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Photodissociation Dynamics of Alkyltellurides

Published online by Cambridge University Press:  26 February 2011

P.D. Brewer ,
J.E. Jensen ,
G.L. Olson ,
L.W. Tutt  and
J.J. Zinck
P.D. Brewer
Affiliation:
Hughes Research Laboratories, 3011 Malibu Canyon Road, Malibu, CA 90265
J.E. Jensen
Affiliation:
Hughes Research Laboratories, 3011 Malibu Canyon Road, Malibu, CA 90265
G.L. Olson
Affiliation:
Hughes Research Laboratories, 3011 Malibu Canyon Road, Malibu, CA 90265
L.W. Tutt
Affiliation:
Hughes Research Laboratories, 3011 Malibu Canyon Road, Malibu, CA 90265
J.J. Zinck
Affiliation:
Hughes Research Laboratories, 3011 Malibu Canyon Road, Malibu, CA 90265
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Abstract

The UV photodissociations of dimethyltelluride (CH3)2Te and diethyltelluride (C2Hs)2Te have been investigated by state-selective detection. Nascent populations of Te(5p Pjw) atoms produced by the photodissociation process were monitored using laser-induced fluorescence following excimer laser (248 nm and 193 nm) photolysis. Experimental results for both molecules indicate that the photolysis at 248 nm produces Te atoms via a single photon process and that the liberated Te atoms populate only the 5p3P2 state. The photolysis of diethyltelluride at 193 nm has also been found to be a single photon process producing Te atoms distributed over the 3P2, 3P1, and Pø states in a ratio of 13:2:1, respectively.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 101: Symposium B – Laser and Particle-Beam Chemical Processing for Microelectronics , 1987 , 327
Copyright
Copyright © Materials Research Society 1998

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References

REFERENCES

1 Stringfellow, G.B., Proceedings of the Third International Conference on Metalorganic Vapor Phase Epitaxy (North-Hoiland, Amsterdam, 1986).Google Scholar
2 Connor, J., Greig, G., Strausz, O.P., J. Am. Chem. Soc. 91, 5695 (1969).Google Scholar
3 Young, P.J., Gosavi, R.K., Connor, J., Strausz, O.P., and Gunning, H.E., J. Chem. Phys. 58, 5280 (1973).Google Scholar
4 Mullin, J.B. and Irvine, S.J.C., J. Vac. Sei. Technol. 21, 178 (1982).Google Scholar
5 Brewer, P.D., Chem. Phys. Lett. 141, 301 (1987).Google Scholar
6 Potts, A.W., and Price, W.C., Proc. Roy. Soc. Lond. A 326, 181 (1972).Google Scholar
7 Calvert, J.G., and Pitts, J.N. Jr., Photochemistry (John Wiley & Sons, New York, 1966).Google Scholar
8 Zinck, J.J., Brewer, P.D., Jensen, J.E., Olson, G.L. and Tutt, L.W., to be published App. Phys. Lett. 1988.Google Scholar