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Silicon Suboxides: The “Co-Deposition” of a-Si:H and SiO2

Published online by Cambridge University Press:  25 February 2011

D. V. Tsu
Affiliation:
Departments of Physics and Materials Science and Engineering, North Carolina State University, Raleigh, NC 27695-8202
G. Lucovsky
Affiliation:
Departments of Physics and Materials Science and Engineering, North Carolina State University, Raleigh, NC 27695-8202
M. W. Watkins
Affiliation:
Departments of Physics and Materials Science and Engineering, North Carolina State University, Raleigh, NC 27695-8202
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Abstract

The deposition mechanism of silicon suboxides (SiOx, x<2) prepared by remote plasma enhanced chemical vapor deposition (Remote PECVD) is investigated. These films were deposited in a Deposition/Analysis chamber designed to investigate the gas phase chemistry. In this technique, an O2/He mixture is plasma excited, and the silane reactant is injected into the deposition chamber down-stream from the plasma tube. We show that if the plasma after-glow is prevented from extending into the deposition region by an electrical grid placed between the plasma tube and the deposition region, silicon dioxide is then deposited for all O2/He mixtures investigated (0.1 to 1.0 %). In contrast, hydrogenated suboxides of silicon are deposited when the plasma after-glow is allowed to extend past the grid into the deposition region.

Type
Research Article
Copyright
Copyright © Materials Research Society 1989

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References

REFERENCES

1. Tsu, D.V., Parsons, G.N., Lucovsky, G. and Watkins, M.W., Mat. Res. Soc. Proc. (Fall 1987, in press)Google Scholar
2. Tsu, D.V., Parsons, G.N., Lucovsky, G. and Watkins, M.W., J. Vac. Sci. Technol. A, (1989, in press)Google Scholar
3. Parsons, G.N., Tsu, D.V., Wang, C. and Lucovsky, G., J. Vac. Sci. Technol. A, (1989, in press)Google Scholar
4. Lucovsky, G., Mantini, M.J., Srivastava, J.K. and Irene, E.A., J. Vac. Sci. Technol. B 5, 530 (1987)CrossRefGoogle Scholar
5. Lucovsky, G., Yang, J., Chao, S.S., Tyler, J.E. and Czubatyi, W., Phys. Rev. B 28, 3225 (1983)CrossRefGoogle Scholar
6. Lucovsky, G., Solid State Commun. 29, 571 (1979)CrossRefGoogle Scholar
7. Chapman, B., Glow Discharge Processes (John Wiley & Sons, New York, 1980)Google Scholar
8. Knights, J.C., Lujan, R.A., Rosenblum, M.P., Street, R.A., Bieglesen, D.K. and Reimer, J.A., Appl. Phys. Lett. 38, 331 (1981).CrossRefGoogle Scholar