Hostname: page-component-848d4c4894-cjp7w Total loading time: 0 Render date: 2024-06-22T09:11:31.316Z Has data issue: false hasContentIssue false
  • English
  • Français

Photoluminescence and Electroluminescence in Combination of Rare-Earth Metal Complexes and Phosphorescent Molecules

Published online by Cambridge University Press:  26 February 2011

Zenken Kin ,
Yuichi Hino ,
Hirotake Kajii ,
Yasuchika Hasegawa ,
Tsuyoshi Kawai  and
Yutaka Ohmori
Zenken Kin
Affiliation:
k-zenken@casi.osaka-u.ac.jp, Osaka University, Center for Advanced Science and Innovation, 2-1 Yamada-Oka, Suita, 565-0871, Japan
Yuichi Hino
Affiliation:
hino@casi.osaka-u.ac.jp, Osaka University, Center for Advanced Science and Innovation, 2-1 Yamada-oka, Suita, 565-0871, Japan
Hirotake Kajii
Affiliation:
kajii@casi.osaka-u.ac.jp, Osaka University, Center for Advanced Science and Innovation, 2-1 Yamada-oka, Suita, 565-0871, Japan
Yasuchika Hasegawa
Affiliation:
hasegawa@ms.naist.jp, Nara Institute of Science and Technology, Graduate School of Materials Science, 8916-5 Takayama-cho, Ikoma, 630-0192, Japan
Tsuyoshi Kawai
Affiliation:
tkawai@ms.naist.jp, Nara Institute of Science and Technology, Graduate School of Materials Science, 8916-5 Takayama-cho, Ikoma, 630-0192, Japan
Yutaka Ohmori
Affiliation:
ohmori@casi.osaka-u.ac.jp, Osaka University, Center for Advanced Science and Innovation, 2-1 Yamada-oka, Suita, 565-0871, Japan
Get access

Abstract

We investigated luminescent properties of rare-earth metal complexes and phosphor-rescent molecules doped in a conducting polymer. Electroluminescent (EL) properties in combination of red emissive europium complex of tris(di-benzoylmethane)-mono(4,7-diphenyl-phenanthroline) europium (III) (Eu(dbm)3phen) and blue phosphorescent molecule of bis[(4,6-difluoro-phenyl)-pyridinato-N,C2'] (picolinate) iridium (III) (FIrpic) doped in poly(N-vinyl-carbazole) (PVK) and a new rare-earth complex tris(hexafluoroacethylacetonato) (phenan-throline) samarium(III) [Sm(hfa)3(phen)2] have been investigated as an EL emitter. White EL has been obtained from mixed layer of Eu(dbm)3phen and FIrpic, and EL from Sm complex has been obtained. Energy transfer and the emission mechanisms have been discussed.

Keywords

organicoptical propertiesoptoelectronic
Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 965: Symposium S – Organic Electronics – Materials, Devices and Applications , 2006 , 0965-S04-02
Copyright
Copyright © Materials Research Society 2007

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1. Tang, C.W., Van Slyke, S.A., Appl. Phys. Lett. 51, 913 (1987).Google Scholar
2. Ohmori, Y., Uchida, M., Muro, K., Yoshino, K., Jpn. J. Appl. Phys. 30, L1938 (1991).Google Scholar
3. Kido, J., Hongawa, K., Okuyama, K., Nagai, K., Appl. Phys. Lett. 64, 815 (1994).Google Scholar
4. Adachi, C., Baldo, M.A., Forrest, S.R., J. Appl. Phys. 87, 8049 (2000).Google Scholar
5. Moon, D.G., Salata, O.V., Etchells, M., Dobson, P.J., Christou, V., Synth. Met. 123, 355 (2001).Google Scholar
6. Hong, Z., Li, W., Zhao, D., Liang, C., Liu, X., Peng, J., Zhao, D., Synth. Met. 104, 165 (1999).Google Scholar
7. Kawamura, Y., Wada, Y., Hasegawa, Y., Iwamuro, M., Kitamura, T., Yanagida, S., Appl. Phys. Lett., 74, 3245 (1999).Google Scholar
8. Adachi, C., Baldo, M. A., Thompson, M. E., Forrest, S. R., J. Appl. Phys., 90, 5048 (2001).Google Scholar
9. Holmes, R. J. and Forrest, S. R., Tung, Y.-J., Kwong, R. C., Brown, J. J., Garon, S., Thompson, M. E., Appl. Phys. Lett., 82, 2422 (2003).Google Scholar
10. Baldo, M. A., Adachi, C., Forrest, S.R., Phys. Rev. B, 62, 10967 (2000).Google Scholar
11. Hino, Y., Kajii, H., Ohmori, Y., IEICE Transactions on Electronics, E89-C, 1465 (2006).Google Scholar
12. Reyes, R., Hering, E.N., Cremona, M., Silva, C.F.B.da, Brito, H.F., Achete, C.A., Thin Solid Films., 420, 23 (2002).Google Scholar