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The Role of Nanoparticle Inclusions on High-performance half-Heusler Thermoelectric Materials

Published online by Cambridge University Press:  01 February 2011

Rumana Yaqub
Affiliation:
ryaqub@uno.edu, Advanced Material Research Institute, Univeristy of New Orleans, New Orleans, Louisiana, United States
Paranti Sahoo Sahoo
Affiliation:
pshoo@uno.edu, Advanced Material Research Institute, Univeristy of New Orleans, New Orleans, Louisiana, United States
Julien Pierre Makongo
Affiliation:
jmkongo@uno.edu, Advanced Material Reserch Institute, Univeristy of New Orleans, New Orleans, Louisiana, United States
Westly M Notling
Affiliation:
kazkek@gmail.com, Advanced Material Research Institute, Univeristy of New Orealns, New Orleans, Louisiana, United States
Pierre F. P. Poudeu
Affiliation:
ppoudeup@uno.edu, University of New Orleans, Chemistry, 2000 Lakeshore Dr, SC2005, New Orleans, Louisiana, 70148, United States, (504)2801057, (504)2803185
Kevin L. Stokes
Affiliation:
klstokes@uno.edu, University of New Orleans, Physics, New Orleans, Louisiana, United States
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Abstract

We report the effect of adding NiO nanoparticles on the transport properties of the half-Heusler alloys Zr0.5Hf0.5Ni1-xPdxSn0.99Sb0.01 (x=0, and 0.2). The half-Heusler matrix materials are prepared by traditional powder metallurgy methods. The resulting bulk matrix is mixed with different volume fractions of nanometer-sized NiO particles, previously synthesized by solution-phase chemical methods. The resulting mixture is densified under uniaxial pressure to form a composite. The resulting material is found to contain both half-Heusler and full-Heusler phases. The corresponding compounds have higher thermal conductivity and electron mobility.

Type
Research Article
Copyright
Copyright © Materials Research Society 2010

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