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Photoluminescence of Poly(P-Phenylene Vinylene) encapsulated In Mesoporous Silica

Published online by Cambridge University Press:  10 February 2011

Andras G. Pattantyus-Abraham  and
Michael O. Wolf
Andras G. Pattantyus-Abraham
Affiliation:
Department of Chemistry, University of British Columbia, Vancouver, BC, CANADA, V6T IZI
Michael O. Wolf
Affiliation:
Department of Chemistry, University of British Columbia, Vancouver, BC, CANADA, V6T IZI
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Abstract

The preparation of poly(ρ-phenylene vinylene) (PPV) encapsulated in a mesoporous silica, MCM-41, is reported. In situ polymerization of xylylene bis(tetrahydrothiophenium chloride) yields a highly luminescent, yellow powder with a fluorescence spectrum matching that of unencapsulated PPV. Nitrogen adsorption isotherms show that the pore size of the PPVloaded MCM-41 is significantly smaller than that of empty MCM-41 and a polymer loading of ca. 8% by weight is obtained by thermogravimetric analysis. Photoluminescence data for the encapsulated PPV are presented.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 560: Symposium E – Luminescent Materials , 1999 , 291
Copyright
Copyright © Materials Research Society 1999

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