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Processable, Chemical Routes to Binary Metal Sulfides

Published online by Cambridge University Press:  22 February 2011

William S. Rees Jr.  and
Gertrud Krauter
William S. Rees Jr.*
Affiliation:
Department of Chemistry and Materials Research and Technology Center, The Florida State University, Tallahassee, Florida 32306-3006
Gertrud Krauter
Affiliation:
Department of Chemistry and Materials Research and Technology Center, The Florida State University, Tallahassee, Florida 32306-3006
*
*Address all correspondence to this author at: School of Chemistry and Biochemistry and School of Materials Science and Engineering, Georgia Institute of Technology, Atlanta, Georgia, 30332-0400
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Abstract

Metal thiolates of the general formula M(SR)2 (M = Pb, Zn, Cd) and Cl-Hg-SR (R = alkyl) have been prepared and characterized by spectroscopic techniques, TGA and, in selected cases, single crystal X-ray diffraction. The metal bis(thiolate) compounds can be converted into the related metal sulfides by thermolyses. The solid state materials have been characterized by XRPD, SEM and, in selected cases, by particle size determination. The volatile pyrolytic co-products have been isolated and characterized by GC/MS. The decomposition pathways of mercury chlorothiolates are more complicated and depend on the nature of the organic group present in Cl-Hg-SR.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 327: Symposium N – Covalent Ceramics II: Non-Oxides , 1993 , 3
Copyright
Copyright © Materials Research Society 1994

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References

1. Smith, R. A., Semiconductors, 2nd ed., (Cambridge University Press, Cambridge, 1978).Google Scholar
2. a) Cowley, A. H., Jones, R. A., Harris, P. A., Atwood, D. A., Contreras, L., Burek, C. J., Angew. Chem. 103, 1164 (1991); Angew. Chem. Int. Eng. Ed. 30, 1143 (1991). b) M. B. Power, A. R. Barron, Chem. Commun. 1991 1315. c) A. N. Mclnnes, M. B. Power, A. R. Barron, Chem. Mater. 4, 11, (1992). d) M. B. Power, J. W. Ziller, A. N. Tyler, A. R. Barron, Organometallics 11, 1055 (1992).Google Scholar
3. a) Rees, W. S. Jr., Anderson, T. J., Green, D. M., Bretschneider, E., MRS Proceedings, Vol. 242, (Materials Research Society, Pittsburgh, 1992), pp. 281–286. b) W. S. Rees, Jr., D. M. Green, W. Hesse, Polyhedron 11, 1667 (1992). c) W. S. Rees, Jr., D. M. Green, T. J. Anderson, E. Bretschneider, B. Pathangey, C. Park, J. Kim., J. Electron. Mater. 21, 361 -366 (1992). d) W. S. Rees, Jr., D. M. Green, W. Hesse, MRS Proceedings, Vol. 282, (Materials Research Society, Pittsburgh, 1993), pp. 63-67.Google Scholar
4. Cowley, A. H. and Jones, R. A., Angew. Chem. Int. Engl. Ed. 28, 1208 (1989).Google Scholar
5. Osakado, K. and Yamamoto, T., Inorg. Chem. 30, 2328 (1991) and references therein.Google Scholar
6. Dance, I., Polyhedron 5, 1037 (1986).Google Scholar
7. Bochmann, M., Webb, K., Harman, M. and Hursthouse, M. B., Angew. Chem. Int. Engl. Ed. 29, 638 (1990).Google Scholar
8. Brennan, J. G., Siegrist, T., Carroll, P. J., Stuczynki, S. M., Brus, L. E. and Steigerwald, M. L., J. Am. Chem. Soc. 111, 4141 (1989).Google Scholar
9. Berg, J. M., Prog. Inorg. Chem. 37, 143 (1988).Google Scholar
10. Dev, S., Ramli, E., Rauchfuss, T. B. and Stem, C. L., J. Am. Chem. Soc. 118, 6385 (1990).Google Scholar
11. Stenhouse, J., Lieb. Ann. 41, 1459 (1869).Google Scholar
12. a) Rees, W. S. Jr., Krduter, G. and Goedken, V., MRS Symposium Proceedings, Volume 283, (Materials Research Society, Pittsburgh, PA, 1993), p. 859. b.) G. Krèuter, V. L. Goedken, B. Neumriller and W. S. Rees, Jr., MRS, Abstract N.4.7, Fall Meeting, Boston, MA, Materials Research Society, Pittsburgh, PA, (1993).Google Scholar
13. Traill, R. J. and Boyle, R. W., Am. Miner. 40, 555 (1955).Google Scholar
14. Ulrich, F. and Zachariasen, W., Z. Krist. 62, 260 (1925).Google Scholar
15. Milligan, W. O., J. Phys. Chem. 38, 797 (1934).Google Scholar
16. Shaw, R. A. and Woods, M., J. Chem. Soc. 1971, 1569.Google Scholar
17. Krüuter, G., Favreau, P., Nunnally, B. and Rees, W. S. Jr., MRS, Abstract N 4.8, Fall Meeting, Boston, MA, Materials Research Society, Pittsburgh, PA, 1993.Google Scholar
18. Krduter, G., Favreau, P., Rees, W. S. Jr., Chem. Mater., submitted for publ.Google Scholar
19. Steigerwald, M. L., Sprinkle, C. R., J. Am. Chem. Soc. 109, 7200 (1987).Google Scholar
20. Biscarini, P., Foresti, E. and Pandella, G., J. Chem. Soc., Dalton Trans. 1984, 953.Google Scholar