Hostname: page-component-8448b6f56d-sxzjt Total loading time: 0 Render date: 2024-04-18T22:07:50.032Z Has data issue: false hasContentIssue false
  • English
  • Français

Preceramic Polymer Applications - Processing and Modifications by Chemical Means

Published online by Cambridge University Press:  10 February 2011

H. J. Wu ,
Y. D. Blum ,
S. M. Johnson ,
C. Kanazawa ,
J. R. Porter  and
D. M. Wilson
H. J. Wu
Affiliation:
SRI International, Menlo Park, CA 94025
Y. D. Blum
Affiliation:
SRI International, Menlo Park, CA 94025
S. M. Johnson
Affiliation:
SRI International, Menlo Park, CA 94025
J. R. Porter
Affiliation:
Rockwell Science Center, Thousand Oaks, CA
D. M. Wilson
Affiliation:
3M Corporation, St. Paul, MN
Get access

Abstract

The use of preceramic polymers in diverse ceramic applications requires control of a complex set of chemical characteristics to ease processing and develop suitable ceramic properties. The desirable characteristics of a good precursor system are controllable viscosity (preferably without the use of solvents), inhibition of curing during fabrication followed by rapid curing, minimal release of volatiles during curing, high ceramic yield, and controllable final composition and stoichiometry.

This paper describes the use of chemical concepts to synthesize, modify, and manipulate polymeric precursors to silicates and the importance of curing (crosslinking) mechanisms and processing conditions as critical elements in developing ceramic matrix composites.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 435: Symposium V – Better Ceramics Through Chemistry VII , 1996 , 431
Copyright
Copyright © Materials Research Society 1996

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

1. Rosato, D. in Encyclopedia of Polymer Science and Engineering edited by Mark, H. F., Bikales, N.M., Overberger, C G., Menges, G., and Kroschwitz, J.I., Vol. 14, (John Wiley, New York, 1988), pp. 377–391.Google Scholar
2. Leek, R., Carpenter, G., Madsen, J., and Donnellan, T.M., Ceramic Eng. & Sci. Proceedings 16 (4), 191–199 (1995). # The Mullite Matrix Composites (M2C) Consortium consists of 3M, Rockwell, and SRI International. It is funded on a cost-sharing basis by ARPA.Google Scholar
3. (a) Morgan, P.E.D. and Marshall, D.B., Mater. Sci. Eng. A162, 15–25 (1993).(b) P.E.D. Morgan and D.B. Marshall, J. Amer. Ceram. Soc. 78, 1553–63 (1995). (c) P.E.D. Morgan, D.B. Marshall, and R.M. Housley, Mater. Sci. Eng. A195, 215–222 (1995).Google Scholar
4. White, M.S. in Siloxane Polymers, edited by Larson, S.J.C. and Semlyen, J.A. (PTR Prentice Hall, Englewood Cliffs, 1993), pp. 245–308.Google Scholar
5. (a) Blum, Y.D., US Patent 5, 246, 738 (June 7, 1994).(b) Y.D. Blum, US Patent 5,319,121 (September 21, 1993).Google Scholar
6. Kiser, J. D. and Singh, M., Ceramic Eng. & Sci. Proceedings 16 (5), 1107–1114 (1995).Google Scholar
7. Erdal, M., Friedrichs, B., and Guceri, S., Ceramic Eng. & Sci. Proceedings 16( 5), 1097–1100 (1995).Google Scholar
8. Jamet, J., Spann, J.R., Rice, R.W., Lewis, D. and Coblenz, W.S., Ceramic Eng. & Sci. Proceedings 5 (7–8), 677–689 (1984).Google Scholar