Hostname: page-component-76fb5796d-vfjqv Total loading time: 0 Render date: 2024-04-26T07:24:22.525Z Has data issue: false hasContentIssue false
  • English
  • Français

Reactive Template-Induced Self-Assembly to Ordered Mesoporous Polymer and Carbon

Published online by Cambridge University Press:  08 August 2013

Yeru Liang ,
Ruowen Fu  and
Dingcai Wu
Yeru Liang
Affiliation:
Materials Science Institute, PCFM Lab and DSAPM Lab, School of Chemistry and Chemical Engineering, Sun Yat-sen University, Guangzhou 510275, P. R. China
Ruowen Fu
Affiliation:
Materials Science Institute, PCFM Lab and DSAPM Lab, School of Chemistry and Chemical Engineering, Sun Yat-sen University, Guangzhou 510275, P. R. China
Dingcai Wu*
Affiliation:
Materials Science Institute, PCFM Lab and DSAPM Lab, School of Chemistry and Chemical Engineering, Sun Yat-sen University, Guangzhou 510275, P. R. China
*
*Email: wudc@mail.sysu.edu.cn
Get access

Abstract

As an important method for preparing ordered mesoporous polymer and carbon, organic template directed self-assembly is facing challenges because of the weak non-covalent interactions between the organic templates and the building blocks. Herein we developed a novel synthetic procedure based on a reactive template-induced self-assembly to construct ordered mesoporous framework. The aldehyde end-group of reactive template can react with the building blocks (i.e., resol) to form a stable covalent bond during the self-assembly process. This leads to an enhanced interaction between resol and template and thus achieves the formation of ordered mesostructure.

Keywords

self-assemblychemical synthesisnanostructure
Type
Articles
Information
MRS Online Proceedings Library (OPL) , Volume 1549: Symposium P – Carbon Functional Nanomaterials, Graphene and Related 2D-Layered Systems , 2013 , pp. 143 - 147
Copyright
Copyright © Materials Research Society 2013 

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

Wu, D.; Xu, F.; Sun, B.; Fu, R.; He, H.; Matyjaszewski, K. Design and Preparation of Porous Polymers. Chem. Rev. 2012, 112, 3959–4015.CrossRefGoogle ScholarPubMed
Choi, M.; Ryoo, R. Ordered Nanoporous Polymer-Carbon Composites. Nat. Mater. 2003, 2, 473–476.CrossRefGoogle ScholarPubMed
Liang, C. D.; Li, Z. J.; Dai, S. Mesoporous Carbon Materials: Synthesis and Modification. Angew. Chem. Int. Ed. 2008, 47, 3696–3717.CrossRefGoogle ScholarPubMed
Su, D. S.; Delgado, J. J.; Liu, X.; Wang, D.; Schloegl, R.; Wang, L.; Zhang, Z.; Shan, Z.; Xiao, F.-S. Highly Ordered Mesoporous Carbon as Catalyst for Oxidative Dehydrogenation of Ethylbenzene to Styrene. Chem. Asian J. 2009, 4, 1108–1113.CrossRefGoogle ScholarPubMed
Munoz, B.; Ramila, A.; Perez-Pariente, J.; Diaz, I.; Vallet-Regi, M. MCM-41 Organic Modification as Drug Delivery Rate Regulator. Chem. Mater. 2003, 15, 500–503.CrossRefGoogle Scholar
Wu, Z. X.; Zhao, D. Y. Ordered Mesoporous Materials as Adsorbents. Chem. Commun. 2011, 47, 3332–3338.CrossRefGoogle ScholarPubMed
Zhai, Y.; Dou, Y.; Zhao, D.; Fulvio, P. F.; Mayes, R. T.; Dai, S. Carbon Materials for Chemical Capacitive Energy Storage. Adv. Mater. 2011, 23, 4828–4850.CrossRefGoogle ScholarPubMed
Zhang, F.; Meng, Y.; Gu, D.; Yan, Y.; Chen, Z.; Tu, B.; Zhao, D. An Aqueous Cooperative Assembly Route to Synthesize Ordered Mesoporous Carbons with Controlled Structures and Morphology. Chem. Mater. 2006, 18, 5279–5288.CrossRefGoogle Scholar
Liang, C. D.; Hong, K. L.; Guiochon, G. A.; Mays, J. W.; Dai, S. Synthesis of a large-scale highly ordered porous carbon film by self-assembly of block copolymers. Angew. Chem. Int. Ed. 2004, 43, 5785–5789.CrossRefGoogle ScholarPubMed
Meng, Y.; Gu, D.; Zhang, F.; Shi, Y.; Yang, H.; Li, Z.; Yu, C.; Tu, B.; Zhao, D. Ordered mesoporous polymers and homologous carbon frameworks: amphiphilic surfactant templating and direct transformation. Angew. Chem. Int. Ed. 2005, 44, 7053–7059.CrossRefGoogle ScholarPubMed