Hostname: page-component-848d4c4894-x5gtn Total loading time: 0 Render date: 2024-05-22T03:37:29.698Z Has data issue: false hasContentIssue false
  • English
  • Français

Preparation of Mesoporous Si-M Imide Gels (M=B, Al) via a Non-Aqueous Sol-Gel Route

Published online by Cambridge University Press:  01 February 2011

Fei Cheng ,
Berangere Toury ,
Ralf Supplit  and
John S. Bradley
Fei Cheng
Affiliation:
Department of Chemistry, University of Hull, Cottingham Road, Hull, HU6 7RX, UK
Berangere Toury
Affiliation:
Department of Chemistry, University of Hull, Cottingham Road, Hull, HU6 7RX, UK
Ralf Supplit
Affiliation:
Department of Chemistry, University of Hull, Cottingham Road, Hull, HU6 7RX, UK
John S. Bradley
Affiliation:
Department of Chemistry, University of Hull, Cottingham Road, Hull, HU6 7RX, UK
Get access

Abstract

Silicon-boron and silicon-aluminum imide gels were prepared by catalyzed ammonolyses of the precursors 2,4,6-tris[tris(dimethylamino)silylamino]borazine, {[(CH3)2N]3SiNH}3B3N3H3, 1, 2-(dimethylamino)4,6-di[tris(dimethylamino)silylaminoborazine, {[(CH3)2N]3SiNH}2B3(NMe2)N3H3, 2, and tris(dimethylaminosilylamino)-(tetrahydrofuran)alane, C4H8O)Al[NHSi(NMe2)3]3, 3, respectively. All the gels exhibited mesoporous structures with high surface area.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 726: Symposium Q – Hybrid Organic-Inorganic Materials , 2002 , Q7.8
Copyright
Copyright © Materials Research Society 2002

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

1. Brinker, C.J. and Schere, G.W. Sol-Gel Science, Academic Press, London, 1990.Google Scholar
2. Segal, D. J. Mater. Chem., 7, 1297 (1997).Google Scholar
3. Guizard, C.G. Julbe, A.C. and Ayral, A. J. Mater. Chem., 9, 55 (1999).Google Scholar
4. Gabriel, A.O. Riedel, R. Storck, S. and Maier, W. F. Appl. Organomet. Chem., 11, 1 (1997).Google Scholar
5. Rovai, R. Lehmann, C.W. and Bradley, J.S. Angew. Chem. Int. Ed., 38, 2036 (1999).Google Scholar
6. Mazdiyasni, K. S. Cooke, C. M. J. Am. Ceram. Soc., 56, 628 (1973).Google Scholar
7. a) Farrusseng, D. Schlichte, K. Wingen, A. Kaskel, S. Zibrowius, B. Bradley, J. S. Schüth, F. Angew. Chem. Int. Ed. Engl, 40, 4204, 2001; b)S. Kaskel, D. Farrusseng, K. Schlichte, Chem. Commun., 2481, 2000Google Scholar
8. Cheng, F. Toury, B. Archibald, S. and Bradley, J. S. J. Organometal. Chem. (in press).Google Scholar
9. Toury, B. Miele, P. Cornu, D. Bonnetot, B. and Mongeot, H. Main Group Metal Chem., 22 231 (1999).Google Scholar
10. Nakamoto, K. Infrared and Roman Spectra of Inorganic and Coordination Compounds, (John Wiley & Sons, Inc., New York), 1997.Google Scholar
11. Narula, C. K. Ceramic Precursor Technology and Its Application, Marcel Dekker, New York, 1995.Google Scholar