaimin Chen
Affiliation:
Northwestern University, Department of Chemistry and Materials Research Center, Evanston, IL 60208
M.A. Ratner
Affiliation:
Northwestern University, Department of Chemistry and Materials Research Center, Evanston, IL 60208
D.F. Shriver
Affiliation:
Northwestern University, Department of Chemistry and Materials Research Center, Evanston, IL 60208
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Abstract

Two classes of alkali metal single-ion conducting polymer electrolytes have been characterized and their conductivities examined. Both polymers are sodium ion conductors. The first class is based upon a tetra(alkoxy)-aluminate counterion incorporated into a polyether network, and the second has a sulfonate counterion covalently bonded to a phosphazene backbone. The temperature dependent and concentration dependent conductivities of these polymers are contrasted. Phosphazene polymers that are anion conductors are also discussed.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 135: Symposium M – Solid State Ionics I , 1988 , 343
Copyright
Copyright © Materials Research Society 1989

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References

1. Tonge, J.S., and Shriver, D.F. in Polymers for Electronic Applications, edited by Lai, J. (CRC, Boca Raton, FL) in press.Google Scholar
2. Armand, M.B., Ann. Rev. Mater. Sci., 16, 245, (1986).CrossRefGoogle Scholar
3. See for example Polymer Electrolyte Reviews, edited by MacCallum, J.R. and Vincent, C.A. (Elsevier Applied Science, New York, 1987), Chapters 1-3.Google Scholar
4. Blonsky, P.M., Shriver, D.F., Austin, P.E., and Allcock, H.R., J. Am. Chem. Soc. 106, 6854 (1984).CrossRefGoogle Scholar
5. Blonsky, P.M., Shriver, D.F., Austin, P.E., and Allcock, H.R., Solid State lonics, 18/19, 258 (1986).CrossRefGoogle Scholar
6. Spindler, R. and Shriver, D.F., Macromolecules, 21, 648 (1988).Google Scholar
7. Nicholas, C.V., WIlson, D.J., Booth, C., and Giles, J.R.M., Brit. Polym. J., 20 (3), 289 (1988).Google Scholar
8. Craven, J.R., Mobbs, R.H., Booth, C. and Giles, J.R.M., Makromol. Chem., Rapid Commun., 2, 81 (1986).CrossRefGoogle Scholar
9. Craven, J.R., Nicholas, C.V., Webster, R., Wilson, D.J., Mobbs, R.H., Morris, R.H., Heatley, G.A., Booth, C., and Giles, J.R.M., Brit. Polym. J., 19, 509 (1987).Google Scholar
10. Hardy, L.C. and Shriver, D.F., Macromolecules, 12, 975 (1984).CrossRefGoogle Scholar
11. Hardy, L.C. and Shriver, D.F., J. Am. Chem. Soc., 107, 3823 (1985).CrossRefGoogle Scholar
12. LeNest, J.F., Gandini, A., Cheradame, H. and Cohen-Addad, J.P., Polym. Commun., 28, 302 (1987).Google Scholar
13. Kobayashi, N., Uchiyama, M., and Tsuchida, E., Solid State Ionics, 17, 307 (1985).CrossRefGoogle Scholar
14. Liu, H., Okamoto, Y., Skotheim, T., Pak, Y.S., and Greenbaum, S.G., These Proceedings.Google Scholar
15. Canapathiappan, S., Chen, K. and Shriver, D.F., Macromolecules, 21, 2299 (1988).CrossRefGoogle Scholar
16. Ganapathiappan, S., Chen, K. and Shriver, D.F., J. Am. Chem. Soc., submitted.Google Scholar
17. Papke, B.L., Ratner, M.A. and Shriver, D.F., J. Phys. Chem. Solids, A2, 493 (1981).Google Scholar
18. Angell, C.A., Solid State lonics, 9/10, 3 (1983).Google Scholar