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Preparation and Characterization of Li4/3Ti5/3O4 Thin Films by Sol-gel Method

Published online by Cambridge University Press:  26 February 2011

C. Hu ,
W. Zhang ,
H. Hao ,
M. H. Cao ,
S. J. Lai ,
X. J. Zhu  and
H. X. Liu
C. Hu
Affiliation:
whhuchen@yahoo.com.cn, Wuhan University of Technology, State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, Wuhan430070,Hubei, PR China., Wuhan, 430070, China, People's Republic of
W. Zhang
Affiliation:
whhuchen@yahoo.com.cn, Wuhan University of Technology, State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan, 430070, China, People's Republic of
H. Hao
Affiliation:
whhuchen@yahoo.com.cn, Wuhan University of Technology, State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan, 430070, China, People's Republic of
M. H. Cao
Affiliation:
whhuchen@yahoo.com.cn, Wuhan University of Technology, State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan, 430070, China, People's Republic of
S. J. Lai
Affiliation:
juanzi211@163.com, Wuhan University of Technology, State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan, 430070, China, People's Republic of
X. J. Zhu
Affiliation:
whhuchen@yahoo.com.cn, Wuhan University of Technology, State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan, 430070, China, People's Republic of
H. X. Liu
Affiliation:
lhxhp@mail.whut.edu.cn, Wuhan University of Technology, State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan, 430070, China, People's Republic of
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Abstract

In the study Li4/3Ti5/3O4 thin films were deposited on Pt substrates by sol-gel method using a spin coator. The coated films are dried at 310-360 °C, and then annealed at 500-800 °C for 30min. The prepared films were characterized by X-ray diffraction, atomic force microscope and scanning electron microscope. The results indicated that the prepared film belonged to a spinel structure and had a uniform morphology. Electrochemical properties of the prepared electrode films were evaluated by using a discharge and charge test. From these results, it can be showed that the thin film electrode annealed at 700 °C exhibited good crystallinity, smooth surface morphology, high capacity, and good rechargeability. Therefore, This film was therefore suitable for use as an anode for thin-film microbatteries.

Keywords

Lisol-gelfilm
Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 972: Symposium AA – Solid-State Ionics—2006 , 2006 , 0972-AA06-16
Copyright
Copyright © Materials Research Society 2007

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References

REFERENCES

1. Rho, Y. H., Kanamura, K., andUmegaki, T., Solid State Ionics 151, 151 (2002).Google Scholar
2. Kanamura, K., Naito, H., andTakehara, Z., Chem. Lett.,45, 1997.Google Scholar
3. Bates, J.B., Gruzalski, G.R., andYu, X., Solid State Ionics 70–71, 619–623 (1994)Google Scholar
4. Bates, J.B., Dudney, N.J., andZuhr, R.A., Journal of Power Sources 54, 58–62 (1995).Google Scholar
5. Striebel, K.A., Wen, S.J., Cairns, E.J., Journal of Electro- chemical Society 143 (6) (1996) 1821.Google Scholar
6. Fragnaud, P., Nagarajan, R., Schleich, K.M., Journal of Power Sources 54, 362–366 (1995)Google Scholar
7. Fragnaud, P., Schleich, D.M., Sensors and Actuators A 51(1995) 21–23.Google Scholar
8. Kim, M. K., Chung, H. T., Park, Y. J., andKim, H. G., J. Power Sources, 99, 34 (2001).Google Scholar
9. Liquan, C., Schoonman, J., Solid State Ionics 67, 17–23 (1994).Google Scholar
10. Croquennec, L., Deniard, P., andBroussely, M., Solid State Ionics 89, 127–137 (1996).Google Scholar